Thermodynamic and experimental explorations of CO2 methanation over highly active metal-free fibrous silica-beta zeolite (FS@SiO2-BEA) of innovative morphology

• Main Authors: Hussain, I., A. A., Jalil, S. M., Izan, M. S., Azami, K., Kidam, Nurul Aini, Razali, A., Ripin
• Format: Article
• Language: English; English
• Published: Elsevier 2021
• Subjects: TP Chemical technology
• Online Access: http://umpir.ump.edu.my/id/eprint/29707/1/Thermodynamic%20and%20experimental%20explorations%20of%20CO2%20methanation%20over%20highly%20.pdf; http://umpir.ump.edu.my/id/eprint/29707/2/Thermodynamic%20and%20experimental%20explorations%20of%20CO2%20methanation%20over%20highly_FULL.pdf; http://umpir.ump.edu.my/id/eprint/29707/; https://doi.org/10.1016/j.ces.2020.116015; https://doi.org/10.1016/j.ces.2020.116015

CO2 methanation is a novel way for climate change mitigation by converting CO2 into substitute natural gas. In this study, a highly active fibrous silica-beta zeolite (FS@SiO2-BEA) catalyst was prepared for CO2 methanation by a microemulsion process, and examined by N2 adsorption–desorption, field emission scanning electron microscope (FESEM), transmission electron microscopy (TEM), and electron spin resonance (ESR) spectroscopy techniques. It was found that the FS@SiO2-BEA catalyst possessed a fibrous silica morphology, leading to high surface area (609 m2/g), oxygen vacancies, and basicity. A thermodynamic study was also carried out using Gibbs free energy minimization method, and it was found that low temperatures (25–350 °C) and high H2: CO2 ≥ 4 ratios have enhanced the CO2 methanation activity. The prepared FS@SiO2-BEA catalyst exhibited high CO2 conversion (65%), and CH4 selectivity (61%) with a space–time yield of 3.30 g gcat−1 h−1. The obtained experimental results highly followed the thermodynamic calculations.