Synthesis and Characterization of Molecularly Imprinted Polymer for the Removal/Extraction of Thymol from Spiked Blood Serum and River water
Molecularly imprinted polymers (MIPs) were prepared by precipitation polymerization using thymol as a template molecule, acrylamide as a functional monomer and N,N-methylbisacrylamide as the crosslinker with a non-covalent approach. The polymers were characterized by scanning electron microscopy (S...
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my.unimas.ir.296612021-04-23T00:07:00Z http://ir.unimas.my/id/eprint/29661/ Synthesis and Characterization of Molecularly Imprinted Polymer for the Removal/Extraction of Thymol from Spiked Blood Serum and River water Bhawani, Showkat Ahmad Salma, Bakhtiar Syed Rizwan, Shafqat QD Chemistry Molecularly imprinted polymers (MIPs) were prepared by precipitation polymerization using thymol as a template molecule, acrylamide as a functional monomer and N,N-methylbisacrylamide as the crosslinker with a non-covalent approach. The polymers were characterized by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), fourier-transform infra red spectroscopy(FT-IR) and Brunauer-Emmett-Teller (BET). The SEM results depicted that the shape of polymer particles is spherical with uniform size (micrometers). The BET results also showed better surface area, pore size and pore volume of MIP as compared to non-imprinted polymer (NIP). A series of parameters such as initial concentration, polymer dosage, effect of pH and slectivity with structural analogue were conducted. The selectivity of MIP towards thymol was appreciable as compared to its structural analogue gallic acid with a relative selectivity coefficient of 3.59. Finally, MIP has been successfully used for extraction of thymol from the spiked blood serum (84 %) and river water sample (98 %). Asian Publication Corporation 2019 Article PeerReviewed text en http://ir.unimas.my/id/eprint/29661/1/SALMA%20BAKHTIAR.pdf Bhawani, Showkat Ahmad and Salma, Bakhtiar and Syed Rizwan, Shafqat (2019) Synthesis and Characterization of Molecularly Imprinted Polymer for the Removal/Extraction of Thymol from Spiked Blood Serum and River water. Asian Journal of Chemistry, 31 (11). pp. 2479-2484. ISSN 0975-427X http://www.asianjournalofchemistry.co.in/user/journal/viewarticle.aspx?ArticleID=31_11_12 DOI: 10.14233/ajchem.2019.22151 |
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QD Chemistry Bhawani, Showkat Ahmad Salma, Bakhtiar Syed Rizwan, Shafqat Synthesis and Characterization of Molecularly Imprinted Polymer for the Removal/Extraction of Thymol from Spiked Blood Serum and River water |
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Molecularly imprinted polymers (MIPs) were prepared by precipitation polymerization using thymol as a template molecule, acrylamide as a functional monomer and N,N-methylbisacrylamide as the crosslinker with a non-covalent approach. The polymers were characterized
by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), fourier-transform infra red spectroscopy(FT-IR) and Brunauer-Emmett-Teller (BET). The SEM results depicted that the shape of polymer particles is spherical with uniform size (micrometers). The BET results also showed better surface area, pore size and pore volume of MIP as compared to non-imprinted polymer
(NIP). A series of parameters such as initial concentration, polymer dosage, effect of pH and slectivity with structural analogue were conducted. The selectivity of MIP towards thymol was appreciable as compared to its structural analogue gallic acid with a relative selectivity coefficient of 3.59. Finally, MIP has been successfully used for extraction of thymol from the spiked blood serum (84 %) and river water sample (98 %). |
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Article |
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Bhawani, Showkat Ahmad Salma, Bakhtiar Syed Rizwan, Shafqat |
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Bhawani, Showkat Ahmad Salma, Bakhtiar Syed Rizwan, Shafqat |
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Bhawani, Showkat Ahmad |
title |
Synthesis and Characterization of Molecularly Imprinted Polymer for the Removal/Extraction of Thymol from Spiked Blood Serum and River water |
title_short |
Synthesis and Characterization of Molecularly Imprinted Polymer for the Removal/Extraction of Thymol from Spiked Blood Serum and River water |
title_full |
Synthesis and Characterization of Molecularly Imprinted Polymer for the Removal/Extraction of Thymol from Spiked Blood Serum and River water |
title_fullStr |
Synthesis and Characterization of Molecularly Imprinted Polymer for the Removal/Extraction of Thymol from Spiked Blood Serum and River water |
title_full_unstemmed |
Synthesis and Characterization of Molecularly Imprinted Polymer for the Removal/Extraction of Thymol from Spiked Blood Serum and River water |
title_sort |
synthesis and characterization of molecularly imprinted polymer for the removal/extraction of thymol from spiked blood serum and river water |
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Asian Publication Corporation |
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2019 |
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http://ir.unimas.my/id/eprint/29661/1/SALMA%20BAKHTIAR.pdf http://ir.unimas.my/id/eprint/29661/ http://www.asianjournalofchemistry.co.in/user/journal/viewarticle.aspx?ArticleID=31_11_12 |
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