Influence of complexing agent in Tl-containing sol-gel derived precursor on critical temperature enhancement of Tl0.5Pb0.5Sr1.8Yb0.2 CaCu2O7 superconductor
Superconducting oxide ceramics of composition Tl0.5Pb0.5Sr1.8Yb0.2CaCu 2O7 was prepared by using a single-step sol-gel process using two different complexing agents (tartaric acid and citric acid). The effect of the complexing agents (0.0-11.0% (w/w %)) on superconductivity of the samples were studi...
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| 主要な著者: | , , , , |
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| フォーマット: | 論文 |
| 言語: | en_US |
| 出版事項: |
2017
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| タグ: |
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| 要約: | Superconducting oxide ceramics of composition Tl0.5Pb0.5Sr1.8Yb0.2CaCu 2O7 was prepared by using a single-step sol-gel process using two different complexing agents (tartaric acid and citric acid). The effect of the complexing agents (0.0-11.0% (w/w %)) on superconductivity of the samples were studied. It was found that the values of critical temperature, Tc zero, was enhanced from 88 K (for the sample without any complexing agents) to 95 K (for sample with 11 w/w % tartaric acid) and 97 K (for sample with 11 w/w% citric acid). SEM analysis showed formation of ultra-fine grains with 1-2 μm average grains size for the sample without complexing agents. Addition of the complexing agents induced growth of elongated grains of 5-10 μm in average length. The Tc enhancement was discussed in terms of changes in hole concentration and sample microstructure as a result of use of the complexing agents. © 2008 Asian Network for Scientific Information. |
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