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Analytical Study of ion–selective electrodes using nanoparticulate ZnO

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Main Authors: Al-Samarrai, Khalaf F., Al-Obeidi, Omar H., Al-Doori, Mahmood S.
Other Authors: alfarisalsamarrai2013@gmail.com.
Format: Article
Language:English
Published: Universiti Malaysia Perlis 2016
Subjects:
Nanoparticles
Electrode
Analysis
Online Access:http://dspace.unimap.edu.my:80/xmlui/handle/123456789/41338
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spelling my.unimap-413382016-04-22T10:54:53Z Analytical Study of ion–selective electrodes using nanoparticulate ZnO Al-Samarrai, Khalaf F. Al-Obeidi, Omar H. Al-Doori, Mahmood S. alfarisalsamarrai2013@gmail.com. Nanoparticles Electrode Analysis Link to publisher's homepage at http://ijneam.unimap.edu.my/ Zinc Oxide nanoparticles (NPs) were prepared from raw materials via a microwaveassisted method. The ZnO NPs were characterized by X-ray Diffraction (XRD) and scanning electron microscopy (SEM). NPs were approximately 22.5 nm in size, as calculated using the Scherrer formula from the most intense XRD peak. The ZnO NPs were compared with ZnO microparticles (MPs) through thermal analysis (thermogravimetry TG, derivative thermogravimetry DTG, and differential thermal analysis DTA). A Zn2+-selective electrode based on polyvinyl chloride was prepared using ZnO NP powder and di-butyl phthalate, and then the analytical specifications of the ZnO NP and ZnO MP electrodes were compared. The ZnO NPs and ZnO MPs electrodes respectively had linear ranges of 10−2– 10−5 and 10−2–10−4 M, Nernstain slopes of 28.71 and 27.79 mV/decade, correlation coefficients of 0.999 and 0.999, detection limits of 1.371 × 10−7 and 2.513 × 10−6 M, quantitative limits of 4.569 × 10−7 and 8.383 × 10−6 M, and response times of 9–39 and 13– 36 s respectively. The lifetime of each electrode was 11 day. The optimum conditions for each electrode were pH 5–8, 25–30 °C temperature, and 10−3 M filling solution concentration. The selectivity of the electrodes was measured in different solutions, and results showed that the selectivity coefficient values for all interference ions were less than one. 2016-04-22T10:54:53Z 2016-04-22T10:54:53Z 2015 Article International Journal of Nanoelectronics and Materials, vol.8, 2015, pages 121-128 1985-5761 (Printed) 1997-4434 (Online) http://dspace.unimap.edu.my:80/xmlui/handle/123456789/41338 en Universiti Malaysia Perlis
institution Universiti Malaysia Perlis
building UniMAP Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Perlis
content_source UniMAP Library Digital Repository
url_provider http://dspace.unimap.edu.my/
language English
topic Nanoparticles
Electrode
Analysis
spellingShingle Nanoparticles
Electrode
Analysis
Al-Samarrai, Khalaf F.
Al-Obeidi, Omar H.
Al-Doori, Mahmood S.
Analytical Study of ion–selective electrodes using nanoparticulate ZnO
description Link to publisher's homepage at http://ijneam.unimap.edu.my/
author2 alfarisalsamarrai2013@gmail.com.
author_facet alfarisalsamarrai2013@gmail.com.
Al-Samarrai, Khalaf F.
Al-Obeidi, Omar H.
Al-Doori, Mahmood S.
format Article
author Al-Samarrai, Khalaf F.
Al-Obeidi, Omar H.
Al-Doori, Mahmood S.
author_sort Al-Samarrai, Khalaf F.
title Analytical Study of ion–selective electrodes using nanoparticulate ZnO
title_short Analytical Study of ion–selective electrodes using nanoparticulate ZnO
title_full Analytical Study of ion–selective electrodes using nanoparticulate ZnO
title_fullStr Analytical Study of ion–selective electrodes using nanoparticulate ZnO
title_full_unstemmed Analytical Study of ion–selective electrodes using nanoparticulate ZnO
title_sort analytical study of ion–selective electrodes using nanoparticulate zno
publisher Universiti Malaysia Perlis
publishDate 2016
url http://dspace.unimap.edu.my:80/xmlui/handle/123456789/41338
_version_ 1643799685182259200
score 13.214268

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