A review study on coupling agents used as ceramic fillers modifiers for dental applications

• Main Authors: Ali Sabri B., Meenaloshini S., Abreeza N.M., Abed A.N.
• Other Authors: 57221737520
• Format: Article
• Published: Elsevier Ltd 2024
• Subjects: Aqueous oral environment; Dental composites; Dental reinforcements; Hydrolytic degradation; Silane coupling agents; Titanium coupling agents (TCAs); Coupling agents; Filled polymers; Fillers; Silica; Titanium; Aqueous environment; Ceramic fillers; Dental applications; Dental reinforcement; Performance; Silane-coupling agents; Titania; Titania coupling agent; Reinforcement

The aim of this study is to provide a review on silanized composite performance when exposed in a complex wet aqueous environment and the role of titanium coupling agent as a more stable and reinforcement material in the construction of dental composites. Silanes are considered as the most dominant materials used for surface modification of the filler added to the polymer material in dental applications. Due to the presence of silica in the silane structure, so, the silane coupling agent were considered to be more effective in modifying materials which are consisting of silica because of the similarity in their ordered structure. Silanes are relatively characterized by dehydration inside the oral aqueous environment. On the other hand, titanate coupling agents are effective in serving at a wet environment, because its ability to react with the positive proton available on the surface of the filler (H+). TCAs are superior in performance in comparison to silane by creating a strong internal bonding between the filler and polymer matrix, and having a significant effect on the dispersion and resolving of particles agglomeration and good hydrolytic stability inside the mouth. This paper presents a comparative study between the effects of silane coupling agents against the TCAs performance in oral environment. � 2021