Removal of Ni(II), Zn(II) and Pb(II) from aqueous solutions using cation-exchange resin in fixed-bed column
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2016
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my.unimap-411642016-03-21T08:21:46Z Removal of Ni(II), Zn(II) and Pb(II) from aqueous solutions using cation-exchange resin in fixed-bed column Myzairah, Hamdzah Zaini, Ujang Mohamed Mahmoud, Nasef Norhayati, Abdullah Farrah Aini, Dahalan farrahaini@unimap.edu.my Bohart–Adam model Cation exchange resins Heavy metal Thomas model Link to publisher's homepage at http://www.tandfonline.com Breakthrough curves for the removal of Ni(II), Zn(II), and Pb(II) from aqueous solutions using cation exchange resin (Dowex 50W) were determined at dynamic conditions in a fixed-bed column under ambient temperature. The experiments and data obtained were designed and analyzed using response surface methodology, respectively. Three operating parameters: flow rate (15–25 mL min−1), pH (3–9), and bed height (3–5 cm) were investigated. Fixed-bed adsorption models namely Thomas model and Bohart–Adam model were adopted to describe the dynamics of metal adsorption in the column. The obtained experimental data were fitted to these models based on the kinetic constant kBA(mg min cm−3), kTH (cm3 mg−1 min), the maximum amount of metal exchange N0 (mg cm−3), and the maximum adsorption capacities qtm (mg), accordingly. The Thomas model was found to best fit all the experimental conditions studied with correlation coefficients of 0.91, 0.97, and 0.92 for Ni(II), Zn(II), and Pb(II), respectively. 2016-03-21T08:21:46Z 2016-03-21T08:21:46Z 2015-10-13 Article Desalination and Water Treatment, 2015, pages 1-12 1944-3994 1944-3986 (online) http://dspace.unimap.edu.my:80/xmlui/handle/123456789/41164 10.1080/19443994.2015.1095118 en Taylor and Francis Ltd. |
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Bohart–Adam model Cation exchange resins Heavy metal Thomas model |
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Bohart–Adam model Cation exchange resins Heavy metal Thomas model Myzairah, Hamdzah Zaini, Ujang Mohamed Mahmoud, Nasef Norhayati, Abdullah Farrah Aini, Dahalan Removal of Ni(II), Zn(II) and Pb(II) from aqueous solutions using cation-exchange resin in fixed-bed column |
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Link to publisher's homepage at http://www.tandfonline.com |
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farrahaini@unimap.edu.my |
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farrahaini@unimap.edu.my Myzairah, Hamdzah Zaini, Ujang Mohamed Mahmoud, Nasef Norhayati, Abdullah Farrah Aini, Dahalan |
format |
Article |
author |
Myzairah, Hamdzah Zaini, Ujang Mohamed Mahmoud, Nasef Norhayati, Abdullah Farrah Aini, Dahalan |
author_sort |
Myzairah, Hamdzah |
title |
Removal of Ni(II), Zn(II) and Pb(II) from aqueous solutions using cation-exchange resin in fixed-bed column |
title_short |
Removal of Ni(II), Zn(II) and Pb(II) from aqueous solutions using cation-exchange resin in fixed-bed column |
title_full |
Removal of Ni(II), Zn(II) and Pb(II) from aqueous solutions using cation-exchange resin in fixed-bed column |
title_fullStr |
Removal of Ni(II), Zn(II) and Pb(II) from aqueous solutions using cation-exchange resin in fixed-bed column |
title_full_unstemmed |
Removal of Ni(II), Zn(II) and Pb(II) from aqueous solutions using cation-exchange resin in fixed-bed column |
title_sort |
removal of ni(ii), zn(ii) and pb(ii) from aqueous solutions using cation-exchange resin in fixed-bed column |
publisher |
Taylor and Francis Ltd. |
publishDate |
2016 |
url |
http://dspace.unimap.edu.my:80/xmlui/handle/123456789/41164 |
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1643799579368357888 |
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13.222552 |