Oxidative addition of (bromoethynyl) benzene to κ 2-acetylacetonatobis (trimethylphosphine) rhodium (I)

The reaction of (bromoethynyl)benzene with κ2-acetylacetonatobis(trimethylphosphine)rhodium(I), [Rh(acac)(PMe3)2] 1, was followed by in situ1H and 31P NMR spectroscopy. The kinetic product is that of cis-oxidative addition of the C–Br bond to Rh, and this species rearranges to the thermodynamically...

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Main Authors: Marie-Hélèn, Thibault, Meng Guan, Tay, Andrei S, Batsanov, Judith AK, Howard, Todd B, Marder
Format: E-Article
Published: Elsevier 2013
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Online Access:http://ir.unimas.my/id/eprint/7403/
http://www.sciencedirect.com/science/article/pii/S0022328X12006778
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