Characteristics and adsorption mechanism of Ion-exchange resin for biodiesel production

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Main Author: Muhamad Syahir, Abdul Latiff
Other Authors: Rahimah Othman
Format: Learning Object
Language:English
Published: Universiti Malaysia Perlis (UniMAP) 2013
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Online Access:http://dspace.unimap.edu.my/xmlui/handle/123456789/27745
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spelling my.unimap-277452013-08-27T09:10:01Z Characteristics and adsorption mechanism of Ion-exchange resin for biodiesel production Muhamad Syahir, Abdul Latiff Rahimah Othman Biodiesel Ion-exchange resin Access is limited to UniMAP community. Biodiesel is produced via transesterification process that involved reaction of triglycerides which is the major fatty acid content in crude palm oil (raw material) with methanol and producing Fatty acid Methyl Ester (FAME) and glycerol. The objectives of this study is to determine and optimize process variables for the biodiesel production using Response Surface Method based on Central Composite Design (RSM:CCD). The recomended optimization condition is temperature at 63.43 ºC, stirring speed at approximately 772.83 rpm, reaction time around 120 minutes and molar ratio of methanol : oil at 13:1. Under this operating condition, the model was predicted to get 90.17 % conversion of biodiesel. After demonstrating the suggested model, 89.23 % conversion of biodiesel was obtained experimentally and shows only 1.04% error to predicted conversion was obtained from the real experiments. Then, the suggested optimum process variables were applied for purification steps of biodiesel using DOWEXTM DR-G8 ion exchange resin. The effectiveness and physico-chemical characteristics of utilizing ion-exchange resin as adsorbent in biodiesel production system was been investigated by using Scanning Electron Microscopic (SEM) and Energy Dispersive X-ray (EDX). The investigation on determining the adsorption mechanism also been performed by fitting various kinetic and thermodynamic models determine the best-fit isotherm conditions. Langmuir adsorption isotherm model was founded to fit the adsorption mechanism of ion exchange resin due to highest correlation coefficient, R2 value which is at 0.986. As a conclusion, all the objectives of this study was achieved and shows that ion exchange resin is the best method for purifying crude biodiesel. 2013-08-27T09:10:01Z 2013-08-27T09:10:01Z 2012-06 Learning Object http://hdl.handle.net/123456789/27745 en Universiti Malaysia Perlis (UniMAP) School of Bioprocess Engineering
institution Universiti Malaysia Perlis
building UniMAP Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Perlis
content_source UniMAP Library Digital Repository
url_provider http://dspace.unimap.edu.my/
language English
topic Biodiesel
Ion-exchange resin
spellingShingle Biodiesel
Ion-exchange resin
Muhamad Syahir, Abdul Latiff
Characteristics and adsorption mechanism of Ion-exchange resin for biodiesel production
description Access is limited to UniMAP community.
author2 Rahimah Othman
author_facet Rahimah Othman
Muhamad Syahir, Abdul Latiff
format Learning Object
author Muhamad Syahir, Abdul Latiff
author_sort Muhamad Syahir, Abdul Latiff
title Characteristics and adsorption mechanism of Ion-exchange resin for biodiesel production
title_short Characteristics and adsorption mechanism of Ion-exchange resin for biodiesel production
title_full Characteristics and adsorption mechanism of Ion-exchange resin for biodiesel production
title_fullStr Characteristics and adsorption mechanism of Ion-exchange resin for biodiesel production
title_full_unstemmed Characteristics and adsorption mechanism of Ion-exchange resin for biodiesel production
title_sort characteristics and adsorption mechanism of ion-exchange resin for biodiesel production
publisher Universiti Malaysia Perlis (UniMAP)
publishDate 2013
url http://dspace.unimap.edu.my/xmlui/handle/123456789/27745
_version_ 1643795394686091264
score 13.222552