Temperature dependence on conductivity and thermal properties of a solid polymeric electrolyte of PVC- ZnO- LiClO4

Ionic conductivity of PVC-ZnO-LiClO4 as a function of temperature was studied. The electrolyte samples were prepared by solution casting technique. The ionic conductivity was measured using impedance spectroscopy technique. The temperature dependence on the conductivity of electrolyte was modelled b...

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Main Authors: Rahman M.Y.A., Ahmad A., Mangsor M.R., Wahab S.A.
Other Authors: 55347217400
Format: Article
Published: Elsevier 2023
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spelling my.uniten.dspace-309442023-12-29T15:56:19Z Temperature dependence on conductivity and thermal properties of a solid polymeric electrolyte of PVC- ZnO- LiClO4 Rahman M.Y.A. Ahmad A. Mangsor M.R. Wahab S.A. 55347217400 16306307100 24376838200 24377043100 Glass transition temperature Solid polymeric electrolyte Thermal stability ZnO filler Electrolytes Fillers Glass Glass transition Ionic conductivity Polymeric glass Polymers Polyvinyl chlorides Solid electrolytes Temperature Temperature distribution Thermodynamic stability Zinc oxide Decomposition temperature Filler contents Impedance spectroscopy On conductivities Solid polymeric electrolytes Solution-casting technique Temperature dependence Weight loss Polyelectrolytes Ionic conductivity of PVC-ZnO-LiClO4 as a function of temperature was studied. The electrolyte samples were prepared by solution casting technique. The ionic conductivity was measured using impedance spectroscopy technique. The temperature dependence on the conductivity of electrolyte was modelled by Arhennius and Vogel-Tammann-Fulcher (VTF) equations, respectively. The highest conductivity of the electrolyte of 5.8 � 10-7 S cm-1 was obtained at 90�C. It was found that the glass transition temperature of the electrolyte does not significantly vary with ZnO filler content. The percentage of weight loss of the electrolyte varies with the ZnO filler content. The electrolyte doped with 30 wt% ZnO shows the highest thermal stability with its decomposition temperature of 255�'C. Crown Copyright � 2008 Published by Elsevier B.V. All rights reserved. Final 2023-12-29T07:56:19Z 2023-12-29T07:56:19Z 2008 Article 10.1016/j.physb.2008.05.007 2-s2.0-55349107227 https://www.scopus.com/inward/record.uri?eid=2-s2.0-55349107227&doi=10.1016%2fj.physb.2008.05.007&partnerID=40&md5=ad1ad7deaa5e1fc8a8d26111350c9a64 https://irepository.uniten.edu.my/handle/123456789/30944 403 19-20 3414 3416 Elsevier Scopus
institution Universiti Tenaga Nasional
building UNITEN Library
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country Malaysia
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topic Glass transition temperature
Solid polymeric electrolyte
Thermal stability
ZnO filler
Electrolytes
Fillers
Glass
Glass transition
Ionic conductivity
Polymeric glass
Polymers
Polyvinyl chlorides
Solid electrolytes
Temperature
Temperature distribution
Thermodynamic stability
Zinc oxide
Decomposition temperature
Filler contents
Impedance spectroscopy
On conductivities
Solid polymeric electrolytes
Solution-casting technique
Temperature dependence
Weight loss
Polyelectrolytes
spellingShingle Glass transition temperature
Solid polymeric electrolyte
Thermal stability
ZnO filler
Electrolytes
Fillers
Glass
Glass transition
Ionic conductivity
Polymeric glass
Polymers
Polyvinyl chlorides
Solid electrolytes
Temperature
Temperature distribution
Thermodynamic stability
Zinc oxide
Decomposition temperature
Filler contents
Impedance spectroscopy
On conductivities
Solid polymeric electrolytes
Solution-casting technique
Temperature dependence
Weight loss
Polyelectrolytes
Rahman M.Y.A.
Ahmad A.
Mangsor M.R.
Wahab S.A.
Temperature dependence on conductivity and thermal properties of a solid polymeric electrolyte of PVC- ZnO- LiClO4
description Ionic conductivity of PVC-ZnO-LiClO4 as a function of temperature was studied. The electrolyte samples were prepared by solution casting technique. The ionic conductivity was measured using impedance spectroscopy technique. The temperature dependence on the conductivity of electrolyte was modelled by Arhennius and Vogel-Tammann-Fulcher (VTF) equations, respectively. The highest conductivity of the electrolyte of 5.8 � 10-7 S cm-1 was obtained at 90�C. It was found that the glass transition temperature of the electrolyte does not significantly vary with ZnO filler content. The percentage of weight loss of the electrolyte varies with the ZnO filler content. The electrolyte doped with 30 wt% ZnO shows the highest thermal stability with its decomposition temperature of 255�'C. Crown Copyright � 2008 Published by Elsevier B.V. All rights reserved.
author2 55347217400
author_facet 55347217400
Rahman M.Y.A.
Ahmad A.
Mangsor M.R.
Wahab S.A.
format Article
author Rahman M.Y.A.
Ahmad A.
Mangsor M.R.
Wahab S.A.
author_sort Rahman M.Y.A.
title Temperature dependence on conductivity and thermal properties of a solid polymeric electrolyte of PVC- ZnO- LiClO4
title_short Temperature dependence on conductivity and thermal properties of a solid polymeric electrolyte of PVC- ZnO- LiClO4
title_full Temperature dependence on conductivity and thermal properties of a solid polymeric electrolyte of PVC- ZnO- LiClO4
title_fullStr Temperature dependence on conductivity and thermal properties of a solid polymeric electrolyte of PVC- ZnO- LiClO4
title_full_unstemmed Temperature dependence on conductivity and thermal properties of a solid polymeric electrolyte of PVC- ZnO- LiClO4
title_sort temperature dependence on conductivity and thermal properties of a solid polymeric electrolyte of pvc- zno- liclo4
publisher Elsevier
publishDate 2023
_version_ 1806424049992073216
score 13.222552