A Novel Graphene-Supported Palladium Catalyst for Suzuki–Miyaura Coupling of Less Reactive Heteroaryl Halides in Water

An efficient reduced graphene oxide-supported heterogenized palladium complex with pyrene-tagged ketoiminato ligand has been developed and used for cross-coupling of less reactive heteroaryl halides in water. Desirable catalytic activity was observed with high (up to 98%) conversion of the less reac...

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Bibliographic Details
Main Authors: Abu, Taher, Lee, Dong-Jin, Lee, Ik-Mo, Lutfor, M. R., Sarkar, Shaheen M.
Format: Article
Language:English
English
Published: Korean Chemical Society, Seoul & Wiley-VCH 2016
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Online Access:http://umpir.ump.edu.my/id/eprint/16779/1/Bul%20Korean%20Chem%20Soc.pdf
http://umpir.ump.edu.my/id/eprint/16779/7/fist-29016-shaheen-novel%20graphene1.pdf
http://umpir.ump.edu.my/id/eprint/16779/
http://dx.doi.org/10.1002/bkcs.10894
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Summary:An efficient reduced graphene oxide-supported heterogenized palladium complex with pyrene-tagged ketoiminato ligand has been developed and used for cross-coupling of less reactive heteroaryl halides in water. Desirable catalytic activity was observed with high (up to 98%) conversion of the less reactive reactants under relatively mild conditions. The efficiency and green nature of the catalyst were confirmed without significant loss of activity.