Solvolytic liquefaction of oil palm empty fruit bunch (EFB) fibres: Analysis of product fractions using FTIR and pyrolysis-GCMS

• Main Authors: Pua, F.L., Zakaria, S., Chia, C.H., Fan, S.P., Rosenau, T., Potthast, A., Liebner, F.
• Published: 2018
• Online Access: http://dspace.uniten.edu.my/jspui/handle/123456789/7959

Oil palm empty fruit bunch (EFB) fibers were subjected to solvolytic liquefaction to convert into liquid products using ethylene glycol (EG) as a supporting agent. The process was carried out at 250°C for 60 min. The water-insoluble product fraction was exhaustively extracted with acetone (ASL fraction) to separate all less polar. FTIR and comparative analytical pyrolysis GC/MS of the parent EFB fiber and the ASL fraction confirmed the formation of larger amounts of long-chain lipophilic compounds under liquefaction conditions. Furthermore, a considerable amount of less polar thermal lignin degradation products were obtained comprising all of the three main lignin building blocks, i.e. 4-hydroxyphenyl-(P units), 4-hydroxy-3-methoxyphenyl-(G units) and 3,5-dimethoxy-4-hydroxyphenyl (S units) substituted compounds. 4-Prop-2-en-1-yl substituted phenolic compounds contributed mostly to the cumulated peak area of all lignin derived pyrolysis products obtained by analytical Curie point pyrolysis GC/MS at 600C. The results of both instrumental-analytical methods confirm the formation of phenol and its derivatives, furan derivatives, organic acids, hydrocarbon, ester, benzene groups and alcohols.