Effects of HfB2 addition on the oxidation resistance, microstructure, and mechanical properties of pressureless sintered ZrB2-SiC composite

Microstructure; Molybdenum compounds; Oxidation resistance; Particle size; Silicon carbide; Vickers hardness; X ray diffraction analysis; Zirconium compounds; Nano-sized particles; Oxidized surfaces; Oxygen penetration; Pressureless-sintered; Reinforcing phase; SiC-based ceramics; Silicon carbides (...

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Main Authors: Mashhadi M., Salimi I.G., Golieskardi M.
Other Authors: 24776823200
Format: Article
Published: Begell House Inc. 2023
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spelling my.uniten.dspace-266022023-05-29T17:12:36Z Effects of HfB2 addition on the oxidation resistance, microstructure, and mechanical properties of pressureless sintered ZrB2-SiC composite Mashhadi M. Salimi I.G. Golieskardi M. 24776823200 57221439232 55866907000 Microstructure; Molybdenum compounds; Oxidation resistance; Particle size; Silicon carbide; Vickers hardness; X ray diffraction analysis; Zirconium compounds; Nano-sized particles; Oxidized surfaces; Oxygen penetration; Pressureless-sintered; Reinforcing phase; SiC-based ceramics; Silicon carbides (SiC); Solid solution formation; Hafnium compounds In order to improve oxidation resistance and mechanical properties of ZrB2-based composites, 10% silicon carbide (SiC) nano-sized particles were used as a reinforcing phase and 4% MoSi2 as a synthesizer aid. In this work, the effects of HfB2 addition (0, 5, 10, 15, 20, and 25%) on Vickers hardness, bulk density, oxidation resistance, and microstructure of the ZrB2-SiC-based ceramics were investigated. The results revealed that the samples consisting of 10% HfB2 have the highest relative density (98.4%). The lowest apparent porosity (i.e., 15%) and the highest hardness (i.e., 15.24 GPa) of the samples were achieved by the addition of 20% HfB2. The X-ray diffraction (XRD) analysis indicated that prolonging the oxidation period resulted in the production of more oxide compounds. The sample containing 25% HfB2 in addition to the lowest relative density due to the oxidized surface erosion and the formation of a poor layer of porous SiC exhibited the maximum oxygen penetration into the sample, the highest gain in mass, and the least oxidation resistance even compared to the ZrB2-SiC composite without the HfB2 addition. It was concluded that by increasing the temperature and time, solid solution formation increases. � 2020 by Begell House, Inc. Final 2023-05-29T09:12:36Z 2023-05-29T09:12:36Z 2021 Article 10.1615/COMPMECHCOMPUTAPPLINTJ.2020030129 2-s2.0-85099140482 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85099140482&doi=10.1615%2fCOMPMECHCOMPUTAPPLINTJ.2020030129&partnerID=40&md5=6e1362bb79ae3b8ef798b4cc87539f27 https://irepository.uniten.edu.my/handle/123456789/26602 11 4 287 308 Begell House Inc. Scopus
institution Universiti Tenaga Nasional
building UNITEN Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Tenaga Nasional
content_source UNITEN Institutional Repository
url_provider http://dspace.uniten.edu.my/
description Microstructure; Molybdenum compounds; Oxidation resistance; Particle size; Silicon carbide; Vickers hardness; X ray diffraction analysis; Zirconium compounds; Nano-sized particles; Oxidized surfaces; Oxygen penetration; Pressureless-sintered; Reinforcing phase; SiC-based ceramics; Silicon carbides (SiC); Solid solution formation; Hafnium compounds
author2 24776823200
author_facet 24776823200
Mashhadi M.
Salimi I.G.
Golieskardi M.
format Article
author Mashhadi M.
Salimi I.G.
Golieskardi M.
spellingShingle Mashhadi M.
Salimi I.G.
Golieskardi M.
Effects of HfB2 addition on the oxidation resistance, microstructure, and mechanical properties of pressureless sintered ZrB2-SiC composite
author_sort Mashhadi M.
title Effects of HfB2 addition on the oxidation resistance, microstructure, and mechanical properties of pressureless sintered ZrB2-SiC composite
title_short Effects of HfB2 addition on the oxidation resistance, microstructure, and mechanical properties of pressureless sintered ZrB2-SiC composite
title_full Effects of HfB2 addition on the oxidation resistance, microstructure, and mechanical properties of pressureless sintered ZrB2-SiC composite
title_fullStr Effects of HfB2 addition on the oxidation resistance, microstructure, and mechanical properties of pressureless sintered ZrB2-SiC composite
title_full_unstemmed Effects of HfB2 addition on the oxidation resistance, microstructure, and mechanical properties of pressureless sintered ZrB2-SiC composite
title_sort effects of hfb2 addition on the oxidation resistance, microstructure, and mechanical properties of pressureless sintered zrb2-sic composite
publisher Begell House Inc.
publishDate 2023
_version_ 1806426467292151808
score 13.18916