Studies on the effect of H+ carrier toward ionic conduction properties in alginate-ammonium sulfate complexes–based polymer electrolytes system
The present work highlights the contribution of ammonium sulfate (NH4)2SO4 as H+ carriers in alginate-based solid polymer electrolytes (SPEs) that were successfully prepared via a solution casting technique. The Fourier transform infrared analysis revealed that molecular interactions between the hos...
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Online Access: | http://umpir.ump.edu.my/id/eprint/37742/1/Studies%20on%20the%20effect%20of%20H%2B%20carrier%20toward%20ionic%20conduction.pdf http://umpir.ump.edu.my/id/eprint/37742/2/Studies%20on%20the%20effect%20of%20H%2B%20carrier%20toward%20ionic%20conduction%20properties%20in%20alginate-ammonium%20sulfate%20complexes%E2%80%93based%20polymer%20electrolytes%20system.pdf http://umpir.ump.edu.my/id/eprint/37742/ https://doi.org/10.1177/09540083221075320 |
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my.ump.umpir.377422023-07-13T01:44:23Z http://umpir.ump.edu.my/id/eprint/37742/ Studies on the effect of H+ carrier toward ionic conduction properties in alginate-ammonium sulfate complexes–based polymer electrolytes system Nurhasniza, M Khan Noor M, Norman Ahmad, S Samsudin T Technology (General) TP Chemical technology The present work highlights the contribution of ammonium sulfate (NH4)2SO4 as H+ carriers in alginate-based solid polymer electrolytes (SPEs) that were successfully prepared via a solution casting technique. The Fourier transform infrared analysis revealed that molecular interactions between the host polymer and the ionic dopant complexes occurred at the wavenumbers 3700–2500 cm-1, 1800–1500 cm-1, and 1200–900 cm-1. These regions corresponded to the O-H stretching, COO− and C-O-C, moieties of alginate, respectively, which coordinated with the H+ carrier from (NH4)2SO4. At ambient temperature, the optimum ionic conductivity was obtained at 3.01 × 10−5 S cm-1 for the sample containing 10 wt.% of (NH4)2SO4. The IR-deconvolution approach shows that the ionic conduction enhancement is governed by the ionic mobility and the diffusion coefficient of H+ carriers, and the findings show that the present biopolymer, which is an alginate-based SPEs system, has an excellent possibility to be used as electrolytes for application in electrochemical devices SAGE Publications Ltd 2022 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/37742/1/Studies%20on%20the%20effect%20of%20H%2B%20carrier%20toward%20ionic%20conduction.pdf pdf en http://umpir.ump.edu.my/id/eprint/37742/2/Studies%20on%20the%20effect%20of%20H%2B%20carrier%20toward%20ionic%20conduction%20properties%20in%20alginate-ammonium%20sulfate%20complexes%E2%80%93based%20polymer%20electrolytes%20system.pdf Nurhasniza, M Khan and Noor M, Norman and Ahmad, S Samsudin (2022) Studies on the effect of H+ carrier toward ionic conduction properties in alginate-ammonium sulfate complexes–based polymer electrolytes system. High Performance Polymers, 34 (6). pp. 637-644. ISSN 0954-0083. (Published) https://doi.org/10.1177/09540083221075320 10.1177/09540083221075320 |
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T Technology (General) TP Chemical technology Nurhasniza, M Khan Noor M, Norman Ahmad, S Samsudin Studies on the effect of H+ carrier toward ionic conduction properties in alginate-ammonium sulfate complexes–based polymer electrolytes system |
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The present work highlights the contribution of ammonium sulfate (NH4)2SO4 as H+ carriers in alginate-based solid polymer electrolytes (SPEs) that were successfully prepared via a solution casting technique. The Fourier transform infrared analysis revealed that molecular interactions between the host polymer and the ionic dopant complexes occurred at the wavenumbers 3700–2500 cm-1, 1800–1500 cm-1, and 1200–900 cm-1. These regions corresponded to the O-H stretching, COO− and C-O-C, moieties of alginate, respectively, which coordinated with the H+ carrier from (NH4)2SO4. At ambient temperature, the optimum ionic conductivity was obtained at 3.01 × 10−5 S cm-1 for the sample containing 10 wt.% of (NH4)2SO4. The IR-deconvolution approach shows that the ionic conduction enhancement is governed by the ionic mobility and the diffusion coefficient of H+ carriers, and the findings show that the present biopolymer, which is an alginate-based SPEs system, has an excellent possibility to be used as electrolytes for application in electrochemical devices |
format |
Article |
author |
Nurhasniza, M Khan Noor M, Norman Ahmad, S Samsudin |
author_facet |
Nurhasniza, M Khan Noor M, Norman Ahmad, S Samsudin |
author_sort |
Nurhasniza, M Khan |
title |
Studies on the effect of H+ carrier toward ionic conduction properties in alginate-ammonium sulfate complexes–based polymer electrolytes system |
title_short |
Studies on the effect of H+ carrier toward ionic conduction properties in alginate-ammonium sulfate complexes–based polymer electrolytes system |
title_full |
Studies on the effect of H+ carrier toward ionic conduction properties in alginate-ammonium sulfate complexes–based polymer electrolytes system |
title_fullStr |
Studies on the effect of H+ carrier toward ionic conduction properties in alginate-ammonium sulfate complexes–based polymer electrolytes system |
title_full_unstemmed |
Studies on the effect of H+ carrier toward ionic conduction properties in alginate-ammonium sulfate complexes–based polymer electrolytes system |
title_sort |
studies on the effect of h+ carrier toward ionic conduction properties in alginate-ammonium sulfate complexes–based polymer electrolytes system |
publisher |
SAGE Publications Ltd |
publishDate |
2022 |
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http://umpir.ump.edu.my/id/eprint/37742/1/Studies%20on%20the%20effect%20of%20H%2B%20carrier%20toward%20ionic%20conduction.pdf http://umpir.ump.edu.my/id/eprint/37742/2/Studies%20on%20the%20effect%20of%20H%2B%20carrier%20toward%20ionic%20conduction%20properties%20in%20alginate-ammonium%20sulfate%20complexes%E2%80%93based%20polymer%20electrolytes%20system.pdf http://umpir.ump.edu.my/id/eprint/37742/ https://doi.org/10.1177/09540083221075320 |
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13.18916 |