Effects of bismuth oxide on the sinterability of hydroxyapatite

• Main Authors: Ramesh S., Tan C.Y., Yeo W.H., Tolouei R., Amiriyan M., Sopyan I., Teng W.D.
• Other Authors: 41061958200
• Format: Article
• Published: 2023
• Subjects: Bismuth oxide; Fracture toughness; Hydroxyapatite; Relative density; Vickers hardness; Young's modulus; Apatite; Bismuth; Elastic moduli; Elasticity; Fracture; Mechanical properties; Sintering; Bismuth oxides; Low temperatures; Relative bulk density; Sinterability; Sintered samples; Sintering temperatures; Vickers; Young's Modulus

The sinterability of Bi2O3-doped hydroxyapatite (HA) has been studied and compared with the undoped HA. Varying amounts of Bi 2O3 ranging from 0.05 wt% to 1.0 wt% were mixed with the HA. The study revealed that most sintered samples composed of the HA phase except for compacts containing 0.3, 0.5 and 1.0 wt% Bi2O3 and when sintered above 1100 �C, 1000 �C and 950 �C, respectively. In general, the addition of 0.5 wt% Bi2O3 was identified as the optimum amount to promote densification as well as to improve the mechanical properties of sintered HA at low temperature of 1000 �C. Throughout the sintering regime, the highest value of relative bulk density of 98.7% was obtained for 0.5 wt% Bi2O3-doped HA when sintered at 1000 �C. A maximum Young's modulus of 119.2 GPa was measured for 0.1 wt% Bi2O3-doped HA when sintered at 1150 �C. Additionally, the ceramic was able to achieve highest hardness of 6.08 GPa and fracture toughness of 1.21 MPa m1/2 at sintering temperature of 1000 �C. � 2010 Elsevier Ltd and Techna Group S.r.l.