A highly photoresponsive and efficient molybdenum‑modified titanium dioxide photocatalyst for the degradation of methyl orange
The degradation of azo dyes in aquatic environments is still challenging due to their stability and perpetual effect. This work demonstrates the application of highly ultraviolet-responsive titanium dioxide/molybdenum photocatalyst to degrade methyl orange. A series of titanium dioxide/molybdenum...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Springer
2021
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| Subjects: | |
| Online Access: | http://ir.unimas.my/id/eprint/35511/1/Devagi_IJEST%20Jun%202021%20Abstract.pdf http://ir.unimas.my/id/eprint/35511/ https://link.springer.com/article/10.1007%2Fs13762-021-03484-y https://doi.org/10.1007/s13762-021-03484-y |
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| Summary: | The degradation of azo dyes in aquatic environments is still challenging due to their stability and perpetual effect. This work
demonstrates the application of highly ultraviolet-responsive titanium dioxide/molybdenum photocatalyst to degrade methyl
orange. A series of titanium dioxide/molybdenum photocatalyst with different molybdenum concentrations (1–10 wt%) were
synthesized by a facile wet impregnation method. The introduction of molybdenum has favorably induced changes in surface
morphology, crystallite size, optical absorption, and specific surface area, which have collectively enhanced the photocatalytic
performance of titanium dioxide/molybdenum photocatalyst on the removal of methyl orange. A systematic investigation on
the influencing parameters such as photocatalyst dosage, initial methyl orange concentration, and initial pH was investigated,
and the optimum conditions were achieved. The best-performing titanium dioxide/molybdenum (3 wt%) photocatalyst yielded
a 94.5% methyl orange photodegradation efficiency within 120 min of irradiation. The dopant concentration, photocatalyst
dosage, and pH were investigated to validate the optimized conditions for titanium dioxide/molybdenum on methyl orange
removal using response surface methodology via the Box–Behnken design. The present results demonstrated that both the
superoxide radical and hydroxyl radical play a primary role in the degradation mechanism. This study provides fresh insight
that the successful structural modification of titanium dioxide by molybdenum could enhance the photocatalytic removal
of dye wastewater. |
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