Synthesis of alumina-CaO-KI catalyst for the production of biodiesel from rubber seed oil [Sintesis mangkin alumina-CaO-KI untuk penghasilan biodiesel daripada minyak biji getah]
In this research, biodiesel was produced by transesterification of rubber seed oil with methanol catalyzed by three types of alumina-supported catalyst. The catalysts were Al2O3 -CaO, Al2O3 -KI, and Al2O3 -CaO-KI. The catalysts were prepared by heating a mixture of alumina and the corresponding salt...
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Universiti Kebangsaan Malaysia
2018
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Online Access: | http://umpir.ump.edu.my/id/eprint/21626/1/Synthesis%20of%20alumina-cao-ki%20catalyst%20for%20the%20production%20of%20biodiesel%20from%20rubber%20seed%20oil.pdf http://umpir.ump.edu.my/id/eprint/21626/ http://www.ukm.my/mjas/v22_n2/pdf/ZainalKifli_22_2_13.pdf |
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my.ump.umpir.216262018-09-14T04:23:46Z http://umpir.ump.edu.my/id/eprint/21626/ Synthesis of alumina-CaO-KI catalyst for the production of biodiesel from rubber seed oil [Sintesis mangkin alumina-CaO-KI untuk penghasilan biodiesel daripada minyak biji getah] Abdul Razak, Zainal Kifli Shahida Hanum, Kamarullah Siti Norhafiza, Mohd Khazaai Gaanty Pragas, Maniam Q Science (General) In this research, biodiesel was produced by transesterification of rubber seed oil with methanol catalyzed by three types of alumina-supported catalyst. The catalysts were Al2O3 -CaO, Al2O3 -KI, and Al2O3 -CaO-KI. The catalysts were prepared by heating a mixture of alumina and the corresponding salt in a furnace at 700 oC. Transesterification reactions were carried out at 65 °C using a mixture of rubber seed oil: methanol of mass ratio 1:9 with different catalyst loadings between 0 and 3.5%. The optimum catalyst loading was at 2.0% for all types of catalyst and Al2O3 -CaO-KI gave the highest yield (91.6%) followed by Al2O3 -KI (90.7%) and Al2O3 -CaO (63.5%). The catalyst Al2O3 -CaO-KI also gave high biodiesel yields over a wider range of catalyst loadings compared to the other two catalysts. Reactions were also carried out at different temperatures (25, 40 and 65°C). It was observed that the yield increased drastically with increasing reaction temperature. At all temperatures the Al2O3 -CaO-KI catalyst gave the highest yield. Therefore, the study showed that among these three catalysts the most productive was Al2O3 -CaO-KI, (100:30:35). Universiti Kebangsaan Malaysia 2018-04 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/21626/1/Synthesis%20of%20alumina-cao-ki%20catalyst%20for%20the%20production%20of%20biodiesel%20from%20rubber%20seed%20oil.pdf Abdul Razak, Zainal Kifli and Shahida Hanum, Kamarullah and Siti Norhafiza, Mohd Khazaai and Gaanty Pragas, Maniam (2018) Synthesis of alumina-CaO-KI catalyst for the production of biodiesel from rubber seed oil [Sintesis mangkin alumina-CaO-KI untuk penghasilan biodiesel daripada minyak biji getah]. Malaysian Journal of Analytical Sciences, 22 (2). pp. 279-285. ISSN 1394-2506 http://www.ukm.my/mjas/v22_n2/pdf/ZainalKifli_22_2_13.pdf 10.17576/mjas-2018-2202-13 |
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Q Science (General) Abdul Razak, Zainal Kifli Shahida Hanum, Kamarullah Siti Norhafiza, Mohd Khazaai Gaanty Pragas, Maniam Synthesis of alumina-CaO-KI catalyst for the production of biodiesel from rubber seed oil [Sintesis mangkin alumina-CaO-KI untuk penghasilan biodiesel daripada minyak biji getah] |
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In this research, biodiesel was produced by transesterification of rubber seed oil with methanol catalyzed by three types of alumina-supported catalyst. The catalysts were Al2O3 -CaO, Al2O3 -KI, and Al2O3 -CaO-KI. The catalysts were prepared by heating a mixture of alumina and the corresponding salt in a furnace at 700 oC. Transesterification reactions were carried out at 65 °C using a mixture of rubber seed oil: methanol of mass ratio 1:9 with different catalyst loadings between 0 and 3.5%. The optimum catalyst loading was at 2.0% for all types of catalyst and Al2O3 -CaO-KI gave the highest yield (91.6%) followed by Al2O3 -KI (90.7%) and Al2O3 -CaO (63.5%). The catalyst Al2O3 -CaO-KI also gave high biodiesel yields over a wider range of catalyst loadings compared to the other two catalysts. Reactions were also carried out at different temperatures (25, 40 and 65°C). It was observed that the yield increased drastically with increasing reaction temperature. At all temperatures the Al2O3 -CaO-KI catalyst gave the highest yield. Therefore, the study showed that among these three catalysts the most productive was Al2O3 -CaO-KI, (100:30:35). |
format |
Article |
author |
Abdul Razak, Zainal Kifli Shahida Hanum, Kamarullah Siti Norhafiza, Mohd Khazaai Gaanty Pragas, Maniam |
author_facet |
Abdul Razak, Zainal Kifli Shahida Hanum, Kamarullah Siti Norhafiza, Mohd Khazaai Gaanty Pragas, Maniam |
author_sort |
Abdul Razak, Zainal Kifli |
title |
Synthesis of alumina-CaO-KI catalyst for the production of biodiesel from rubber seed oil [Sintesis mangkin alumina-CaO-KI untuk penghasilan biodiesel daripada minyak biji getah] |
title_short |
Synthesis of alumina-CaO-KI catalyst for the production of biodiesel from rubber seed oil [Sintesis mangkin alumina-CaO-KI untuk penghasilan biodiesel daripada minyak biji getah] |
title_full |
Synthesis of alumina-CaO-KI catalyst for the production of biodiesel from rubber seed oil [Sintesis mangkin alumina-CaO-KI untuk penghasilan biodiesel daripada minyak biji getah] |
title_fullStr |
Synthesis of alumina-CaO-KI catalyst for the production of biodiesel from rubber seed oil [Sintesis mangkin alumina-CaO-KI untuk penghasilan biodiesel daripada minyak biji getah] |
title_full_unstemmed |
Synthesis of alumina-CaO-KI catalyst for the production of biodiesel from rubber seed oil [Sintesis mangkin alumina-CaO-KI untuk penghasilan biodiesel daripada minyak biji getah] |
title_sort |
synthesis of alumina-cao-ki catalyst for the production of biodiesel from rubber seed oil [sintesis mangkin alumina-cao-ki untuk penghasilan biodiesel daripada minyak biji getah] |
publisher |
Universiti Kebangsaan Malaysia |
publishDate |
2018 |
url |
http://umpir.ump.edu.my/id/eprint/21626/1/Synthesis%20of%20alumina-cao-ki%20catalyst%20for%20the%20production%20of%20biodiesel%20from%20rubber%20seed%20oil.pdf http://umpir.ump.edu.my/id/eprint/21626/ http://www.ukm.my/mjas/v22_n2/pdf/ZainalKifli_22_2_13.pdf |
_version_ |
1643669176908251136 |
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13.18916 |