The effect of Fe substitution on pyroelectric properties of 0.62Pb(Mg1/3Nb2/3)O-3-0.38PbTiO(3) single crystals
Fe-doped 0.62Pb(Mg1/3Nb2/3)O-3-0.38PbTiO(3) (PMN-0.38PT) single crystals with two different dopant concentrations, 0.2 and 1.0 mol %, were grown by a modified Bridgman technique. The effect of Fe substitution on dielectric and pyroelectric properties was examined. The dielectric constant of the 0.2...
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my.um.eprints.82182019-08-27T07:34:09Z http://eprints.um.edu.my/8218/ The effect of Fe substitution on pyroelectric properties of 0.62Pb(Mg1/3Nb2/3)O-3-0.38PbTiO(3) single crystals Chew, Khian Hooi Luo, H.S. Wan, X.M. Chan, H.L.W. Choy, C.L. Zhao, X.Y. QC Physics Fe-doped 0.62Pb(Mg1/3Nb2/3)O-3-0.38PbTiO(3) (PMN-0.38PT) single crystals with two different dopant concentrations, 0.2 and 1.0 mol %, were grown by a modified Bridgman technique. The effect of Fe substitution on dielectric and pyroelectric properties was examined. The dielectric constant of the 0.2 mol % Fe-doped PMN-0.38PT single crystal was controlled successfully, indicating the possibility of tuning the dielectric properties by doping with a small concentration of iron ions. The mechanism of doping effect was also discussed based on the principles of crystal chemistry. The pyroelectric response of the single crystals was measured using a dynamic method from 20 to 50 degrees C. Compared with the 1.0 mol % Fe-doped single crystal, the 0.2 mol % Fe-doped sample possesses the better pyroelectric properties. At room temperature, the pyroelectric coefficient and detectivity figure of merit (F-D) for the 0.2 mol % Fe-doped sample are 568 mu C/m(2) K and 53 mu Pa-1/2, respectively, and they increase slightly with temperature increasing. These excellent pyroelectric properties as well as being able to produce large-size and high-quality single crystals make this kind of single crystal a promising candidate for high-performance infrared detectors and other pyroelectric applications. (C) 2005 American Institute of Physics. 2005 Article PeerReviewed application/pdf en http://eprints.um.edu.my/8218/1/Wan-2005-The_effect_of_Fe_sub.pdf Chew, Khian Hooi and Luo, H.S. and Wan, X.M. and Chan, H.L.W. and Choy, C.L. and Zhao, X.Y. (2005) The effect of Fe substitution on pyroelectric properties of 0.62Pb(Mg1/3Nb2/3)O-3-0.38PbTiO(3) single crystals. Journal of Applied Physics, 97 (6). ISSN 0021-8979 http://scitation.aip.org/getpdf/servlet/GetPDFServlet?filetype=pdf&id=JAPIAU000097000006064105000001&idtype=cvips&doi=10.1063/1.1862320&prog=normal 10.1063/1.1862320 |
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QC Physics Chew, Khian Hooi Luo, H.S. Wan, X.M. Chan, H.L.W. Choy, C.L. Zhao, X.Y. The effect of Fe substitution on pyroelectric properties of 0.62Pb(Mg1/3Nb2/3)O-3-0.38PbTiO(3) single crystals |
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Fe-doped 0.62Pb(Mg1/3Nb2/3)O-3-0.38PbTiO(3) (PMN-0.38PT) single crystals with two different dopant concentrations, 0.2 and 1.0 mol %, were grown by a modified Bridgman technique. The effect of Fe substitution on dielectric and pyroelectric properties was examined. The dielectric constant of the 0.2 mol % Fe-doped PMN-0.38PT single crystal was controlled successfully, indicating the possibility of tuning the dielectric properties by doping with a small concentration of iron ions. The mechanism of doping effect was also discussed based on the principles of crystal chemistry. The pyroelectric response of the single crystals was measured using a dynamic method from 20 to 50 degrees C. Compared with the 1.0 mol % Fe-doped single crystal, the 0.2 mol % Fe-doped sample possesses the better pyroelectric properties. At room temperature, the pyroelectric coefficient and detectivity figure of merit (F-D) for the 0.2 mol % Fe-doped sample are 568 mu C/m(2) K and 53 mu Pa-1/2, respectively, and they increase slightly with temperature increasing. These excellent pyroelectric properties as well as being able to produce large-size and high-quality single crystals make this kind of single crystal a promising candidate for high-performance infrared detectors and other pyroelectric applications. (C) 2005 American Institute of Physics. |
format |
Article |
author |
Chew, Khian Hooi Luo, H.S. Wan, X.M. Chan, H.L.W. Choy, C.L. Zhao, X.Y. |
author_facet |
Chew, Khian Hooi Luo, H.S. Wan, X.M. Chan, H.L.W. Choy, C.L. Zhao, X.Y. |
author_sort |
Chew, Khian Hooi |
title |
The effect of Fe substitution on pyroelectric properties of 0.62Pb(Mg1/3Nb2/3)O-3-0.38PbTiO(3) single crystals |
title_short |
The effect of Fe substitution on pyroelectric properties of 0.62Pb(Mg1/3Nb2/3)O-3-0.38PbTiO(3) single crystals |
title_full |
The effect of Fe substitution on pyroelectric properties of 0.62Pb(Mg1/3Nb2/3)O-3-0.38PbTiO(3) single crystals |
title_fullStr |
The effect of Fe substitution on pyroelectric properties of 0.62Pb(Mg1/3Nb2/3)O-3-0.38PbTiO(3) single crystals |
title_full_unstemmed |
The effect of Fe substitution on pyroelectric properties of 0.62Pb(Mg1/3Nb2/3)O-3-0.38PbTiO(3) single crystals |
title_sort |
effect of fe substitution on pyroelectric properties of 0.62pb(mg1/3nb2/3)o-3-0.38pbtio(3) single crystals |
publishDate |
2005 |
url |
http://eprints.um.edu.my/8218/1/Wan-2005-The_effect_of_Fe_sub.pdf http://eprints.um.edu.my/8218/ http://scitation.aip.org/getpdf/servlet/GetPDFServlet?filetype=pdf&id=JAPIAU000097000006064105000001&idtype=cvips&doi=10.1063/1.1862320&prog=normal |
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1643688250159661056 |
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13.201949 |