Effect of carbon supports on oxygen reduction reaction of iron/cobalt electrocatalyst

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Main Authors: S. A. Anuar, K. S. Loh, S. Samad, A. F. Zainul Abidin, W. Y. Wong, A. B. Mohamad, T. K. Lee
Other Authors: ksloh@ukm.edu.my
Format: Article
Language:English
Published: Universiti Malaysia Perlis (UniMAP) 2020
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Online Access:http://dspace.unimap.edu.my:80/xmlui/handle/123456789/68763
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spelling my.unimap-687632020-11-18T09:24:57Z Effect of carbon supports on oxygen reduction reaction of iron/cobalt electrocatalyst S. A. Anuar K. S. Loh S. Samad A. F. Zainul Abidin W. Y. Wong A. B. Mohamad T. K. Lee ksloh@ukm.edu.my Carbon supports Electrocatalyst Iron/Cobalt Oxygen reduction Link to publisher's homepage at http://ijneam.unimap.edu.my Dual metal FeCo has great potential as Pt-free catalyst in various applications, such as cathodic catalyst for fuel cells, in order to reduce the cost significantly and make fuel cell commercialization, viable. In this study, dual metal FeCo catalyst supported on carbon Vulcan XC-72, carbon nanotubes (CNT), and reduced graphene oxide (rGO) were successfully prepared via facile co-precipitation method with varying weight ratios of Fe and Co. The structure of the as-prepared catalysts was characterized by powder X-ray diffraction (XRD), scanning electron micrographs (SEM), and X-ray photoelectron spectroscopy (XPS). The XPS analysis revealed that CoFe2O4 were present on the catalyst particle surface with different Fe to Co ratio. The emergence of the new peak at 530.5 eV is assigned to the deposition of CoFe2O4, which is enabled via Fe-O-Co bonds. The FeCo/rGO catalyst with weight ratio of 2:1 exhibited the optimum performance for oxygen reduction reaction (ORR), with reduction peak of 0.163 mA cm-2 at 0.385 V vs. Ag/AgCl in an acidic media. The experimental result suggested that the dual metal FeCo catalyst display favourable electrocatalytic activity towards ORR and appears to be a promising cathodic electrocatalyst for an acidic fuel cell. 2020-11-18T09:24:57Z 2020-11-18T09:24:57Z 2020-05 Article International Journal of Nanoelectronics and Materials, vol.13(Special Issue), 2020, pages 225-232 1985-5761 (Printed) 1997-4434 (Online) http://dspace.unimap.edu.my:80/xmlui/handle/123456789/68763 http://ijneam.unimap.edu.my en International Symposium on Science, Technology and Engineering (ISSTE 2019; Universiti Malaysia Perlis (UniMAP)
institution Universiti Malaysia Perlis
building UniMAP Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Perlis
content_source UniMAP Library Digital Repository
url_provider http://dspace.unimap.edu.my/
language English
topic Carbon supports
Electrocatalyst
Iron/Cobalt
Oxygen reduction
spellingShingle Carbon supports
Electrocatalyst
Iron/Cobalt
Oxygen reduction
S. A. Anuar
K. S. Loh
S. Samad
A. F. Zainul Abidin
W. Y. Wong
A. B. Mohamad
T. K. Lee
Effect of carbon supports on oxygen reduction reaction of iron/cobalt electrocatalyst
description Link to publisher's homepage at http://ijneam.unimap.edu.my
author2 ksloh@ukm.edu.my
author_facet ksloh@ukm.edu.my
S. A. Anuar
K. S. Loh
S. Samad
A. F. Zainul Abidin
W. Y. Wong
A. B. Mohamad
T. K. Lee
format Article
author S. A. Anuar
K. S. Loh
S. Samad
A. F. Zainul Abidin
W. Y. Wong
A. B. Mohamad
T. K. Lee
author_sort S. A. Anuar
title Effect of carbon supports on oxygen reduction reaction of iron/cobalt electrocatalyst
title_short Effect of carbon supports on oxygen reduction reaction of iron/cobalt electrocatalyst
title_full Effect of carbon supports on oxygen reduction reaction of iron/cobalt electrocatalyst
title_fullStr Effect of carbon supports on oxygen reduction reaction of iron/cobalt electrocatalyst
title_full_unstemmed Effect of carbon supports on oxygen reduction reaction of iron/cobalt electrocatalyst
title_sort effect of carbon supports on oxygen reduction reaction of iron/cobalt electrocatalyst
publisher Universiti Malaysia Perlis (UniMAP)
publishDate 2020
url http://dspace.unimap.edu.my:80/xmlui/handle/123456789/68763
_version_ 1698698507300372480
score 13.219503