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A Green Approach to Modify Surface Properties of Polyurethane Foam for Enhanced Oil Absorption

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Main Authors: Zhi, Chien Ng, Rosyiela Azwa, Roslan, Woei, Jye Lau, Gürsoy, Mehmet, Mustafa, Karaman, Nora, Jullok, Ahmad Fauzi, Ismail
Other Authors: christine_zcng@yahoo.com
Format: Article
Language:English
Published: MDPI AG 2020
Subjects:
PU foam
CVD
Surface modification
Oil absorption
Water
Online Access:http://dspace.unimap.edu.my:80/xmlui/handle/123456789/68721
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spelling my.unimap-687212020-11-13T03:37:01Z A Green Approach to Modify Surface Properties of Polyurethane Foam for Enhanced Oil Absorption Zhi, Chien Ng Rosyiela Azwa, Roslan Woei, Jye Lau Gürsoy, Mehmet Mustafa, Karaman Nora, Jullok Ahmad Fauzi, Ismail christine_zcng@yahoo.com rosyielaazwa.roslan@yahoo.com afauzi@utm.my mgursoy@ktun.edu.tr mkaraman@ktun.edu.tr norajullok@unimap.edu.my lwoeijye@utm.my PU foam CVD Surface modification Oil absorption Water Link to publisher's homepage at https://www.mdpi.com/ The non-selective property of conventional polyurethane (PU) foam tends to lower its oil absorption efficiency. To address this issue, we modified the surface properties of PU foam using a rapid solvent-free surface functionalization approach based on the chemical vapor deposition (CVD) method to establish an extremely thin yet uniform coating layer to improve foam performance. The PU foam was respectively functionalized using different monomers, i.e., perfluorodecyl acrylate (PFDA), 2,2,3,4,4,4-hexafluorobutyl acrylate (HFBA), and hexamethyldisiloxane (HMDSO), and the effect of deposition times (1, 5 and 10 min) on the properties of foam was investigated. The results showed that all the modified foams demonstrated a much higher water contact angle (i.e., greater hydrophobicity) and greater absorption capacities compared to the control PU foam. This is due to the presence of specific functional groups, e.g., fluorine (F) and silane (Si) in the modified PU foams. Of all, the PU/PHFBAi foam exhibited the highest absorption capacities, recording 66.68, 58.15, 53.70, and 58.38 g/g for chloroform, acetone, cyclohexane, and edible oil, respectively. These values were 39.19–119.31% higher than that of control foam. The promising performance of the PU/PHFBAi foam is due to the improved surface hydrophobicity attributed to the original perfluoroalkyl moieties of the HFBA monomer. The PU/PHFBAi foam also demonstrated a much more stable absorption performance compared to the control foam when both samples were reused for up to 10 cycles. This clearly indicates the positive impact of the proposed functionalization method in improving PU properties for oil absorption processes. 2020-11-13T03:37:01Z 2020-11-13T03:37:01Z 2020-08 Article Polymers, vol.12(9), 2020, 14 pages http://dspace.unimap.edu.my:80/xmlui/handle/123456789/68721 2073-4360 (online) en MDPI AG
institution Universiti Malaysia Perlis
building UniMAP Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Perlis
content_source UniMAP Library Digital Repository
url_provider http://dspace.unimap.edu.my/
language English
topic PU foam
CVD
Surface modification
Oil absorption
Water
spellingShingle PU foam
CVD
Surface modification
Oil absorption
Water
Zhi, Chien Ng
Rosyiela Azwa, Roslan
Woei, Jye Lau
Gürsoy, Mehmet
Mustafa, Karaman
Nora, Jullok
Ahmad Fauzi, Ismail
A Green Approach to Modify Surface Properties of Polyurethane Foam for Enhanced Oil Absorption
description Link to publisher's homepage at https://www.mdpi.com/
author2 christine_zcng@yahoo.com
author_facet christine_zcng@yahoo.com
Zhi, Chien Ng
Rosyiela Azwa, Roslan
Woei, Jye Lau
Gürsoy, Mehmet
Mustafa, Karaman
Nora, Jullok
Ahmad Fauzi, Ismail
format Article
author Zhi, Chien Ng
Rosyiela Azwa, Roslan
Woei, Jye Lau
Gürsoy, Mehmet
Mustafa, Karaman
Nora, Jullok
Ahmad Fauzi, Ismail
author_sort Zhi, Chien Ng
title A Green Approach to Modify Surface Properties of Polyurethane Foam for Enhanced Oil Absorption
title_short A Green Approach to Modify Surface Properties of Polyurethane Foam for Enhanced Oil Absorption
title_full A Green Approach to Modify Surface Properties of Polyurethane Foam for Enhanced Oil Absorption
title_fullStr A Green Approach to Modify Surface Properties of Polyurethane Foam for Enhanced Oil Absorption
title_full_unstemmed A Green Approach to Modify Surface Properties of Polyurethane Foam for Enhanced Oil Absorption
title_sort green approach to modify surface properties of polyurethane foam for enhanced oil absorption
publisher MDPI AG
publishDate 2020
url http://dspace.unimap.edu.my:80/xmlui/handle/123456789/68721
_version_ 1698698501276303360
score 13.222552

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