Room Temperature Synthesis and Characterizations of ZIF-8 Formation at Water-Fatty Alcohols Interface
In this study, Zn based ZIF-8 metal-organic framework were successfully synthesized in a green synthesis approach eliminating hazardous solvents and the need to use surfactant. In this method, the syntheses were done at room temperature followed by a simple hydrothermal method using palm oil derived...
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my.uniten.dspace-108182018-11-22T03:41:10Z Room Temperature Synthesis and Characterizations of ZIF-8 Formation at Water-Fatty Alcohols Interface Halina Misran A. Matsumoto N. Amin Z. Lockman Siti Zubaidah Othman N. Mahadi In this study, Zn based ZIF-8 metal-organic framework were successfully synthesized in a green synthesis approach eliminating hazardous solvents and the need to use surfactant. In this method, the syntheses were done at room temperature followed by a simple hydrothermal method using palm oil derived fatty alcohols (PODFA) with 12 carbon chain in various solvents. The effect of several co-solvents on the formation of ZIF-8 materials and on morphology were investigated. The peak positions agreed well with the simulated ZIF-8. However, as the co-solvents became more polar the (011) peak shifted to a higher 2θ value suggesting that the interplanar d-spacing were reduced. The addition of fatty alcohols promoted the formation of MOF-5 and ZIF-8 at the water-fatty alcohols interfaces by viscosity lowering effect similar to those when using commercial surfactants. The mechanism of the formation was suggested to be similar to those at water-alcohol insoluble monolayer interfaces at the liquid-gas interaction. As the polarity of solvents increased, the miscibility of Zn2+ ions and deprotonated methylimidazole linkers were enhanced causing higher interaction with metal ions which resulted in a smaller unit cell. ZIF-8 exhibited elongated rhombic dodecahedron and truncated dodecahedron morphology at less than 100 nm. 2018-11-22T03:41:10Z 2018-11-22T03:41:10Z 2018 Article http://dspace.uniten.edu.my/jspui/handle/123456789/10818 10.1088/1742-6596/1082/1/012046 en |
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In this study, Zn based ZIF-8 metal-organic framework were successfully synthesized in a green synthesis approach eliminating hazardous solvents and the need to use surfactant. In this method, the syntheses were done at room temperature followed by a simple hydrothermal method using palm oil derived fatty alcohols (PODFA) with 12 carbon chain in various solvents. The effect of several co-solvents on the formation of ZIF-8 materials and on morphology were investigated. The peak positions agreed well with the simulated ZIF-8. However, as the co-solvents became more polar the (011) peak shifted to a higher 2θ value suggesting that the interplanar d-spacing were reduced. The addition of fatty alcohols promoted the formation of MOF-5 and ZIF-8 at the water-fatty alcohols interfaces by viscosity lowering effect similar to those when using commercial surfactants. The mechanism of the formation was suggested to be similar to those at water-alcohol insoluble monolayer interfaces at the liquid-gas interaction. As the polarity of solvents increased, the miscibility of Zn2+ ions and deprotonated methylimidazole linkers were enhanced causing higher interaction with metal ions which resulted in a smaller unit cell. ZIF-8 exhibited elongated rhombic dodecahedron and truncated dodecahedron morphology at less than 100 nm. |
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Article |
author |
Halina Misran A. Matsumoto N. Amin Z. Lockman Siti Zubaidah Othman N. Mahadi |
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Halina Misran A. Matsumoto N. Amin Z. Lockman Siti Zubaidah Othman N. Mahadi Room Temperature Synthesis and Characterizations of ZIF-8 Formation at Water-Fatty Alcohols Interface |
author_facet |
Halina Misran A. Matsumoto N. Amin Z. Lockman Siti Zubaidah Othman N. Mahadi |
author_sort |
Halina Misran |
title |
Room Temperature Synthesis and Characterizations of ZIF-8 Formation at Water-Fatty Alcohols Interface |
title_short |
Room Temperature Synthesis and Characterizations of ZIF-8 Formation at Water-Fatty Alcohols Interface |
title_full |
Room Temperature Synthesis and Characterizations of ZIF-8 Formation at Water-Fatty Alcohols Interface |
title_fullStr |
Room Temperature Synthesis and Characterizations of ZIF-8 Formation at Water-Fatty Alcohols Interface |
title_full_unstemmed |
Room Temperature Synthesis and Characterizations of ZIF-8 Formation at Water-Fatty Alcohols Interface |
title_sort |
room temperature synthesis and characterizations of zif-8 formation at water-fatty alcohols interface |
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2018 |
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http://dspace.uniten.edu.my/jspui/handle/123456789/10818 |
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1644495035796815872 |
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13.160551 |