Synthesis and structural consideration of Metal-Organic Framework (MOF) coordination polymer with various metal linker ratios
Metal-organic framework MOF-5 (i.e. IRMOF-1) with the chemical structure of Zn4O(BDC)3 were successfully synthesized using room temperature synthesis approach of direct-mixing method ans liquid-crystal templating method. The metal clusters organic linker used was benzenedicarboxylic acid (BDC). Dire...
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my.uniten.dspace-69162018-01-11T08:25:21Z Synthesis and structural consideration of Metal-Organic Framework (MOF) coordination polymer with various metal linker ratios Misran, H. Aminuddin, A.M. Zini, F.A.M. Singh, R. Metal-organic framework MOF-5 (i.e. IRMOF-1) with the chemical structure of Zn4O(BDC)3 were successfully synthesized using room temperature synthesis approach of direct-mixing method ans liquid-crystal templating method. The metal clusters organic linker used was benzenedicarboxylic acid (BDC). Direct-mixing approach resulted in MOF-5 with tetragonal cell while the liquid-crystal templating method resulted in cubic structure. The metal/linker ratios were varied from 0.1 to 1 to study the effect of metal linker on the formation of MOF-5 materials and their characteristics. The crystallinity of the evacuated framework MOF-5 materials were increased when the metal/organic linker ratios were increased from 0.3 to 0.5. However, the cubic structure of the evacuated framework was relatively disrupted at metal/linker ratio 0.7. © (2011) Trans Tech Publications. 2018-01-11T08:25:21Z 2018-01-11T08:25:21Z 2011 http://dspace.uniten.edu.my/jspui/handle/123456789/6916 |
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Metal-organic framework MOF-5 (i.e. IRMOF-1) with the chemical structure of Zn4O(BDC)3 were successfully synthesized using room temperature synthesis approach of direct-mixing method ans liquid-crystal templating method. The metal clusters organic linker used was benzenedicarboxylic acid (BDC). Direct-mixing approach resulted in MOF-5 with tetragonal cell while the liquid-crystal templating method resulted in cubic structure. The metal/linker ratios were varied from 0.1 to 1 to study the effect of metal linker on the formation of MOF-5 materials and their characteristics. The crystallinity of the evacuated framework MOF-5 materials were increased when the metal/organic linker ratios were increased from 0.3 to 0.5. However, the cubic structure of the evacuated framework was relatively disrupted at metal/linker ratio 0.7. © (2011) Trans Tech Publications. |
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Misran, H. Aminuddin, A.M. Zini, F.A.M. Singh, R. |
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Misran, H. Aminuddin, A.M. Zini, F.A.M. Singh, R. Synthesis and structural consideration of Metal-Organic Framework (MOF) coordination polymer with various metal linker ratios |
author_facet |
Misran, H. Aminuddin, A.M. Zini, F.A.M. Singh, R. |
author_sort |
Misran, H. |
title |
Synthesis and structural consideration of Metal-Organic Framework (MOF) coordination polymer with various metal linker ratios |
title_short |
Synthesis and structural consideration of Metal-Organic Framework (MOF) coordination polymer with various metal linker ratios |
title_full |
Synthesis and structural consideration of Metal-Organic Framework (MOF) coordination polymer with various metal linker ratios |
title_fullStr |
Synthesis and structural consideration of Metal-Organic Framework (MOF) coordination polymer with various metal linker ratios |
title_full_unstemmed |
Synthesis and structural consideration of Metal-Organic Framework (MOF) coordination polymer with various metal linker ratios |
title_sort |
synthesis and structural consideration of metal-organic framework (mof) coordination polymer with various metal linker ratios |
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2018 |
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http://dspace.uniten.edu.my/jspui/handle/123456789/6916 |
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1644494057770057728 |
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13.159267 |