Asymmetric Transfer Hydrogenation Catalyzed by Mesoporous MCM-41-Supported Chiral Ru-Complex

• Main Authors: Sarkar, Shaheen M., M. M., Yusoff, Lutfor, M. R.
• Format: Article
• Language: English
• Published: John Wiley & Sons, Inc. 2014
• Subjects: QD Chemistry
• Online Access: http://umpir.ump.edu.my/id/eprint/8109/1/Sha_JCCS_2.pdf; http://umpir.ump.edu.my/id/eprint/8109/

Chiral N-sulfonyldiamine was successfully anchored on mesoporous MCM-41 silica. The MCM-41-supported chiral N-sulfonyldiamine was used as an efficient heterogeneous chiral ligand in the asymmetric transfer hydrogenation of ketones. This heterogeneous system offered satisfactory enantioselectivitie...