Treatability ofTropical Wood Using Newly Synthesized Organotin(IV) Complexes

The treatability ofthree tropical wood species namely Alstonia scholar is (pulai), Macaranga triloba (mahang) and Hevea brasiliensis (rubberwood) was investigated Wood species were chemically treated with five newly synthesized organotin(lV) complexes using full-cell treatment method This study ex...

Full description

Saved in:
Bibliographic Details
Main Authors: Jusoh, Ismail, Rahman, Md. Masudur, Affan, Md. Abu, Hamdan, Sinin, Salam, Md. Abdus
Format: E-Article
Language:English
Published: Journal of Applied Sciences 2012
Subjects:
Online Access:http://ir.unimas.my/id/eprint/2385/1/Treatability%20ofTropical%20Wood%20Using%20Newly%20Synthesized%20Organotin%28IV%29%20Complexes.pdf
http://ir.unimas.my/id/eprint/2385/
http://scialert.net/abstract/?doi=jas.2012.535.543
Tags: Add Tag
No Tags, Be the first to tag this record!
id my.unimas.ir.2385
record_format eprints
spelling my.unimas.ir.23852015-09-23T02:06:53Z http://ir.unimas.my/id/eprint/2385/ Treatability ofTropical Wood Using Newly Synthesized Organotin(IV) Complexes Jusoh, Ismail Rahman, Md. Masudur Affan, Md. Abu Hamdan, Sinin Salam, Md. Abdus AC Collections. Series. Collected works The treatability ofthree tropical wood species namely Alstonia scholar is (pulai), Macaranga triloba (mahang) and Hevea brasiliensis (rubberwood) was investigated Wood species were chemically treated with five newly synthesized organotin(lV) complexes using full-cell treatment method This study explored whether tropical wood species could be treated successfully with newly synthesized organotin(IV) complexes as wood preservatives. Ten 19x19x19 mm sized wood cubes of each species were treated with three levels of concentration (0.1, 0.5 and 1 %) ofmono me thyltin (IV) (MMI') andmonophenyltin(IV) (MPT) ofmono series and dimethyltin(IV) (DMT), diphenyltin(IV) (DPT) and dibulyltin(IV) (DBT) ofdiseries organotin(IV) complexes with 2-acetylpyridine-N (4)-cyclohexyl thiosemicarbazone ligand The treated wood species were evaluated by chemical retention values and characterized by FT -IR (Fourier Transform Infrared) spectroscopy analysis. The highest retention (10.59 kg m-1) was found in Alstonia scholaris treated with 1% DMT complexes and the lowest retention (0.47 kg m -') was found inHevea brasiliensis treated with OJ % DMT complexes. FT -IR spectra oftreated wood showed new absorption bands in the range of 594-606 and 441-457 em-I due to Sn-C and Sn-N bonds, respectively. A newly formed absorption band at range 549-569 cm-1 due to Sn-O band was also observed in the treated wood sample spectra. Chemical retention and FTIR spectra suggest tropical wood species are treatable with newly synthesized organotin(IV) complexes as wood preservatives. Journal of Applied Sciences 2012 E-Article NonPeerReviewed text en http://ir.unimas.my/id/eprint/2385/1/Treatability%20ofTropical%20Wood%20Using%20Newly%20Synthesized%20Organotin%28IV%29%20Complexes.pdf Jusoh, Ismail and Rahman, Md. Masudur and Affan, Md. Abu and Hamdan, Sinin and Salam, Md. Abdus (2012) Treatability ofTropical Wood Using Newly Synthesized Organotin(IV) Complexes. Journal of Applied Sciences 12 (6): 535-543,2012, 12 (6). pp. 535-543. http://scialert.net/abstract/?doi=jas.2012.535.543 DOl: 10.3923/jas.20l2.535.543
institution Universiti Malaysia Sarawak
building Centre for Academic Information Services (CAIS)
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Sarawak
content_source UNIMAS Institutional Repository
url_provider http://ir.unimas.my/
language English
topic AC Collections. Series. Collected works
spellingShingle AC Collections. Series. Collected works
Jusoh, Ismail
Rahman, Md. Masudur
Affan, Md. Abu
Hamdan, Sinin
Salam, Md. Abdus
Treatability ofTropical Wood Using Newly Synthesized Organotin(IV) Complexes
description The treatability ofthree tropical wood species namely Alstonia scholar is (pulai), Macaranga triloba (mahang) and Hevea brasiliensis (rubberwood) was investigated Wood species were chemically treated with five newly synthesized organotin(lV) complexes using full-cell treatment method This study explored whether tropical wood species could be treated successfully with newly synthesized organotin(IV) complexes as wood preservatives. Ten 19x19x19 mm sized wood cubes of each species were treated with three levels of concentration (0.1, 0.5 and 1 %) ofmono me thyltin (IV) (MMI') andmonophenyltin(IV) (MPT) ofmono series and dimethyltin(IV) (DMT), diphenyltin(IV) (DPT) and dibulyltin(IV) (DBT) ofdiseries organotin(IV) complexes with 2-acetylpyridine-N (4)-cyclohexyl thiosemicarbazone ligand The treated wood species were evaluated by chemical retention values and characterized by FT -IR (Fourier Transform Infrared) spectroscopy analysis. The highest retention (10.59 kg m-1) was found in Alstonia scholaris treated with 1% DMT complexes and the lowest retention (0.47 kg m -') was found inHevea brasiliensis treated with OJ % DMT complexes. FT -IR spectra oftreated wood showed new absorption bands in the range of 594-606 and 441-457 em-I due to Sn-C and Sn-N bonds, respectively. A newly formed absorption band at range 549-569 cm-1 due to Sn-O band was also observed in the treated wood sample spectra. Chemical retention and FTIR spectra suggest tropical wood species are treatable with newly synthesized organotin(IV) complexes as wood preservatives.
format E-Article
author Jusoh, Ismail
Rahman, Md. Masudur
Affan, Md. Abu
Hamdan, Sinin
Salam, Md. Abdus
author_facet Jusoh, Ismail
Rahman, Md. Masudur
Affan, Md. Abu
Hamdan, Sinin
Salam, Md. Abdus
author_sort Jusoh, Ismail
title Treatability ofTropical Wood Using Newly Synthesized Organotin(IV) Complexes
title_short Treatability ofTropical Wood Using Newly Synthesized Organotin(IV) Complexes
title_full Treatability ofTropical Wood Using Newly Synthesized Organotin(IV) Complexes
title_fullStr Treatability ofTropical Wood Using Newly Synthesized Organotin(IV) Complexes
title_full_unstemmed Treatability ofTropical Wood Using Newly Synthesized Organotin(IV) Complexes
title_sort treatability oftropical wood using newly synthesized organotin(iv) complexes
publisher Journal of Applied Sciences
publishDate 2012
url http://ir.unimas.my/id/eprint/2385/1/Treatability%20ofTropical%20Wood%20Using%20Newly%20Synthesized%20Organotin%28IV%29%20Complexes.pdf
http://ir.unimas.my/id/eprint/2385/
http://scialert.net/abstract/?doi=jas.2012.535.543
_version_ 1644509083298955264
score 13.159267