Tetra-kis(triphenyl-arsane-κAs)silver(I) trifluoro-acetate hemihydrate methanol hemisolvate
The Ag(I) atom in the title hydrated solvated salt, [Ag(C18H15As)4](CF3CO2)·0.5CH3OH·0.5H2O, is coordinated by four As atoms from triphenyl-arsane ligands in a distorted tetra-hedral geometry. In the crystal, O-H⋯O hydrogen bonding occurs between carboxyl-ate groups of anions and lattice solvent mol...
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| Online Access: | http://eprints.um.edu.my/8591/ http://www.ncbi.nlm.nih.gov/pubmed/23468745 http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588780/ |
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my.um.eprints.85912013-12-03T01:39:54Z http://eprints.um.edu.my/8591/ Tetra-kis(triphenyl-arsane-κAs)silver(I) trifluoro-acetate hemihydrate methanol hemisolvate Ng, S.W. R Medicine The Ag(I) atom in the title hydrated solvated salt, [Ag(C18H15As)4](CF3CO2)·0.5CH3OH·0.5H2O, is coordinated by four As atoms from triphenyl-arsane ligands in a distorted tetra-hedral geometry. In the crystal, O-H⋯O hydrogen bonding occurs between carboxyl-ate groups of anions and lattice solvent mol-ecules. Of the four triphenyl-arsane ligands in the Ag complex cation, two each have an equally disordered phenyl ring while the trifluoro-acetate anion is disordered over two positions with respect to the lattice methanol and water mol-ecules which both show half-occupyncy. The crystal studied was a non-merohedral twin with a 13.6 (1)% contribution of the minor twin component. 2012 Article PeerReviewed Ng, S.W. (2012) Tetra-kis(triphenyl-arsane-κAs)silver(I) trifluoro-acetate hemihydrate methanol hemisolvate. Acta Crystallographica Section E: Structure Reports Online. ISSN 1600-5368 http://www.ncbi.nlm.nih.gov/pubmed/23468745 http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588780/ |
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R Medicine Ng, S.W. Tetra-kis(triphenyl-arsane-κAs)silver(I) trifluoro-acetate hemihydrate methanol hemisolvate |
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The Ag(I) atom in the title hydrated solvated salt, [Ag(C18H15As)4](CF3CO2)·0.5CH3OH·0.5H2O, is coordinated by four As atoms from triphenyl-arsane ligands in a distorted tetra-hedral geometry. In the crystal, O-H⋯O hydrogen bonding occurs between carboxyl-ate groups of anions and lattice solvent mol-ecules. Of the four triphenyl-arsane ligands in the Ag complex cation, two each have an equally disordered phenyl ring while the trifluoro-acetate anion is disordered over two positions with respect to the lattice methanol and water mol-ecules which both show half-occupyncy. The crystal studied was a non-merohedral twin with a 13.6 (1)% contribution of the minor twin component.
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| format |
Article |
| author |
Ng, S.W. |
| author_facet |
Ng, S.W. |
| author_sort |
Ng, S.W. |
| title |
Tetra-kis(triphenyl-arsane-κAs)silver(I) trifluoro-acetate hemihydrate methanol hemisolvate |
| title_short |
Tetra-kis(triphenyl-arsane-κAs)silver(I) trifluoro-acetate hemihydrate methanol hemisolvate |
| title_full |
Tetra-kis(triphenyl-arsane-κAs)silver(I) trifluoro-acetate hemihydrate methanol hemisolvate |
| title_fullStr |
Tetra-kis(triphenyl-arsane-κAs)silver(I) trifluoro-acetate hemihydrate methanol hemisolvate |
| title_full_unstemmed |
Tetra-kis(triphenyl-arsane-κAs)silver(I) trifluoro-acetate hemihydrate methanol hemisolvate |
| title_sort |
tetra-kis(triphenyl-arsane-κas)silver(i) trifluoro-acetate hemihydrate methanol hemisolvate |
| publishDate |
2012 |
| url |
http://eprints.um.edu.my/8591/ http://www.ncbi.nlm.nih.gov/pubmed/23468745 http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588780/ |
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