Nanocomposite solid polymeric electrolyte of 49% poly(methyl methacrylate)-grafted natural rubber-titanium dioxide-lithium tetrafluoroborate (MG49-TiO 2-LiBF 4)
A nanocomposite polymer electrolyte consisting of 49% poly(methyl methacrylate)-grafted natural rubber (MG49) as a polymer matrix, lithium tetrafluoroborate (LiBF 4) as a dopant salt, and titanium dioxide (TiO 2) as an inert ceramic filler was prepared by solution casting technique. The ceramic fill...
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my.uniten.dspace-303702023-12-29T15:47:07Z Nanocomposite solid polymeric electrolyte of 49% poly(methyl methacrylate)-grafted natural rubber-titanium dioxide-lithium tetrafluoroborate (MG49-TiO 2-LiBF 4) Low S.P. Ahmad A. Hamzah H. Rahman M.Y.A. 36448840400 16306307100 6602504994 55347217400 49% poly(methyl methacrylate)-grafted natural rubber (MG49) Ionic conductivity Morphology Nanocomposite polymer electrolyte (NCPE) XRD Ceramic materials Esters Filled polymers Fillers Grafting (chemical) Ionic conductivity Lithium Morphology Nanocomposites Oxides Polyelectrolytes Rubber Scanning electron microscopy Sol-gel process Titanium Titanium castings Titanium dioxide X ray diffraction 49% poly(methyl methacrylate)-grafted natural rubber (MG49) Alternating current impedance spectroscopy Ceramic fillers Crystalline phase Dopant salt Filler contents In-situ Lithium tetrafluoroborate Nanocomposite polymer electrolyte Nanocomposite polymer electrolyte (NCPE) Nanocomposite solids Optimum value Salt addition Salt concentration SEM analysis Solution-casting technique Tetrafluoroborates TiO XRD XRD analysis Polymer matrix composites A nanocomposite polymer electrolyte consisting of 49% poly(methyl methacrylate)-grafted natural rubber (MG49) as a polymer matrix, lithium tetrafluoroborate (LiBF 4) as a dopant salt, and titanium dioxide (TiO 2) as an inert ceramic filler was prepared by solution casting technique. The ceramic filler, TiO 2, was synthesized in situ by a sol-gel process. The ionic conductivity was investigated by alternating current impedance spectroscopy. X-ray diffraction (XRD) was used to determine the structure of the electrolyte, and its morphology was examined by scanning electron microscopy (SEM). The highest conductivity, 1.4�10 -5 S cm -1 was obtained at 30 wt.% of LiBF4 salt addition with 6 wt.% of TiO 2 filler content. Ionic conductivity was found to increase with the increase of salt concentration. The optimum value of conductivity was found at 6 wt.% of TiO 2. The XRD analysis revealed that the crystalline phase of the polymer host slightly decreased with the addition of salt and filler. The SEM analysis showed that the smoother the surface of the electrolyte, the higher its conductivity. � Springer-Verlag 2011. Final 2023-12-29T07:47:06Z 2023-12-29T07:47:06Z 2011 Article 10.1007/s10008-010-1252-0 2-s2.0-84855538411 https://www.scopus.com/inward/record.uri?eid=2-s2.0-84855538411&doi=10.1007%2fs10008-010-1252-0&partnerID=40&md5=55e62e0d535589cc2ede34c562f8fb24 https://irepository.uniten.edu.my/handle/123456789/30370 15 11/12/2023 2611 2618 Scopus |
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49% poly(methyl methacrylate)-grafted natural rubber (MG49) Ionic conductivity Morphology Nanocomposite polymer electrolyte (NCPE) XRD Ceramic materials Esters Filled polymers Fillers Grafting (chemical) Ionic conductivity Lithium Morphology Nanocomposites Oxides Polyelectrolytes Rubber Scanning electron microscopy Sol-gel process Titanium Titanium castings Titanium dioxide X ray diffraction 49% poly(methyl methacrylate)-grafted natural rubber (MG49) Alternating current impedance spectroscopy Ceramic fillers Crystalline phase Dopant salt Filler contents In-situ Lithium tetrafluoroborate Nanocomposite polymer electrolyte Nanocomposite polymer electrolyte (NCPE) Nanocomposite solids Optimum value Salt addition Salt concentration SEM analysis Solution-casting technique Tetrafluoroborates TiO XRD XRD analysis Polymer matrix composites |
