Characterization of nano zero-valent iron (nZVI) and its application in sono-Fenton process to remove COD in palm oil mill effluent

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Main Authors: Mohd Raihan, Taha, Prof. Dr., Abdul Haqi, Ibrahim
Other Authors: dmrt@eng.ukm.my
Format: Article
Language:English
Published: Elsevier 2014
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Online Access:http://dspace.unimap.edu.my:80/dspace/handle/123456789/35521
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spelling my.unimap-355212014-06-15T13:18:24Z Characterization of nano zero-valent iron (nZVI) and its application in sono-Fenton process to remove COD in palm oil mill effluent Mohd Raihan, Taha, Prof. Dr. Abdul Haqi, Ibrahim dmrt@eng.ukm.my haqiibrahim@gmail.com Nano zero-valent iron (nZVI) Sono-Fenton Palm oil mill effluent (POME) Link to publisher's homepage at http://www.journals.elsevier.com/journal-of-environmental-chemical-engineering Nano zero-valent iron (nZVI) has received great attention for its capability to treat wastewater. One of its applications is in an advanced oxidation process (AOP) called the sono-Fenton process. This study presents the characterization of the nZVI particle by its particle size, scanning electron microscope (SEM) images, transmission electron microscope (TEM) images, X-ray diffraction (XRD), energy dispersive X-ray (EDX) and X-ray photoelectron spectroscopy (XPS) analysis. Results show that the average size of nZVI is 49 nm and it has two layers. The outer layer (shell) is comprised of iron oxides (i.e. FeO) while the core is elemental iron (Fe). At pH 2, nZVI was found to be a good replacement for iron sulfate (FeSO4) as a ferrous iron (Fe2+) source in the sono-Fenton process. In addition, the removal process of organic pollutants from diluted palm oil mill effluent (POME) was also accelerated by ultrasound, particularly at higher intensity and longer sonication time. Eighty percent (80%) of the chemical oxygen demand (COD) was removed in 2 h instead of 24 h by silent degradation. 2014-06-15T13:18:24Z 2014-06-15T13:18:24Z 2014-03 Article Journal of Environmental Chemical Engineering, vol.2 (1), 2014, pages 1–8 2213-3437 http://dspace.unimap.edu.my:80/dspace/handle/123456789/35521 http://www.sciencedirect.com/science/article/pii/S2213343713002376 10.1016/j.jece.2013.11.021 en Elsevier
institution Universiti Malaysia Perlis
building UniMAP Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Perlis
content_source UniMAP Library Digital Repository
url_provider http://dspace.unimap.edu.my/
language English
topic Nano zero-valent iron (nZVI)
Sono-Fenton
Palm oil mill effluent (POME)
spellingShingle Nano zero-valent iron (nZVI)
Sono-Fenton
Palm oil mill effluent (POME)
Mohd Raihan, Taha, Prof. Dr.
Abdul Haqi, Ibrahim
Characterization of nano zero-valent iron (nZVI) and its application in sono-Fenton process to remove COD in palm oil mill effluent
description Link to publisher's homepage at http://www.journals.elsevier.com/journal-of-environmental-chemical-engineering
author2 dmrt@eng.ukm.my
author_facet dmrt@eng.ukm.my
Mohd Raihan, Taha, Prof. Dr.
Abdul Haqi, Ibrahim
format Article
author Mohd Raihan, Taha, Prof. Dr.
Abdul Haqi, Ibrahim
author_sort Mohd Raihan, Taha, Prof. Dr.
title Characterization of nano zero-valent iron (nZVI) and its application in sono-Fenton process to remove COD in palm oil mill effluent
title_short Characterization of nano zero-valent iron (nZVI) and its application in sono-Fenton process to remove COD in palm oil mill effluent
title_full Characterization of nano zero-valent iron (nZVI) and its application in sono-Fenton process to remove COD in palm oil mill effluent
title_fullStr Characterization of nano zero-valent iron (nZVI) and its application in sono-Fenton process to remove COD in palm oil mill effluent
title_full_unstemmed Characterization of nano zero-valent iron (nZVI) and its application in sono-Fenton process to remove COD in palm oil mill effluent
title_sort characterization of nano zero-valent iron (nzvi) and its application in sono-fenton process to remove cod in palm oil mill effluent
publisher Elsevier
publishDate 2014
url http://dspace.unimap.edu.my:80/dspace/handle/123456789/35521
_version_ 1643797830629851136
score 13.214268