Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa4 N1,N4,N8,N11)copper(II) didecanoate dihydrate
The CuII atom in the title salt, [Cu(C(10)H(24)N(4))(H(2)O)(2)][CH(3)(CH(2))(8)CO(2)](2)center dot 2H(2)O, is chelated by the four N atoms of the 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand and is coordinated by two water molecules in a Jahn-Teller-type tetragonally distorted octahedral geomet...
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Main Authors: | , , , , |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2010
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Subjects: | |
Online Access: | http://eprints.um.edu.my/8031/1/Tajidi-2010-Diaqua%281%2C4%2C8%2C11-tetr.pdf http://eprints.um.edu.my/8031/ http://journals.iucr.org/e/issues/2010/08/00/bt5286/bt5286.pdf |
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Summary: | The CuII atom in the title salt, [Cu(C(10)H(24)N(4))(H(2)O)(2)][CH(3)(CH(2))(8)CO(2)](2)center dot 2H(2)O, is chelated by the four N atoms of the 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand and is coordinated by two water molecules in a Jahn-Teller-type tetragonally distorted octahedral geometry. The CuII atom lies on a center of inversion. The cations, anions and uncoordinated water molecules are linked by N-H...O and O-H...O hydrogen bonds, forming a layer structure parallel to (001). |
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