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49% poly(methyl methacrylate)-grafted natural rubber (MG49) Ionic conductivity Morphology Nanocomposite polymer electrolyte (NCPE) XRD Ceramic materials Esters Filled polymers Fillers Grafting (chemical) Ionic conductivity Lithium Morphology Nanocomposites Oxides Polyelectrolytes Rubber Scanning electron microscopy Sol-gel process Titanium Titanium castings Titanium dioxide X ray diffraction 49% poly(methyl methacrylate)-grafted natural rubber (MG49) Alternating current impedance spectroscopy Ceramic fillers Crystalline phase Dopant salt Filler contents In-situ Lithium tetrafluoroborate Nanocomposite polymer electrolyte Nanocomposite polymer electrolyte (NCPE) Nanocomposite solids Optimum value Salt addition Salt concentration SEM analysis Solution-casting technique Tetrafluoroborates TiO XRD XRD analysis Polymer matrix composites Low S.P. Ahmad A. Hamzah H. Rahman M.Y.A. Nanocomposite solid polymeric electrolyte of 49% poly(methyl methacrylate)-grafted natural rubber-titanium dioxide-lithium tetrafluoroborate (MG49-TiO 2-LiBF 4) |
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A nanocomposite polymer electrolyte consisting of 49% poly(methyl methacrylate)-grafted natural rubber (MG49) as a polymer matrix, lithium tetrafluoroborate (LiBF 4) as a dopant salt, and titanium dioxide (TiO 2) as an inert ceramic filler was prepared by solution casting technique. The ceramic filler, TiO 2, was synthesized in situ by a sol-gel process. The ionic conductivity was investigated by alternating current impedance spectroscopy. X-ray diffraction (XRD) was used to determine the structure of the electrolyte, and its morphology was examined by scanning electron microscopy (SEM). The highest conductivity, 1.4�10 -5 S cm -1 was obtained at 30 wt.% of LiBF4 salt addition with 6 wt.% of TiO 2 filler content. Ionic conductivity was found to increase with the increase of salt concentration. The optimum value of conductivity was found at 6 wt.% of TiO 2. The XRD analysis revealed that the crystalline phase of the polymer host slightly decreased with the addition of salt and filler. The SEM analysis showed that the smoother the surface of the electrolyte, the higher its conductivity. � Springer-Verlag 2011. |
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36448840400 |
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36448840400 Low S.P. Ahmad A. Hamzah H. Rahman M.Y.A. |
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Low S.P. Ahmad A. Hamzah H. Rahman M.Y.A. |
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title |
Nanocomposite solid polymeric electrolyte of 49% poly(methyl methacrylate)-grafted natural rubber-titanium dioxide-lithium tetrafluoroborate (MG49-TiO 2-LiBF 4) |
title_short |
Nanocomposite solid polymeric electrolyte of 49% poly(methyl methacrylate)-grafted natural rubber-titanium dioxide-lithium tetrafluoroborate (MG49-TiO 2-LiBF 4) |
title_full |
Nanocomposite solid polymeric electrolyte of 49% poly(methyl methacrylate)-grafted natural rubber-titanium dioxide-lithium tetrafluoroborate (MG49-TiO 2-LiBF 4) |
title_fullStr |
Nanocomposite solid polymeric electrolyte of 49% poly(methyl methacrylate)-grafted natural rubber-titanium dioxide-lithium tetrafluoroborate (MG49-TiO 2-LiBF 4) |
title_full_unstemmed |
Nanocomposite solid polymeric electrolyte of 49% poly(methyl methacrylate)-grafted natural rubber-titanium dioxide-lithium tetrafluoroborate (MG49-TiO 2-LiBF 4) |
title_sort |
nanocomposite solid polymeric electrolyte of 49% poly(methyl methacrylate)-grafted natural rubber-titanium dioxide-lithium tetrafluoroborate (mg49-tio 2-libf 4) |
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2023 |
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1806424561173921792 |
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13.214268 |