Systematic Study of the Oxidation of Methane Using Supported Gold Palladium Nanoparticles Under Mild Aqueous Conditions
The oxidation of methane using hydrogen peroxide has been studied using supported gold palladium catalysts prepared using the incipient wetness technique. The effect of reaction conditions and catalyst parameters has been investigated. The supported gold palladium nanoparticles produce methyl hydrop...
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my.ump.umpir.94712018-11-22T07:38:57Z http://umpir.ump.edu.my/id/eprint/9471/ Systematic Study of the Oxidation of Methane Using Supported Gold Palladium Nanoparticles Under Mild Aqueous Conditions Mohd Hasbi, Ab. Rahim Forde, Michael M. Hammond, Ceri Jenkins, Robert L. Dimitratos, Nikolaos Lopez-Sanchez, Jose Antonio Carley, Albert F. Taylor, Stuart H. Willock, David J. Hutchings, Graham J. QD Chemistry TP Chemical technology The oxidation of methane using hydrogen peroxide has been studied using supported gold palladium catalysts prepared using the incipient wetness technique. The effect of reaction conditions and catalyst parameters has been investigated. The supported gold palladium nanoparticles produce methyl hydroperoxide as the primary reaction product which is subsequently converted to methanol with high selectivity, ca. 40–70 %. The selectivity to methanol is influenced by the oxidation state the palladium component of the catalyst. In contrast to homogeneous gold and palladium catalysts the heterogeneous gold palladium nanoalloys are reusable and affords high oxygenate selectivity (ca. 90 %). Springer-Verlag 2013-07-23 Article PeerReviewed Mohd Hasbi, Ab. Rahim and Forde, Michael M. and Hammond, Ceri and Jenkins, Robert L. and Dimitratos, Nikolaos and Lopez-Sanchez, Jose Antonio and Carley, Albert F. and Taylor, Stuart H. and Willock, David J. and Hutchings, Graham J. (2013) Systematic Study of the Oxidation of Methane Using Supported Gold Palladium Nanoparticles Under Mild Aqueous Conditions. Topics In Catalysis, 56. pp. 1843-1857. ISSN 1572-9028 http://dx.doi.org/10.1007/s11244-013-0121-3 DOI: 10.1007/s11244-013-0121-3 |
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QD Chemistry TP Chemical technology Mohd Hasbi, Ab. Rahim Forde, Michael M. Hammond, Ceri Jenkins, Robert L. Dimitratos, Nikolaos Lopez-Sanchez, Jose Antonio Carley, Albert F. Taylor, Stuart H. Willock, David J. Hutchings, Graham J. Systematic Study of the Oxidation of Methane Using Supported Gold Palladium Nanoparticles Under Mild Aqueous Conditions |
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The oxidation of methane using hydrogen peroxide has been studied using supported gold palladium catalysts prepared using the incipient wetness technique. The effect of reaction conditions and catalyst parameters has been investigated. The supported gold palladium nanoparticles produce methyl hydroperoxide as the primary reaction product which is subsequently converted to methanol with high selectivity, ca. 40–70 %. The selectivity to methanol is influenced by the oxidation state the palladium component of the catalyst. In contrast to homogeneous gold and palladium catalysts the heterogeneous gold palladium nanoalloys are reusable and affords high oxygenate selectivity (ca. 90 %). |
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Article |
author |
Mohd Hasbi, Ab. Rahim Forde, Michael M. Hammond, Ceri Jenkins, Robert L. Dimitratos, Nikolaos Lopez-Sanchez, Jose Antonio Carley, Albert F. Taylor, Stuart H. Willock, David J. Hutchings, Graham J. |
author_facet |
Mohd Hasbi, Ab. Rahim Forde, Michael M. Hammond, Ceri Jenkins, Robert L. Dimitratos, Nikolaos Lopez-Sanchez, Jose Antonio Carley, Albert F. Taylor, Stuart H. Willock, David J. Hutchings, Graham J. |
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Mohd Hasbi, Ab. Rahim |
title |
Systematic Study of the Oxidation of Methane Using Supported Gold Palladium Nanoparticles Under Mild Aqueous Conditions |
title_short |
Systematic Study of the Oxidation of Methane Using Supported Gold Palladium Nanoparticles Under Mild Aqueous Conditions |
title_full |
Systematic Study of the Oxidation of Methane Using Supported Gold Palladium Nanoparticles Under Mild Aqueous Conditions |
title_fullStr |
Systematic Study of the Oxidation of Methane Using Supported Gold Palladium Nanoparticles Under Mild Aqueous Conditions |
title_full_unstemmed |
Systematic Study of the Oxidation of Methane Using Supported Gold Palladium Nanoparticles Under Mild Aqueous Conditions |
title_sort |
systematic study of the oxidation of methane using supported gold palladium nanoparticles under mild aqueous conditions |
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Springer-Verlag |
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2013 |
url |
http://umpir.ump.edu.my/id/eprint/9471/ http://dx.doi.org/10.1007/s11244-013-0121-3 |
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1643666138042728448 |
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13.18916 |