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Influence of impurities and catalyst surface characteristics on the oxygen charge transfer reaction in the Pt/YSZ system

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Main Authors: Mas Rahayu, Jamil, Naimah, Ibrahim, Poulidi, Danai, Ian S., Metcalfe
Other Authors: naimah@unimap.edu.my
Format: Article
Published: Elsevier B.V. 2016
Subjects:
Electrochemical promotion
Pt film impurities
Solid state cyclic voltammetry
Online Access:http://dspace.unimap.edu.my:80/xmlui/handle/123456789/41173
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spelling my.unimap-411732016-03-21T10:43:52Z Influence of impurities and catalyst surface characteristics on the oxygen charge transfer reaction in the Pt/YSZ system Mas Rahayu, Jamil Naimah, Ibrahim Poulidi, Danai Ian S., Metcalfe naimah@unimap.edu.my ian.metcalfe@ncl.ac.uk Electrochemical promotion Pt film impurities Solid state cyclic voltammetry Link to publisher's homepage at http://www.journals.elsevier.com Spillover processes (i.e. the migration of ionic species from the support to the catalyst and vice versa) are known to play a very important role in catalysis and electrocatalysis. These spillover processes can be influenced by impurities (pre-existing on the catalyst surface) and by the catalyst morphology that may differ as a result of the differences in catalyst manufacturing processes. This work investigates the influence of impurities present in three commercial platinum (Pt) precursors. The resulting platinum films studied here were supported on yttria-stabilised-zirconia (YSZ). It was found that the three different catalyst films contained a range of impurities (determined by ICP-OES) that appear to affect the oxygen charge transfer reaction as studied by cyclic voltammetry (CV). 2016-03-21T10:43:52Z 2016-03-21T10:43:52Z 2012-10-04 Article Solid State Ionics, vol. 225, 2012, pages 390-394 0167-2738 http://dspace.unimap.edu.my:80/xmlui/handle/123456789/41173 doi:10.1016/j.ssi.2012.06.011 10.1016/j.ssi.2012.06.011 Elsevier B.V.
institution Universiti Malaysia Perlis
building UniMAP Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Perlis
content_source UniMAP Library Digital Repository
url_provider http://dspace.unimap.edu.my/
topic Electrochemical promotion
Pt film impurities
Solid state cyclic voltammetry
spellingShingle Electrochemical promotion
Pt film impurities
Solid state cyclic voltammetry
Mas Rahayu, Jamil
Naimah, Ibrahim
Poulidi, Danai
Ian S., Metcalfe
Influence of impurities and catalyst surface characteristics on the oxygen charge transfer reaction in the Pt/YSZ system
description Link to publisher's homepage at http://www.journals.elsevier.com
author2 naimah@unimap.edu.my
author_facet naimah@unimap.edu.my
Mas Rahayu, Jamil
Naimah, Ibrahim
Poulidi, Danai
Ian S., Metcalfe
format Article
author Mas Rahayu, Jamil
Naimah, Ibrahim
Poulidi, Danai
Ian S., Metcalfe
author_sort Mas Rahayu, Jamil
title Influence of impurities and catalyst surface characteristics on the oxygen charge transfer reaction in the Pt/YSZ system
title_short Influence of impurities and catalyst surface characteristics on the oxygen charge transfer reaction in the Pt/YSZ system
title_full Influence of impurities and catalyst surface characteristics on the oxygen charge transfer reaction in the Pt/YSZ system
title_fullStr Influence of impurities and catalyst surface characteristics on the oxygen charge transfer reaction in the Pt/YSZ system
title_full_unstemmed Influence of impurities and catalyst surface characteristics on the oxygen charge transfer reaction in the Pt/YSZ system
title_sort influence of impurities and catalyst surface characteristics on the oxygen charge transfer reaction in the pt/ysz system
publisher Elsevier B.V.
publishDate 2016
url http://dspace.unimap.edu.my:80/xmlui/handle/123456789/41173
_version_ 1643799599718072320
score 13.214268

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