Development of sustainable biomass residues for biofuels applications

A comprehensive understanding of physiochemical properties, thermal degradation behavior and chemical composition is significant for biomass residues before their thermochemical conversion for energy production. In this investigation, teff straw (TS), coffee husk (CH), corn cob (CC), and sweet sorgh...

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Main Authors: Shah M.A., Hayder G., Kumar R., Kumar V., Ahamad T., Kalam M.A., Soudagar M.E.M., Mohamed Shamshuddin S.Z., Mubarak N.M.
Other Authors: 57203128051
Format: Article
Published: Nature Research 2024
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spelling my.uniten.dspace-338982024-10-14T11:17:24Z Development of sustainable biomass residues for biofuels applications Shah M.A. Hayder G. Kumar R. Kumar V. Ahamad T. Kalam M.A. Soudagar M.E.M. Mohamed Shamshuddin S.Z. Mubarak N.M. 57203128051 56239664100 57214462813 7404634425 12790015800 55103352400 57194384501 8541818000 36634677600 Automobiles Biofuels Biological Transport Biomass Cellulose Eragrostis biofuel cellulose biomass car Eragrostis transport at the cellular level A comprehensive understanding of physiochemical properties, thermal degradation behavior and chemical composition is significant for biomass residues before their thermochemical conversion for energy production. In this investigation, teff straw (TS), coffee husk (CH), corn cob (CC), and sweet sorghum stalk (SSS) residues were characterized to assess their potential applications as value-added bioenergy and chemical products. The thermal degradation behavior of CC, CH, TS and SSS samples is calculated using four different heating rates. The activation energy values ranged from 81.919 to 262.238 and 85.737�212.349 kJ�mol?1 and were generated by the KAS and FWO models and aided in understanding the biomass conversion process into bio-products. The cellulose, hemicellulose, and lignin contents of CC, CH, TS, and SSS were found to be in the ranges of 31.56�41.15%, 23.9�32.02%, and 19.85�25.07%, respectively. The calorific values of the residues ranged from 17.3 to 19.7�MJ/kg, comparable to crude biomass. Scanning electron micrographs revealed agglomerated, irregular, and rough textures, with parallel lines providing nutrient and water transport pathways in all biomass samples. Energy Dispersive X-ray spectra and X-ray diffraction analysis indicated the presence of high carbonaceous material and crystalline nature. FTIR analysis identified prominent band peaks at specific wave numbers. Based on these findings, it can be concluded that these residues hold potential as energy sources for various applications, such as the textile, plastics, paints, automobile, and food additive industries. � 2023, Springer Nature Limited. Final 2024-10-14T03:17:24Z 2024-10-14T03:17:24Z 2023 Article 10.1038/s41598-023-41446-1 2-s2.0-85169230606 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85169230606&doi=10.1038%2fs41598-023-41446-1&partnerID=40&md5=645d83035467e2f057b6e3d938f7719a https://irepository.uniten.edu.my/handle/123456789/33898 13 1 14248 All Open Access Gold Open Access Green Open Access Nature Research Scopus
institution Universiti Tenaga Nasional
building UNITEN Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Tenaga Nasional
content_source UNITEN Institutional Repository
url_provider http://dspace.uniten.edu.my/
topic Automobiles
Biofuels
Biological Transport
Biomass
Cellulose
Eragrostis
biofuel
cellulose
biomass
car
Eragrostis
transport at the cellular level
spellingShingle Automobiles
Biofuels
Biological Transport
Biomass
Cellulose
Eragrostis
biofuel
cellulose
biomass
car
Eragrostis
transport at the cellular level
Shah M.A.
Hayder G.
Kumar R.
Kumar V.
Ahamad T.
Kalam M.A.
Soudagar M.E.M.
Mohamed Shamshuddin S.Z.
Mubarak N.M.
Development of sustainable biomass residues for biofuels applications
description A comprehensive understanding of physiochemical properties, thermal degradation behavior and chemical composition is significant for biomass residues before their thermochemical conversion for energy production. In this investigation, teff straw (TS), coffee husk (CH), corn cob (CC), and sweet sorghum stalk (SSS) residues were characterized to assess their potential applications as value-added bioenergy and chemical products. The thermal degradation behavior of CC, CH, TS and SSS samples is calculated using four different heating rates. The activation energy values ranged from 81.919 to 262.238 and 85.737�212.349 kJ�mol?1 and were generated by the KAS and FWO models and aided in understanding the biomass conversion process into bio-products. The cellulose, hemicellulose, and lignin contents of CC, CH, TS, and SSS were found to be in the ranges of 31.56�41.15%, 23.9�32.02%, and 19.85�25.07%, respectively. The calorific values of the residues ranged from 17.3 to 19.7�MJ/kg, comparable to crude biomass. Scanning electron micrographs revealed agglomerated, irregular, and rough textures, with parallel lines providing nutrient and water transport pathways in all biomass samples. Energy Dispersive X-ray spectra and X-ray diffraction analysis indicated the presence of high carbonaceous material and crystalline nature. FTIR analysis identified prominent band peaks at specific wave numbers. Based on these findings, it can be concluded that these residues hold potential as energy sources for various applications, such as the textile, plastics, paints, automobile, and food additive industries. � 2023, Springer Nature Limited.
author2 57203128051
author_facet 57203128051
Shah M.A.
Hayder G.
Kumar R.
Kumar V.
Ahamad T.
Kalam M.A.
Soudagar M.E.M.
Mohamed Shamshuddin S.Z.
Mubarak N.M.
format Article
author Shah M.A.
Hayder G.
Kumar R.
Kumar V.
Ahamad T.
Kalam M.A.
Soudagar M.E.M.
Mohamed Shamshuddin S.Z.
Mubarak N.M.
author_sort Shah M.A.
title Development of sustainable biomass residues for biofuels applications
title_short Development of sustainable biomass residues for biofuels applications
title_full Development of sustainable biomass residues for biofuels applications
title_fullStr Development of sustainable biomass residues for biofuels applications
title_full_unstemmed Development of sustainable biomass residues for biofuels applications
title_sort development of sustainable biomass residues for biofuels applications
publisher Nature Research
publishDate 2024
_version_ 1814061093582012416
score 13.214268