Determination of pKa of ammonium and phenolic groups: Evidence of intramolecular hydrogen bonding in aqueous solution

The ionization constants of 2-hydroxyanilinium, 2-methoxyanilinium, 4-nitroanilinium ions, N-(2′-hydroxyphenyl)-phthalamic acid and N-(2′-methoxyphenyl) phthalamic acid, determined spectrophotometrically, have been rationalized in terms of internal hydrogen bonding and steric hindrance between o-sub...

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Main Authors: Ariffin, Azhar, Khan, Mohammad Niyaz, Sim, Y.L., Ahmad, W.H.W.
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Published: 2008
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Online Access:http://eprints.um.edu.my/8065/
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spelling my.um.eprints.80652019-08-27T04:53:51Z http://eprints.um.edu.my/8065/ Determination of pKa of ammonium and phenolic groups: Evidence of intramolecular hydrogen bonding in aqueous solution Ariffin, Azhar Khan, Mohammad Niyaz Sim, Y.L. Ahmad, W.H.W. QD Chemistry The ionization constants of 2-hydroxyanilinium, 2-methoxyanilinium, 4-nitroanilinium ions, N-(2′-hydroxyphenyl)-phthalamic acid and N-(2′-methoxyphenyl) phthalamic acid, determined spectrophotometrically, have been rationalized in terms of internal hydrogen bonding and steric hindrance between o-substituent and reaction site. 2008 Article PeerReviewed Ariffin, Azhar and Khan, Mohammad Niyaz and Sim, Y.L. and Ahmad, W.H.W. (2008) Determination of pKa of ammonium and phenolic groups: Evidence of intramolecular hydrogen bonding in aqueous solution. Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 47 (2). pp. 240-245. ISSN 0376-4710 http://www.scopus.com/inward/record.url?eid=2-s2.0-42249106609&partnerID=40&md5=69a41b4e053dbf274c0d355ae8e8d042
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QD Chemistry
spellingShingle QD Chemistry
Ariffin, Azhar
Khan, Mohammad Niyaz
Sim, Y.L.
Ahmad, W.H.W.
Determination of pKa of ammonium and phenolic groups: Evidence of intramolecular hydrogen bonding in aqueous solution
description The ionization constants of 2-hydroxyanilinium, 2-methoxyanilinium, 4-nitroanilinium ions, N-(2′-hydroxyphenyl)-phthalamic acid and N-(2′-methoxyphenyl) phthalamic acid, determined spectrophotometrically, have been rationalized in terms of internal hydrogen bonding and steric hindrance between o-substituent and reaction site.
format Article
author Ariffin, Azhar
Khan, Mohammad Niyaz
Sim, Y.L.
Ahmad, W.H.W.
author_facet Ariffin, Azhar
Khan, Mohammad Niyaz
Sim, Y.L.
Ahmad, W.H.W.
author_sort Ariffin, Azhar
title Determination of pKa of ammonium and phenolic groups: Evidence of intramolecular hydrogen bonding in aqueous solution
title_short Determination of pKa of ammonium and phenolic groups: Evidence of intramolecular hydrogen bonding in aqueous solution
title_full Determination of pKa of ammonium and phenolic groups: Evidence of intramolecular hydrogen bonding in aqueous solution
title_fullStr Determination of pKa of ammonium and phenolic groups: Evidence of intramolecular hydrogen bonding in aqueous solution
title_full_unstemmed Determination of pKa of ammonium and phenolic groups: Evidence of intramolecular hydrogen bonding in aqueous solution
title_sort determination of pka of ammonium and phenolic groups: evidence of intramolecular hydrogen bonding in aqueous solution
publishDate 2008
url http://eprints.um.edu.my/8065/
http://www.scopus.com/inward/record.url?eid=2-s2.0-42249106609&partnerID=40&md5=69a41b4e053dbf274c0d355ae8e8d042
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score 13.160551