n-Butyldichlorido{4-cyclohexyl-1-[1-(pyridin 2-yl-jN)ethylidene]thiosemicarbazidato-j2N1,S}tin(IV)
Two independent mol-ecules comprise the asymmetric unit in the title compound, [Sn(C₄H₉)(C₁₄H₁₉N₄S)Cl₂]. In each mol-ecule, the Sn(IV) atom exists within a distorted octa-hedral geometry defined by the N,N',S-tridentate mono-deprotonated Schiff base ligand, two mutually trans Cl atoms, and the...
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| Main Authors: | , , , |
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| Format: | E-Article |
| Language: | English |
| Published: |
IUCR
2012
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| Subjects: | |
| Online Access: | http://ir.unimas.my/id/eprint/14380/1/n-Butyldichlorido%7B4-cyclohexyl-1%20%28abstract%29.pdf http://ir.unimas.my/id/eprint/14380/ https://www.researchgate.net/publication/229161810_n-Butyldichlorido4-cyclo-hexyl-1-1-pyridin-2-yl-kNethyl-idenethio-semi-carb-azi-dato-kNStinIV |
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| Summary: | Two independent mol-ecules comprise the asymmetric unit in the title compound, [Sn(C₄H₉)(C₁₄H₁₉N₄S)Cl₂]. In each mol-ecule, the Sn(IV) atom exists within a distorted octa-hedral geometry defined by the N,N',S-tridentate mono-deprotonated Schiff base ligand, two mutually trans Cl atoms, and the α-C atom of the n-butyl group; the latter is trans to the azo-N atom. The greatest distortion from the ideal geometry is found in the nominally trans angle formed by the S and pyridyl-N atoms at Sn [151.72 (7) and 152.04 (7)°, respectively]. In the crystal, mol-ecules are consolidated into a three-dimensional architecture by a combination of N-H⋯Cl, C-H⋯π and π-π inter-actions [inter-centroid distances = 3.6718 (19) and 3.675 (2) Å]. |
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