Solid polymeric electrolyte of PVC-ENR-LiClO4
The ionic conductivity of PVC-ENR-LiClO4 (PVC, polyvinyl chloride; ENR, epoxidized natural rubber) as a function of LiClO4 concentration, ENR concentration, temperature, and radiation dose of electron beam cross-linking has been studied. The electrolyte samples were prepared by solution casting tech...
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my.uniten.dspace-298212023-12-28T16:57:46Z Solid polymeric electrolyte of PVC-ENR-LiClO4 Ahmad A. Rahman M.Y.A. Ali M.L.M. Hashim H. Kalam F.A. 16306307100 55347217400 57199279748 57203416900 16307526500 Electron beam cross-linking Ionic conductivity PVC-ENR-LiClO<sub>4</sub> Solution casting Crosslinking Dosimetry Electron beams Ionic conductivity Polyvinyl chlorides Rubber Thermal conductivity Electrolyte conductivity Electron beam cross-linking Epoxidized natural rubber Solution casting Lithium compounds The ionic conductivity of PVC-ENR-LiClO4 (PVC, polyvinyl chloride; ENR, epoxidized natural rubber) as a function of LiClO4 concentration, ENR concentration, temperature, and radiation dose of electron beam cross-linking has been studied. The electrolyte samples were prepared by solution casting technique. Their ionic conductivities were measured using the impedance spectroscopy technique. It was observed that the relationship between the concentration of salt, as well as temperature, and conductivity were linear. The electrolyte conductivity increases with ENR concentration. This relationship was discussed using the number of charge carrier theory. The conductivity-temperature behaviour of the electrolyte is Arrhenian. The conductivity also varies with the radiation dose of the electron beam cross-linking. The highest room temperature conductivity of the electrolyte of 8.5?�?10-7 S/cm was obtained at 30% by weight of LiClO4. The activation energy, E a and pre-exponential factor, ? o, are 1.4?�?10-2 eV and 1.5?�?10-11 S/cm, respectively. � Springer-Verlag 2007. Final 2023-12-28T08:57:46Z 2023-12-28T08:57:46Z 2007 Article 10.1007/s11581-007-0074-2 2-s2.0-34248366575 https://www.scopus.com/inward/record.uri?eid=2-s2.0-34248366575&doi=10.1007%2fs11581-007-0074-2&partnerID=40&md5=6eec76df87d61e3b13a2d9822552d306 https://irepository.uniten.edu.my/handle/123456789/29821 13 2 67 70 Scopus |
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Electron beam cross-linking Ionic conductivity PVC-ENR-LiClO<sub>4</sub> Solution casting Crosslinking Dosimetry Electron beams Ionic conductivity Polyvinyl chlorides Rubber Thermal conductivity Electrolyte conductivity Electron beam cross-linking Epoxidized natural rubber Solution casting Lithium compounds |
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Electron beam cross-linking Ionic conductivity PVC-ENR-LiClO<sub>4</sub> Solution casting Crosslinking Dosimetry Electron beams Ionic conductivity Polyvinyl chlorides Rubber Thermal conductivity Electrolyte conductivity Electron beam cross-linking Epoxidized natural rubber Solution casting Lithium compounds Ahmad A. Rahman M.Y.A. Ali M.L.M. Hashim H. Kalam F.A. Solid polymeric electrolyte of PVC-ENR-LiClO4 |
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The ionic conductivity of PVC-ENR-LiClO4 (PVC, polyvinyl chloride; ENR, epoxidized natural rubber) as a function of LiClO4 concentration, ENR concentration, temperature, and radiation dose of electron beam cross-linking has been studied. The electrolyte samples were prepared by solution casting technique. Their ionic conductivities were measured using the impedance spectroscopy technique. It was observed that the relationship between the concentration of salt, as well as temperature, and conductivity were linear. The electrolyte conductivity increases with ENR concentration. This relationship was discussed using the number of charge carrier theory. The conductivity-temperature behaviour of the electrolyte is Arrhenian. The conductivity also varies with the radiation dose of the electron beam cross-linking. The highest room temperature conductivity of the electrolyte of 8.5?�?10-7 S/cm was obtained at 30% by weight of LiClO4. The activation energy, E a and pre-exponential factor, ? o, are 1.4?�?10-2 eV and 1.5?�?10-11 S/cm, respectively. � Springer-Verlag 2007. |
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16306307100 |
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16306307100 Ahmad A. Rahman M.Y.A. Ali M.L.M. Hashim H. Kalam F.A. |
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Article |
author |
Ahmad A. Rahman M.Y.A. Ali M.L.M. Hashim H. Kalam F.A. |
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Ahmad A. |
title |
Solid polymeric electrolyte of PVC-ENR-LiClO4 |
title_short |
Solid polymeric electrolyte of PVC-ENR-LiClO4 |
title_full |
Solid polymeric electrolyte of PVC-ENR-LiClO4 |
title_fullStr |
Solid polymeric electrolyte of PVC-ENR-LiClO4 |
title_full_unstemmed |
Solid polymeric electrolyte of PVC-ENR-LiClO4 |
title_sort |
solid polymeric electrolyte of pvc-enr-liclo4 |
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2023 |
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1806427660153257984 |
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13.222552 |