Synthesis of Nickel(II) Complexes Using α,β-Conjugated Schiff Base Compounds

Two types of α,β-conjugated Schiff base compounds with different R substituents were synthesized by the condensation reaction of cinnamaldehyde with aniline (1) and 4methoxycinnamaldehyde with 4-methoxyaniline (2) in the presence of ethanol. Then, the α,βconjugated Schiff bases (1-2) were allowed to...

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Main Author: Nadarajan, Priya
Format: E-LPTA
Language:English
English
Published: Universiti Malaysia Sarawak, (UNIMAS) 2015
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Online Access:http://ir.unimas.my/id/eprint/11057/1/Synthesis%20of%20Nickel%28II%29%20Complexes%20Using%20%CE%B1%2C%CE%B2-Conjugated%20Schiff%20Base%20Compounds%20%2824%20pages%29.pdf
http://ir.unimas.my/id/eprint/11057/2/Synthesis%20of%20Nickel%28II%29%20Complexes%20Using%20%CE%B1%2C%CE%B2-Conjugated%20Schiff%20Base%20Compounds.pdf
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spelling my.unimas.ir.110572016-03-22T03:12:20Z http://ir.unimas.my/id/eprint/11057/ Synthesis of Nickel(II) Complexes Using α,β-Conjugated Schiff Base Compounds Nadarajan, Priya TP Chemical technology Two types of α,β-conjugated Schiff base compounds with different R substituents were synthesized by the condensation reaction of cinnamaldehyde with aniline (1) and 4methoxycinnamaldehyde with 4-methoxyaniline (2) in the presence of ethanol. Then, the α,βconjugated Schiff bases (1-2) were allowed to react with NiCl2·6H2O to produce nickel(II) complexes (3-4). The α,β-conjugated Schiff bases (1-2) and their complexes (3-4) obtained were characterized using Fourier Transform Infrared (FTIR), UV-Vis spectroscopy, CHN analyser and 1H Nuclear Magnetic Resonance (1H NMR). Both the α,β-conjugated Schiff bases (1-2) and complexes (3-4) are polar in nature. Spectral studies suggested that α,βconjugated Schiff base compounds (1-2) acted as a bidentate ligand towards nickel(II) ion and metal complex 4 was suggested to demonstrate a square planar geometry. Universiti Malaysia Sarawak, (UNIMAS) 2015 E-LPTA NonPeerReviewed text en http://ir.unimas.my/id/eprint/11057/1/Synthesis%20of%20Nickel%28II%29%20Complexes%20Using%20%CE%B1%2C%CE%B2-Conjugated%20Schiff%20Base%20Compounds%20%2824%20pages%29.pdf text en http://ir.unimas.my/id/eprint/11057/2/Synthesis%20of%20Nickel%28II%29%20Complexes%20Using%20%CE%B1%2C%CE%B2-Conjugated%20Schiff%20Base%20Compounds.pdf Nadarajan, Priya (2015) Synthesis of Nickel(II) Complexes Using α,β-Conjugated Schiff Base Compounds. [E-LPTA] (Unpublished)
institution Universiti Malaysia Sarawak
building Centre for Academic Information Services (CAIS)
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Sarawak
content_source UNIMAS Institutional Repository
url_provider http://ir.unimas.my/
language English
English
topic TP Chemical technology
spellingShingle TP Chemical technology
Nadarajan, Priya
Synthesis of Nickel(II) Complexes Using α,β-Conjugated Schiff Base Compounds
description Two types of α,β-conjugated Schiff base compounds with different R substituents were synthesized by the condensation reaction of cinnamaldehyde with aniline (1) and 4methoxycinnamaldehyde with 4-methoxyaniline (2) in the presence of ethanol. Then, the α,βconjugated Schiff bases (1-2) were allowed to react with NiCl2·6H2O to produce nickel(II) complexes (3-4). The α,β-conjugated Schiff bases (1-2) and their complexes (3-4) obtained were characterized using Fourier Transform Infrared (FTIR), UV-Vis spectroscopy, CHN analyser and 1H Nuclear Magnetic Resonance (1H NMR). Both the α,β-conjugated Schiff bases (1-2) and complexes (3-4) are polar in nature. Spectral studies suggested that α,βconjugated Schiff base compounds (1-2) acted as a bidentate ligand towards nickel(II) ion and metal complex 4 was suggested to demonstrate a square planar geometry.
format E-LPTA
author Nadarajan, Priya
author_facet Nadarajan, Priya
author_sort Nadarajan, Priya
title Synthesis of Nickel(II) Complexes Using α,β-Conjugated Schiff Base Compounds
title_short Synthesis of Nickel(II) Complexes Using α,β-Conjugated Schiff Base Compounds
title_full Synthesis of Nickel(II) Complexes Using α,β-Conjugated Schiff Base Compounds
title_fullStr Synthesis of Nickel(II) Complexes Using α,β-Conjugated Schiff Base Compounds
title_full_unstemmed Synthesis of Nickel(II) Complexes Using α,β-Conjugated Schiff Base Compounds
title_sort synthesis of nickel(ii) complexes using α,β-conjugated schiff base compounds
publisher Universiti Malaysia Sarawak, (UNIMAS)
publishDate 2015
url http://ir.unimas.my/id/eprint/11057/1/Synthesis%20of%20Nickel%28II%29%20Complexes%20Using%20%CE%B1%2C%CE%B2-Conjugated%20Schiff%20Base%20Compounds%20%2824%20pages%29.pdf
http://ir.unimas.my/id/eprint/11057/2/Synthesis%20of%20Nickel%28II%29%20Complexes%20Using%20%CE%B1%2C%CE%B2-Conjugated%20Schiff%20Base%20Compounds.pdf
http://ir.unimas.my/id/eprint/11057/
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score 13.160551