Nanocomposite solid polymeric electrolyte of 49% poly(methyl methacrylate)-grafted natural rubber-titanium dioxide-lithium tetrafluoroborate (MG49-TiO 2-LiBF 4)

A nanocomposite polymer electrolyte consisting of 49% poly(methyl methacrylate)-grafted natural rubber (MG49) as a polymer matrix, lithium tetrafluoroborate (LiBF 4) as a dopant salt, and titanium dioxide (TiO 2) as an inert ceramic filler was prepared by solution casting technique. The ceramic fill...

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Main Authors: Low S.P., Ahmad A., Hamzah H., Rahman M.Y.A.
Other Authors: 36448840400
Format: Article
Published: 2023
Subjects:
XRD
TiO
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spelling my.uniten.dspace-303702023-12-29T15:47:07Z Nanocomposite solid polymeric electrolyte of 49% poly(methyl methacrylate)-grafted natural rubber-titanium dioxide-lithium tetrafluoroborate (MG49-TiO 2-LiBF 4) Low S.P. Ahmad A. Hamzah H. Rahman M.Y.A. 36448840400 16306307100 6602504994 55347217400 49% poly(methyl methacrylate)-grafted natural rubber (MG49) Ionic conductivity Morphology Nanocomposite polymer electrolyte (NCPE) XRD Ceramic materials Esters Filled polymers Fillers Grafting (chemical) Ionic conductivity Lithium Morphology Nanocomposites Oxides Polyelectrolytes Rubber Scanning electron microscopy Sol-gel process Titanium Titanium castings Titanium dioxide X ray diffraction 49% poly(methyl methacrylate)-grafted natural rubber (MG49) Alternating current impedance spectroscopy Ceramic fillers Crystalline phase Dopant salt Filler contents In-situ Lithium tetrafluoroborate Nanocomposite polymer electrolyte Nanocomposite polymer electrolyte (NCPE) Nanocomposite solids Optimum value Salt addition Salt concentration SEM analysis Solution-casting technique Tetrafluoroborates TiO XRD XRD analysis Polymer matrix composites A nanocomposite polymer electrolyte consisting of 49% poly(methyl methacrylate)-grafted natural rubber (MG49) as a polymer matrix, lithium tetrafluoroborate (LiBF 4) as a dopant salt, and titanium dioxide (TiO 2) as an inert ceramic filler was prepared by solution casting technique. The ceramic filler, TiO 2, was synthesized in situ by a sol-gel process. The ionic conductivity was investigated by alternating current impedance spectroscopy. X-ray diffraction (XRD) was used to determine the structure of the electrolyte, and its morphology was examined by scanning electron microscopy (SEM). The highest conductivity, 1.4�10 -5 S cm -1 was obtained at 30 wt.% of LiBF4 salt addition with 6 wt.% of TiO 2 filler content. Ionic conductivity was found to increase with the increase of salt concentration. The optimum value of conductivity was found at 6 wt.% of TiO 2. The XRD analysis revealed that the crystalline phase of the polymer host slightly decreased with the addition of salt and filler. The SEM analysis showed that the smoother the surface of the electrolyte, the higher its conductivity. � Springer-Verlag 2011. Final 2023-12-29T07:47:06Z 2023-12-29T07:47:06Z 2011 Article 10.1007/s10008-010-1252-0 2-s2.0-84855538411 https://www.scopus.com/inward/record.uri?eid=2-s2.0-84855538411&doi=10.1007%2fs10008-010-1252-0&partnerID=40&md5=55e62e0d535589cc2ede34c562f8fb24 https://irepository.uniten.edu.my/handle/123456789/30370 15 11/12/2023 2611 2618 Scopus
institution Universiti Tenaga Nasional
building UNITEN Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Tenaga Nasional
content_source UNITEN Institutional Repository
url_provider http://dspace.uniten.edu.my/
topic 49% poly(methyl methacrylate)-grafted natural rubber (MG49)
Ionic conductivity
Morphology
Nanocomposite polymer electrolyte (NCPE)
XRD
Ceramic materials
Esters
Filled polymers
Fillers
Grafting (chemical)
Ionic conductivity
Lithium
Morphology
Nanocomposites
Oxides
Polyelectrolytes
Rubber
Scanning electron microscopy
Sol-gel process
Titanium
Titanium castings
Titanium dioxide
X ray diffraction
