Carbon precursor analysis for catalytic growth of carbon nanotube in flame synthesis based on semi-empirical approach
Although fame synthesis promises economic beneft and rapid synthesis of carbon nanotube (CNT), the lack of control and understanding of the efects of fame parameters (e.g., temperature and precursor composition) impose some challenges in modelling and identifying CNT growth region for obtaining bett...
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Springer Nature Switzerland
2020
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Online Access: | http://ir.unimas.my/id/eprint/29306/1/Carbon%20precursor%20analysis%20for%20catalytic%20growth%20of%20carbon%20nanotube%20in%20flame%20synthesis%20-%20Copy.pdf http://ir.unimas.my/id/eprint/29306/ https://www.springer.com/journal/42823 |
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my.unimas.ir.293062021-03-30T04:06:05Z http://ir.unimas.my/id/eprint/29306/ Carbon precursor analysis for catalytic growth of carbon nanotube in flame synthesis based on semi-empirical approach Khairul Fikri, Tamrin Muhammad Thalhah, Zainal Mohd Fairus, Mohd Yasin Wan Fahmin Faiz, Wan Ali Mohd Hanafi, Ani TJ Mechanical engineering and machinery Although fame synthesis promises economic beneft and rapid synthesis of carbon nanotube (CNT), the lack of control and understanding of the efects of fame parameters (e.g., temperature and precursor composition) impose some challenges in modelling and identifying CNT growth region for obtaining better throughput. The present study presents an investigation on the types of carbon precursor that afect CNT growth region on nickel catalyst particles in an ethylene inverse difusion fame. An established CNT growth rate model that describes physical growth of CNT is utilised to predict CNT length and growth region using empirical inputs of fame temperature and species composition from the literature. Two variations of the model are employed to determine the dominant precursor for CNT growth which are the constant adsorption activation energy (CAAE) model and the varying adsorption activation energy (VAAE) model. The carbon precursors investigated include ethylene, acetylene, and carbon monoxide as base precursors and all possible combinations of the base precursors. In the CAAE model, the activation energy for adsorption of carbon precursor species on catalyst surface Ea,1 is held constant whereas in the VAAE model, Ea,1 is varied based on the investigated precursor. The sensitivity of the growth rate model is demonstrated by comparing the shifting of predicted growth regions between the CAAE model and the VAAE model where the CAAE model serves as a control case. Midpoint-based and threshold-based techniques are employed within each model to quantify the predicted CNT growth region. Growth region prediction based on the midpoint-VAAE approach demonstrates the importance of acetylene and carbon monoxide to some extent towards CNT growth. Ultimately, the threshold-VAAE model shows that the dominant precursor for CNT growth is the mixture of acetylene and carbon monoxide. A simplifed reaction mechanism is proposed to describe the surface chemistry for precursor reactions with nickel catalyst where decomposition of the ethylene fuel source into acetylene and carbon monoxide is accounted for by chemisorption. Springer Nature Switzerland 2020-02 Article PeerReviewed text en http://ir.unimas.my/id/eprint/29306/1/Carbon%20precursor%20analysis%20for%20catalytic%20growth%20of%20carbon%20nanotube%20in%20flame%20synthesis%20-%20Copy.pdf Khairul Fikri, Tamrin and Muhammad Thalhah, Zainal and Mohd Fairus, Mohd Yasin and Wan Fahmin Faiz, Wan Ali and Mohd Hanafi, Ani (2020) Carbon precursor analysis for catalytic growth of carbon nanotube in flame synthesis based on semi-empirical approach. Carbon Letters, 31 (1). pp. 1-10. ISSN 2233-4998 https://www.springer.com/journal/42823 DOI:org.10.1007/s42823-020-00127-z |
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TJ Mechanical engineering and machinery Khairul Fikri, Tamrin Muhammad Thalhah, Zainal Mohd Fairus, Mohd Yasin Wan Fahmin Faiz, Wan Ali Mohd Hanafi, Ani Carbon precursor analysis for catalytic growth of carbon nanotube in flame synthesis based on semi-empirical approach |
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Although fame synthesis promises economic beneft and rapid synthesis of carbon nanotube (CNT), the lack of control and understanding of the efects of fame parameters (e.g., temperature and precursor composition) impose some challenges in modelling and identifying CNT growth region for obtaining better throughput. The present study presents an investigation on the types of carbon precursor that afect CNT growth region on nickel catalyst particles in an ethylene inverse difusion fame. An established CNT growth rate model that describes physical growth of CNT is utilised to predict CNT length and growth region using empirical inputs of fame temperature and species composition from the literature. Two variations of the model are employed to determine the dominant precursor for CNT growth which are the constant adsorption activation energy (CAAE) model and the varying adsorption activation energy (VAAE) model. The carbon precursors investigated include ethylene, acetylene, and carbon monoxide as base precursors and all possible combinations of the base precursors. In the CAAE model, the activation energy for adsorption of carbon precursor species on catalyst surface Ea,1 is held constant whereas in the VAAE model, Ea,1 is varied based on the investigated precursor. The sensitivity of the growth rate model is demonstrated by comparing the shifting of predicted growth regions between the CAAE model and the VAAE model where the CAAE model serves as a control case. Midpoint-based and threshold-based techniques are employed within each model to quantify the predicted CNT growth region. Growth region prediction based on the midpoint-VAAE approach demonstrates the importance of acetylene and carbon monoxide to some extent towards CNT growth. Ultimately, the threshold-VAAE model shows that the dominant precursor for CNT growth is the mixture of acetylene and carbon monoxide. A simplifed reaction mechanism is proposed to describe the surface chemistry for precursor reactions with nickel catalyst where decomposition of the ethylene fuel source into acetylene and carbon monoxide is accounted for by chemisorption. |
format |
Article |
author |
Khairul Fikri, Tamrin Muhammad Thalhah, Zainal Mohd Fairus, Mohd Yasin Wan Fahmin Faiz, Wan Ali Mohd Hanafi, Ani |
author_facet |
Khairul Fikri, Tamrin Muhammad Thalhah, Zainal Mohd Fairus, Mohd Yasin Wan Fahmin Faiz, Wan Ali Mohd Hanafi, Ani |
author_sort |
Khairul Fikri, Tamrin |
title |
Carbon precursor analysis for catalytic growth of carbon nanotube in flame synthesis based on semi-empirical approach |
title_short |
Carbon precursor analysis for catalytic growth of carbon nanotube in flame synthesis based on semi-empirical approach |
title_full |
Carbon precursor analysis for catalytic growth of carbon nanotube in flame synthesis based on semi-empirical approach |
title_fullStr |
Carbon precursor analysis for catalytic growth of carbon nanotube in flame synthesis based on semi-empirical approach |
title_full_unstemmed |
Carbon precursor analysis for catalytic growth of carbon nanotube in flame synthesis based on semi-empirical approach |
title_sort |
carbon precursor analysis for catalytic growth of carbon nanotube in flame synthesis based on semi-empirical approach |
publisher |
Springer Nature Switzerland |
publishDate |
2020 |
url |
http://ir.unimas.my/id/eprint/29306/1/Carbon%20precursor%20analysis%20for%20catalytic%20growth%20of%20carbon%20nanotube%20in%20flame%20synthesis%20-%20Copy.pdf http://ir.unimas.my/id/eprint/29306/ https://www.springer.com/journal/42823 |
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1696979504895885312 |
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13.2014675 |