(SiO2)100-x-Nix (x = 2.5, 10.0) Composite-based photoanode with polymer gel electrolyte for increased dye-sensitized solar cell performance

Dye-sensitized solar cells; Electron transport properties; Mechanical stability; Nickel; Open circuit voltage; Particle size; Polymer solar cells; Polymerization; Silica; Sol-gel process; Sol-gels; Solar cells; Solid electrolytes; Thin films; Brunauer Emmett Teller analysis; Field emission electron...

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Main Authors: Abdullah H., Zainudin M.K., Ahmad M., Mahalingam S., Manap A.
Other Authors: 26025061200
Format: Article
Published: Institute for Ionics 2023
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spelling my.uniten.dspace-246202023-05-29T15:25:12Z (SiO2)100-x-Nix (x = 2.5, 10.0) Composite-based photoanode with polymer gel electrolyte for increased dye-sensitized solar cell performance Abdullah H. Zainudin M.K. Ahmad M. Mahalingam S. Manap A. 26025061200 57205657943 57194770216 55434075500 57200642155 Dye-sensitized solar cells; Electron transport properties; Mechanical stability; Nickel; Open circuit voltage; Particle size; Polymer solar cells; Polymerization; Silica; Sol-gel process; Sol-gels; Solar cells; Solid electrolytes; Thin films; Brunauer Emmett Teller analysis; Field emission electron microscopy; Gel polymer electrolytes; Polyacrylonitrile (PAN); Polymer gel electrolytes; Power conversion efficiencies; Sol-gel polymerization; Tetra-ethyl-ortho-silicate; Polyelectrolytes This work aims on the degradation performance of (SiO2)100-x-Nix (x = 2.5, 10.0) photoanodes incorporating with liquid and gel polymer electrolyte for dye-sensitized solar cell (DSSC). The silica doped with nickel and gel polymer electrolyte was prepared by sol-gel polymerization of tetraethyl orthosilicate and sol-gel polymerization of polyacrylonitrile (PAN), respectively. The utilization of PAN-based gel polymer electrolyte improved the value of open circuit voltage due to its high ionic conductivity and mechanical stability in DSSC. The (SiO2)90.0-Ni10.0-based DSSC utilizing PAN-based gel polymer electrolyte exhibited the highest power conversion efficiency of 2.96%. The field emission electron microscopy images show larger average particle size with greater porosity in the (SiO2)90.0-Ni10.0 thin film. Moreover, the Brunauer-Emmett-Teller analysis determines greater active surface area on (SiO2)90.0-Ni10.0 thin films that indicates more dye molecules may adsorb on the mesoporous photoanode to facilitate electron transport in the DSSC. � 2019, Springer-Verlag GmbH Germany, part of Springer Nature. Final 2023-05-29T07:25:12Z 2023-05-29T07:25:12Z 2019 Article 10.1007/s11581-019-02886-w 2-s2.0-85060970695 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85060970695&doi=10.1007%2fs11581-019-02886-w&partnerID=40&md5=9ffd8bd2803a680b8d384b32cd70eb64 https://irepository.uniten.edu.my/handle/123456789/24620 25 7 3387 3396 Institute for Ionics Scopus
institution Universiti Tenaga Nasional
building UNITEN Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Tenaga Nasional
content_source UNITEN Institutional Repository
url_provider http://dspace.uniten.edu.my/
description Dye-sensitized solar cells; Electron transport properties; Mechanical stability; Nickel; Open circuit voltage; Particle size; Polymer solar cells; Polymerization; Silica; Sol-gel process; Sol-gels; Solar cells; Solid electrolytes; Thin films; Brunauer Emmett Teller analysis; Field emission electron microscopy; Gel polymer electrolytes; Polyacrylonitrile (PAN); Polymer gel electrolytes; Power conversion efficiencies; Sol-gel polymerization; Tetra-ethyl-ortho-silicate; Polyelectrolytes
author2 26025061200
author_facet 26025061200
Abdullah H.
Zainudin M.K.
Ahmad M.
Mahalingam S.
Manap A.
format Article
author Abdullah H.
Zainudin M.K.
Ahmad M.
Mahalingam S.
Manap A.
spellingShingle Abdullah H.
Zainudin M.K.
Ahmad M.
Mahalingam S.
Manap A.
(SiO2)100-x-Nix (x = 2.5, 10.0) Composite-based photoanode with polymer gel electrolyte for increased dye-sensitized solar cell performance
author_sort Abdullah H.
title (SiO2)100-x-Nix (x = 2.5, 10.0) Composite-based photoanode with polymer gel electrolyte for increased dye-sensitized solar cell performance
title_short (SiO2)100-x-Nix (x = 2.5, 10.0) Composite-based photoanode with polymer gel electrolyte for increased dye-sensitized solar cell performance
title_full (SiO2)100-x-Nix (x = 2.5, 10.0) Composite-based photoanode with polymer gel electrolyte for increased dye-sensitized solar cell performance
title_fullStr (SiO2)100-x-Nix (x = 2.5, 10.0) Composite-based photoanode with polymer gel electrolyte for increased dye-sensitized solar cell performance
title_full_unstemmed (SiO2)100-x-Nix (x = 2.5, 10.0) Composite-based photoanode with polymer gel electrolyte for increased dye-sensitized solar cell performance
title_sort (sio2)100-x-nix (x = 2.5, 10.0) composite-based photoanode with polymer gel electrolyte for increased dye-sensitized solar cell performance
publisher Institute for Ionics
publishDate 2023
_version_ 1806428128320421888
score 13.214268