Removal of chromium (VI) from aqueous solution using treated oil palm fibre

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Main Authors: Mohamed Hasnain, Isa, Naimah, Ibrahim, Hamidi, Abdul Aziz, Mohd. Nordin, Adlan, Nor Habsah, Md. Sabiani, Ali Akbar Lorestani, Zinatizadeh, Shamsul Rahman, Mohamed Kutty
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Language:English
Published: Elsevier B.V 2009
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Online Access:http://dspace.unimap.edu.my/xmlui/handle/123456789/6619
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spelling my.unimap-66192009-07-31T00:48:07Z Removal of chromium (VI) from aqueous solution using treated oil palm fibre Mohamed Hasnain, Isa Naimah, Ibrahim Hamidi, Abdul Aziz Mohd. Nordin, Adlan Nor Habsah, Md. Sabiani Ali Akbar Lorestani, Zinatizadeh Shamsul Rahman, Mohamed Kutty Chromium (VI) Adsorption Treated oil palm fibre Kinetic Oil palm Adsorbent Chromium Isotherm Link to publisher's homepage at http://www.elsevier.com/wps/find/journaldescription.cws_home/502691/description#description This study proposed an oil palm by-product as a low-cost adsorbent for the removal of hexavalent chromium [Cr (VI)] from aqueous solution. Adsorption of Cr (VI) by sulphuric acid and heat-treated oil palm fibre was conducted using batch tests. The influence of pH, contact time, initial chromium concentration and adsorbent dosage on the removal of Cr (VI) from the solutions was investigated. The optimum initial pH for maximum uptake of Cr (VI) from aqueous solution was found to be 1.5. The removal efficiency was found to correlate with the initial Cr (VI) concentration, adsorbent dosage as well as the contact time between Cr (VI) and the adsorbent. The adsorption kinetics tested with pseudo first order and pseudo second order models yielded high R2 values from 0.9254 to 0.9870 and from 0.9936 to 0.9998, respectively. The analysis of variance (ANOVA) showed significant difference between the R2 values of the two models at 99% confidence level. The Freundlich isotherm (R2 = 0.8778) described Cr (VI) adsorption slightly better than the Langmuir isotherm (R2 = 0.8715). Difficulty in desorption of Cr (VI) suggests the suitability of treated oil palm fibre as a single-use adsorbent for Cr (VI) removal from aqueous solution. 2009-07-31T00:47:49Z 2009-07-31T00:47:49Z 2007-07-17 Article Journal of Hazardous Materials, vol.152 (2), 1 April 2008 pages 662-668 0304-3894 http://www.sciencedirect.com/science/journal/03043894 http://hdl.handle.net/123456789/6619 en Elsevier B.V
institution Universiti Malaysia Perlis
building UniMAP Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Perlis
content_source UniMAP Library Digital Repository
url_provider http://dspace.unimap.edu.my/
language English
topic Chromium (VI)
Adsorption
Treated oil palm fibre
Kinetic
Oil palm
Adsorbent
Chromium
Isotherm
spellingShingle Chromium (VI)
Adsorption
Treated oil palm fibre
Kinetic
Oil palm
Adsorbent
Chromium
Isotherm
Mohamed Hasnain, Isa
Naimah, Ibrahim
Hamidi, Abdul Aziz
Mohd. Nordin, Adlan
Nor Habsah, Md. Sabiani
Ali Akbar Lorestani, Zinatizadeh
Shamsul Rahman, Mohamed Kutty
Removal of chromium (VI) from aqueous solution using treated oil palm fibre
description Link to publisher's homepage at http://www.elsevier.com/wps/find/journaldescription.cws_home/502691/description#description
format Article
author Mohamed Hasnain, Isa
Naimah, Ibrahim
Hamidi, Abdul Aziz
Mohd. Nordin, Adlan
Nor Habsah, Md. Sabiani
Ali Akbar Lorestani, Zinatizadeh
Shamsul Rahman, Mohamed Kutty
author_facet Mohamed Hasnain, Isa
Naimah, Ibrahim
Hamidi, Abdul Aziz
Mohd. Nordin, Adlan
Nor Habsah, Md. Sabiani
Ali Akbar Lorestani, Zinatizadeh
Shamsul Rahman, Mohamed Kutty
author_sort Mohamed Hasnain, Isa
title Removal of chromium (VI) from aqueous solution using treated oil palm fibre
title_short Removal of chromium (VI) from aqueous solution using treated oil palm fibre
title_full Removal of chromium (VI) from aqueous solution using treated oil palm fibre
title_fullStr Removal of chromium (VI) from aqueous solution using treated oil palm fibre
title_full_unstemmed Removal of chromium (VI) from aqueous solution using treated oil palm fibre
title_sort removal of chromium (vi) from aqueous solution using treated oil palm fibre
publisher Elsevier B.V
publishDate 2009
url http://dspace.unimap.edu.my/xmlui/handle/123456789/6619
_version_ 1643788572050849792
score 13.214268