Synthesis of Nickel(II) Complexes Using α,β-Conjugated Schiff Base Compounds
Two types of α,β-conjugated Schiff base compounds with different R substituents were synthesized by the condensation reaction of cinnamaldehyde with aniline (1) and 4methoxycinnamaldehyde with 4-methoxyaniline (2) in the presence of ethanol. Then, the α,βconjugated Schiff bases (1-2) were allowed to...
Saved in:
Main Author: | |
---|---|
Format: | E-LPTA |
Language: | English English |
Published: |
Universiti Malaysia Sarawak, (UNIMAS)
2015
|
Subjects: | |
Online Access: | http://ir.unimas.my/id/eprint/11057/1/Synthesis%20of%20Nickel%28II%29%20Complexes%20Using%20%CE%B1%2C%CE%B2-Conjugated%20Schiff%20Base%20Compounds%20%2824%20pages%29.pdf http://ir.unimas.my/id/eprint/11057/2/Synthesis%20of%20Nickel%28II%29%20Complexes%20Using%20%CE%B1%2C%CE%B2-Conjugated%20Schiff%20Base%20Compounds.pdf http://ir.unimas.my/id/eprint/11057/ |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
id |
my.unimas.ir.11057 |
---|---|
record_format |
eprints |
spelling |
my.unimas.ir.110572016-03-22T03:12:20Z http://ir.unimas.my/id/eprint/11057/ Synthesis of Nickel(II) Complexes Using α,β-Conjugated Schiff Base Compounds Nadarajan, Priya TP Chemical technology Two types of α,β-conjugated Schiff base compounds with different R substituents were synthesized by the condensation reaction of cinnamaldehyde with aniline (1) and 4methoxycinnamaldehyde with 4-methoxyaniline (2) in the presence of ethanol. Then, the α,βconjugated Schiff bases (1-2) were allowed to react with NiCl2·6H2O to produce nickel(II) complexes (3-4). The α,β-conjugated Schiff bases (1-2) and their complexes (3-4) obtained were characterized using Fourier Transform Infrared (FTIR), UV-Vis spectroscopy, CHN analyser and 1H Nuclear Magnetic Resonance (1H NMR). Both the α,β-conjugated Schiff bases (1-2) and complexes (3-4) are polar in nature. Spectral studies suggested that α,βconjugated Schiff base compounds (1-2) acted as a bidentate ligand towards nickel(II) ion and metal complex 4 was suggested to demonstrate a square planar geometry. Universiti Malaysia Sarawak, (UNIMAS) 2015 E-LPTA NonPeerReviewed text en http://ir.unimas.my/id/eprint/11057/1/Synthesis%20of%20Nickel%28II%29%20Complexes%20Using%20%CE%B1%2C%CE%B2-Conjugated%20Schiff%20Base%20Compounds%20%2824%20pages%29.pdf text en http://ir.unimas.my/id/eprint/11057/2/Synthesis%20of%20Nickel%28II%29%20Complexes%20Using%20%CE%B1%2C%CE%B2-Conjugated%20Schiff%20Base%20Compounds.pdf Nadarajan, Priya (2015) Synthesis of Nickel(II) Complexes Using α,β-Conjugated Schiff Base Compounds. [E-LPTA] (Unpublished) |
institution |
Universiti Malaysia Sarawak |
building |
Centre for Academic Information Services (CAIS) |
collection |
Institutional Repository |
continent |
Asia |
country |
Malaysia |
content_provider |
Universiti Malaysia Sarawak |
content_source |
UNIMAS Institutional Repository |
url_provider |
http://ir.unimas.my/ |
language |
English English |
topic |
TP Chemical technology |
spellingShingle |
TP Chemical technology Nadarajan, Priya Synthesis of Nickel(II) Complexes Using α,β-Conjugated Schiff Base Compounds |
description |
Two types of α,β-conjugated Schiff base compounds with different R substituents were synthesized by the condensation reaction of cinnamaldehyde with aniline (1) and 4methoxycinnamaldehyde with 4-methoxyaniline (2) in the presence of ethanol. Then, the α,βconjugated Schiff bases (1-2) were allowed to react with NiCl2·6H2O to produce nickel(II) complexes (3-4). The α,β-conjugated Schiff bases (1-2) and their complexes (3-4) obtained were characterized using Fourier Transform Infrared (FTIR), UV-Vis spectroscopy, CHN analyser and 1H Nuclear Magnetic Resonance (1H NMR). Both the α,β-conjugated Schiff bases (1-2) and complexes (3-4) are polar in nature. Spectral studies suggested that α,βconjugated Schiff base compounds (1-2) acted as a bidentate ligand towards nickel(II) ion and metal complex 4 was suggested to demonstrate a square planar geometry. |
format |
E-LPTA |
author |
Nadarajan, Priya |
author_facet |
Nadarajan, Priya |
author_sort |
Nadarajan, Priya |
title |
Synthesis of Nickel(II) Complexes Using α,β-Conjugated Schiff Base Compounds |
title_short |
Synthesis of Nickel(II) Complexes Using α,β-Conjugated Schiff Base Compounds |
title_full |
Synthesis of Nickel(II) Complexes Using α,β-Conjugated Schiff Base Compounds |
title_fullStr |
Synthesis of Nickel(II) Complexes Using α,β-Conjugated Schiff Base Compounds |
title_full_unstemmed |
Synthesis of Nickel(II) Complexes Using α,β-Conjugated Schiff Base Compounds |
title_sort |
synthesis of nickel(ii) complexes using α,β-conjugated schiff base compounds |
publisher |
Universiti Malaysia Sarawak, (UNIMAS) |
publishDate |
2015 |
url |
http://ir.unimas.my/id/eprint/11057/1/Synthesis%20of%20Nickel%28II%29%20Complexes%20Using%20%CE%B1%2C%CE%B2-Conjugated%20Schiff%20Base%20Compounds%20%2824%20pages%29.pdf http://ir.unimas.my/id/eprint/11057/2/Synthesis%20of%20Nickel%28II%29%20Complexes%20Using%20%CE%B1%2C%CE%B2-Conjugated%20Schiff%20Base%20Compounds.pdf http://ir.unimas.my/id/eprint/11057/ |
_version_ |
1644511120904421376 |
score |
13.160551 |