Synthesis and characterizations of MOF-199 using PODFA as porogen for CO2 adsorption applications
Alcohols; Carbon dioxide; Copper oxides; Crystalline materials; Morphology; Organometallics; Particle size analysis; X ray diffraction analysis; CO2 sorption; Environmental-friendly; High-temperature synthesis; Metal organic framework; Microporous; Mof-199; Structure directing agents; Synthesis and...
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Trans Tech Publications Ltd
2023
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my.uniten.dspace-229642023-05-29T14:13:46Z Synthesis and characterizations of MOF-199 using PODFA as porogen for CO2 adsorption applications Mahadi N. Misran H. Othman S.Z. 57189241140 6506899840 55548997100 Alcohols; Carbon dioxide; Copper oxides; Crystalline materials; Morphology; Organometallics; Particle size analysis; X ray diffraction analysis; CO2 sorption; Environmental-friendly; High-temperature synthesis; Metal organic framework; Microporous; Mof-199; Structure directing agents; Synthesis and characterizations; Palm oil Copper-based metal-organic framework (MOF-199, also known as Cu-BTC and HKUST-1) materials were successfully synthesized by hydrothermal method using renewable straight-chain fatty alcohol with eight carbon chain length (i.e. octyl alcohol). The addition of palm oil derived fatty alcohol (PODFA) was suggested to act as porogen (structure directing agent) that aided the particle formation and flexible porous structure. This synthesis approach was environmental-friendly and sustainable by utilizing the fatty alcohols originated from biomass such as palm oil. The resulting MOF-199 materials exhibited single crystalline octahedral morphology structure by X-ray diffraction analyses and SEM images. The optimum ratio of octyl alcohol exhibited well-defined single octahedral particles at size range of ca. 10-50 ?m and reduced byproduct formation of cuprous oxide at high temperature synthesis. The nature of MOF-199 having apparently high surface area, high pore volume and low density provided the possibility in carbon capture storage. The CO2 adsorption capacity of MOF-199 investigated using high pressure volumetric analyser (HPVA-II) at ambient temperature (i.e. 25 �C) was found to be at maximum working capacity. � 2016 Trans Tech Publications, Switzerland. Final 2023-05-29T06:13:46Z 2023-05-29T06:13:46Z 2016 Conference Paper 10.4028/www.scientific.net/KEM.694.44 2-s2.0-84974686988 https://www.scopus.com/inward/record.uri?eid=2-s2.0-84974686988&doi=10.4028%2fwww.scientific.net%2fKEM.694.44&partnerID=40&md5=284fc0677d05f3c65b7f3cbd5be686ab https://irepository.uniten.edu.my/handle/123456789/22964 694 44 49 Trans Tech Publications Ltd Scopus |
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| description |
Alcohols; Carbon dioxide; Copper oxides; Crystalline materials; Morphology; Organometallics; Particle size analysis; X ray diffraction analysis; CO2 sorption; Environmental-friendly; High-temperature synthesis; Metal organic framework; Microporous; Mof-199; Structure directing agents; Synthesis and characterizations; Palm oil |
| author2 |
57189241140 |
| author_facet |
57189241140 Mahadi N. Misran H. Othman S.Z. |
| format |
Conference Paper |
| author |
Mahadi N. Misran H. Othman S.Z. |
| spellingShingle |
Mahadi N. Misran H. Othman S.Z. Synthesis and characterizations of MOF-199 using PODFA as porogen for CO2 adsorption applications |
| author_sort |
Mahadi N. |
| title |
Synthesis and characterizations of MOF-199 using PODFA as porogen for CO2 adsorption applications |
| title_short |
Synthesis and characterizations of MOF-199 using PODFA as porogen for CO2 adsorption applications |
| title_full |
Synthesis and characterizations of MOF-199 using PODFA as porogen for CO2 adsorption applications |
| title_fullStr |
Synthesis and characterizations of MOF-199 using PODFA as porogen for CO2 adsorption applications |
| title_full_unstemmed |
Synthesis and characterizations of MOF-199 using PODFA as porogen for CO2 adsorption applications |
| title_sort |
synthesis and characterizations of mof-199 using podfa as porogen for co2 adsorption applications |
| publisher |
Trans Tech Publications Ltd |
| publishDate |
2023 |
| _version_ |
1806424145900077056 |
| score |
13.214268 |