Synthesis of molecular imprinting polymers for extraction of gallic acid from urine
The molecularly imprinted polymers for gallic acid were synthesized by precipitation polymerization. During the process of synthesis a non-covalent approach was used for the interaction of template and monomer. In the polymerization process, gallic acid was used as a template, acrylic acid as a func...
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my.unimas.ir.198152021-05-03T14:17:30Z http://ir.unimas.my/id/eprint/19815/ Synthesis of molecular imprinting polymers for extraction of gallic acid from urine Bhawani, Showkat Ahmad Tham, Soon Sen Mohammad Nasir, bin Mohammad Ibrahim Q Science (General) QD Chemistry The molecularly imprinted polymers for gallic acid were synthesized by precipitation polymerization. During the process of synthesis a non-covalent approach was used for the interaction of template and monomer. In the polymerization process, gallic acid was used as a template, acrylic acid as a functional monomer, ethylene glycol dimethacrylate as a cross-linker and 2,2'-azobisisobutyronitrile as an initiator and acetonitrile as a solvent. The synthesized imprinted and non-imprinted polymer particles were characterized by using Fourier-transform infrared spectroscopy and scanning electron microscopy. The rebinding efficiency of synthesized polymer particles was evaluated by batch binding assay. The highly selective imprinted polymer for gallic acid was MIPI1 with a composition (molar ratio) of 1:4:20, template: monomer: cross-linker, respectively. The MIPI1 showed highest binding efficiency (79.50%) as compared to other imprinted and non-imprinted polymers. The highly selective imprinted polymers have successfully extracted about 80% of gallic acid from spiked urine sample. © The Author(s) 2018. Springer 2018-12-01 Article PeerReviewed text en http://ir.unimas.my/id/eprint/19815/1/Bhawani%2C%20Showkat%20Ahmad.pdf Bhawani, Showkat Ahmad and Tham, Soon Sen and Mohammad Nasir, bin Mohammad Ibrahim (2018) Synthesis of molecular imprinting polymers for extraction of gallic acid from urine. Chemistry Central Journal, 12 (1). pp. 1-7. ISSN 1752-153X https://www.scopus.com/inward/record.uri?eid=2-s2.0-85042443766&doi=10.1186%2fs13065-018-0392-7&partnerID=40&md5=651cb852f55ae8b2a3b1b4628095d5ee DOI: 10.1186/s13065-018-0392-7 |
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Q Science (General) QD Chemistry Bhawani, Showkat Ahmad Tham, Soon Sen Mohammad Nasir, bin Mohammad Ibrahim Synthesis of molecular imprinting polymers for extraction of gallic acid from urine |
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The molecularly imprinted polymers for gallic acid were synthesized by precipitation polymerization. During the process of synthesis a non-covalent approach was used for the interaction of template and monomer. In the polymerization process, gallic acid was used as a template, acrylic acid as a functional monomer, ethylene glycol dimethacrylate as a cross-linker and 2,2'-azobisisobutyronitrile as an initiator and acetonitrile as a solvent. The synthesized imprinted and non-imprinted polymer particles were characterized by using Fourier-transform infrared spectroscopy and scanning electron microscopy. The rebinding efficiency of synthesized polymer particles was evaluated by batch binding assay. The highly selective imprinted polymer for gallic acid was MIPI1 with a composition (molar ratio) of 1:4:20, template: monomer: cross-linker, respectively. The MIPI1 showed highest binding efficiency (79.50%) as compared to other imprinted and non-imprinted polymers. The highly selective imprinted polymers have successfully extracted about 80% of gallic acid from spiked urine sample. © The Author(s) 2018. |
format |
Article |
author |
Bhawani, Showkat Ahmad Tham, Soon Sen Mohammad Nasir, bin Mohammad Ibrahim |
author_facet |
Bhawani, Showkat Ahmad Tham, Soon Sen Mohammad Nasir, bin Mohammad Ibrahim |
author_sort |
Bhawani, Showkat Ahmad |
title |
Synthesis of molecular imprinting polymers for extraction of gallic acid from urine |
title_short |
Synthesis of molecular imprinting polymers for extraction of gallic acid from urine |
title_full |
Synthesis of molecular imprinting polymers for extraction of gallic acid from urine |
title_fullStr |
Synthesis of molecular imprinting polymers for extraction of gallic acid from urine |
title_full_unstemmed |
Synthesis of molecular imprinting polymers for extraction of gallic acid from urine |
title_sort |
synthesis of molecular imprinting polymers for extraction of gallic acid from urine |
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Springer |
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2018 |
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http://ir.unimas.my/id/eprint/19815/1/Bhawani%2C%20Showkat%20Ahmad.pdf http://ir.unimas.my/id/eprint/19815/ https://www.scopus.com/inward/record.uri?eid=2-s2.0-85042443766&doi=10.1186%2fs13065-018-0392-7&partnerID=40&md5=651cb852f55ae8b2a3b1b4628095d5ee |
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13.18916 |