49% poly(methyl methacrylate)-grafted natural rubber (MG49)
Alternating current impedance spectroscopy
Ceramic fillers
Crystalline phase
Dopant salt
Filler contents
In-situ
Lithium tetrafluoroborate
Nanocomposite polymer electrolyte
Nanocomposite polymer electrolyte (NCPE)
Nanocomposite solids
Optimum value
Salt addition
Salt concentration
SEM analysis
Solution-casting technique
Tetrafluoroborates
TiO
XRD
XRD analysis
Polymer matrix composites
spellingShingle 49% poly(methyl methacrylate)-grafted natural rubber (MG49)
Ionic conductivity
Morphology
Nanocomposite polymer electrolyte (NCPE)
XRD
Ceramic materials
Esters
Filled polymers
Fillers
Grafting (chemical)
Ionic conductivity
Lithium
Morphology
Nanocomposites
Oxides
Polyelectrolytes
Rubber
Scanning electron microscopy
Sol-gel process
Titanium
Titanium castings
Titanium dioxide
X ray diffraction
49% poly(methyl methacrylate)-grafted natural rubber (MG49)
Alternating current impedance spectroscopy
Ceramic fillers
Crystalline phase
Dopant salt
Filler contents
In-situ
Lithium tetrafluoroborate
Nanocomposite polymer electrolyte
Nanocomposite polymer electrolyte (NCPE)
Nanocomposite solids
Optimum value
Salt addition
Salt concentration
SEM analysis
Solution-casting technique
Tetrafluoroborates
TiO
XRD
XRD analysis
Polymer matrix composites
Low S.P.
Ahmad A.
Hamzah H.
Rahman M.Y.A.
Nanocomposite solid polymeric electrolyte of 49% poly(methyl methacrylate)-grafted natural rubber-titanium dioxide-lithium tetrafluoroborate (MG49-TiO 2-LiBF 4)
description A nanocomposite polymer electrolyte consisting of 49% poly(methyl methacrylate)-grafted natural rubber (MG49) as a polymer matrix, lithium tetrafluoroborate (LiBF 4) as a dopant salt, and titanium dioxide (TiO 2) as an inert ceramic filler was prepared by solution casting technique. The ceramic filler, TiO 2, was synthesized in situ by a sol-gel process. The ionic conductivity was investigated by alternating current impedance spectroscopy. X-ray diffraction (XRD) was used to determine the structure of the electrolyte, and its morphology was examined by scanning electron microscopy (SEM). The highest conductivity, 1.4�10 -5 S cm -1 was obtained at 30 wt.% of LiBF4 salt addition with 6 wt.% of TiO 2 filler content. Ionic conductivity was found to increase with the increase of salt concentration. The optimum value of conductivity was found at 6 wt.% of TiO 2. The XRD analysis revealed that the crystalline phase of the polymer host slightly decreased with the addition of salt and filler. The SEM analysis showed that the smoother the surface of the electrolyte, the higher its conductivity. � Springer-Verlag 2011.
author2 36448840400
author_facet 36448840400
Low S.P.
Ahmad A.
Hamzah H.
Rahman M.Y.A.
format Article
author Low S.P.
Ahmad A.
Hamzah H.
Rahman M.Y.A.
author_sort Low S.P.
title Nanocomposite solid polymeric electrolyte of 49% poly(methyl methacrylate)-grafted natural rubber-titanium dioxide-lithium tetrafluoroborate (MG49-TiO 2-LiBF 4)
title_short Nanocomposite solid polymeric electrolyte of 49% poly(methyl methacrylate)-grafted natural rubber-titanium dioxide-lithium tetrafluoroborate (MG49-TiO 2-LiBF 4)
title_full Nanocomposite solid polymeric electrolyte of 49% poly(methyl methacrylate)-grafted natural rubber-titanium dioxide-lithium tetrafluoroborate (MG49-TiO 2-LiBF 4)
title_fullStr Nanocomposite solid polymeric electrolyte of 49% poly(methyl methacrylate)-grafted natural rubber-titanium dioxide-lithium tetrafluoroborate (MG49-TiO 2-LiBF 4)
title_full_unstemmed Nanocomposite solid polymeric electrolyte of 49% poly(methyl methacrylate)-grafted natural rubber-titanium dioxide-lithium tetrafluoroborate (MG49-TiO 2-LiBF 4)
title_sort nanocomposite solid polymeric electrolyte of 49% poly(methyl methacrylate)-grafted natural rubber-titanium dioxide-lithium tetrafluoroborate (mg49-tio 2-libf 4)
publishDate 2023
_version_ 1806424561173921792
score 13.214268