A comparative study on curing characteristics, mechanical properties, swelling behavior, thermal stability, and Morphology of feldspar and silica in SMR L vulcanizates
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2014
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my.unimap-351562014-06-06T09:37:12Z A comparative study on curing characteristics, mechanical properties, swelling behavior, thermal stability, and Morphology of feldspar and silica in SMR L vulcanizates Hakimah, Osman, Dr. Azlan, Ariffin Hanafi, Ismail, Prof. Dr. hakimah@unimap.edu.my hanafi@eng.usm.my azlan@eng.usm.my Feldspar Silica Curing characteristics Mechanical properties Swelling behavior Thermal analysis Morphology SMR L vulcanizates Link to publisher's homepage at http://www.tandfonline.com/ Comparison studies on effects of feldspar and silica (Vulcasil C) as a filler in (SMR L grade natural rubber) vulcanizates on curing characteristics, mechanical properties, swelling behavior, thermal analysis, and morphology were examined. The incorporation of both fillers increases the scorch time, t 2, and cure time, t 90, of SMR L vulcanizates. At a similar filler loading, feldspar exhibited longer t 2 and t 90 but lower values of maximum torque, MHR, and torque difference, MHR–ML than did silica-filled SMR L vulcanizates. For mechanical properties, both fillers were found to be effective in enhancing the tensile strength (up to 10 phr), tensile modulus, and hardness of the vulcanizates. However, feldspar-filled SMR L vulcanizates showed lower values of mechanical properties than did silica-filled SMR L vulcanizates. Swelling measurement indicates that swelling percentages of both fillers-filled SMR L vulcanizates decrease with increasing filler loading whereas silica shows a lower swelling percentage than feldspar-filled SMR L vulcanizates. Scanning electron microscopy (SEM) on fracture surface of tensile samples showed poor filler–matrix adhesion for both fillers with increasing filler loading in the vulcanizates. However, feldspar-filled SMR L vulcanizates showed poorer filler–matrix adhesion than did silica-filled SMR L vulcanizates. Thermogravimetric analysis (TGA) results indicate that the feldspar-filled SMR L vulcanizates have higher thermal stability than do silica-filled SMR L vulcanizates. 2014-06-06T09:10:56Z 2014-06-06T09:10:56Z 2005 Article Polymer-Plastics Technology and Engineering, vol.43, 2005, pages 1323-1344 0360-2559 http://www.tandfonline.com/doi/abs/10.1081/.U5F-8YaQZYY http://dspace.unimap.edu.my:80/dspace/handle/123456789/35156 10.1081/PPT-200030163 en Taylor Francis Inc |
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Feldspar Silica Curing characteristics Mechanical properties Swelling behavior Thermal analysis Morphology SMR L vulcanizates |
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Feldspar Silica Curing characteristics Mechanical properties Swelling behavior Thermal analysis Morphology SMR L vulcanizates Hakimah, Osman, Dr. Azlan, Ariffin Hanafi, Ismail, Prof. Dr. A comparative study on curing characteristics, mechanical properties, swelling behavior, thermal stability, and Morphology of feldspar and silica in SMR L vulcanizates |
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Link to publisher's homepage at http://www.tandfonline.com/ |
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hakimah@unimap.edu.my |
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hakimah@unimap.edu.my Hakimah, Osman, Dr. Azlan, Ariffin Hanafi, Ismail, Prof. Dr. |
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Article |
author |
Hakimah, Osman, Dr. Azlan, Ariffin Hanafi, Ismail, Prof. Dr. |
author_sort |
Hakimah, Osman, Dr. |
title |
A comparative study on curing characteristics, mechanical properties, swelling behavior, thermal stability, and Morphology of feldspar and silica in SMR L vulcanizates |
title_short |
A comparative study on curing characteristics, mechanical properties, swelling behavior, thermal stability, and Morphology of feldspar and silica in SMR L vulcanizates |
title_full |
A comparative study on curing characteristics, mechanical properties, swelling behavior, thermal stability, and Morphology of feldspar and silica in SMR L vulcanizates |
title_fullStr |
A comparative study on curing characteristics, mechanical properties, swelling behavior, thermal stability, and Morphology of feldspar and silica in SMR L vulcanizates |
title_full_unstemmed |
A comparative study on curing characteristics, mechanical properties, swelling behavior, thermal stability, and Morphology of feldspar and silica in SMR L vulcanizates |
title_sort |
comparative study on curing characteristics, mechanical properties, swelling behavior, thermal stability, and morphology of feldspar and silica in smr l vulcanizates |
publisher |
Taylor Francis Inc |
publishDate |
2014 |
url |
http://dspace.unimap.edu.my:80/dspace/handle/123456789/35156 |
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1643797738492526592 |
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13.219503 |