Poly[(μ(3)-nicotinato-κO:O':N)(μ(2)-nicotinato-κO,O':N)iron(II)].

In the crystal structure of the title compound, [Fe(C(6)H(4)NO(2))(2)](n), one nicotinate group O,O'-chelates one Fe atom and binds through the N atom to the other Fe atom; the second nicotinate group bridges three Fe atoms through the N and two O atoms. The μ(2)- and μ(3)-bridging modes of the...

全面介紹

Saved in:
書目詳細資料
主要作者: Ng, S.W.
格式: Article
出版: International Union of Crystallography 2008
主題:
在線閱讀:http://eprints.um.edu.my/858/
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961197/
標簽: 添加標簽
沒有標簽, 成為第一個標記此記錄!
實物特徵
總結:In the crystal structure of the title compound, [Fe(C(6)H(4)NO(2))(2)](n), one nicotinate group O,O'-chelates one Fe atom and binds through the N atom to the other Fe atom; the second nicotinate group bridges three Fe atoms through the N and two O atoms. The μ(2)- and μ(3)-bridging modes of the two nicotinate groups result in a polymeric three-dimensional network structure. The Fe atom shows octa-hedral coordination geometry but one of the Fe-O bonds is somewhat long [2.522 (2) Å].