(2-1,1-Bis(hydroxy-meth-yl)-2-oxidoeth-ylimino-meth-yl-4-chloro-phenolato-kap paN,O,O')dibutyl-tin(IV)
The Schiff base ligand in the title compound, Sn(C4H 9)2(C11H12ClNO4), chelates to the Sn atom through the two deprotonated O atoms, as well as through the N atom, to confer an overall cis-C2SnNO2 trigonal-bipyramidal geometry at tin C - Sn - C = 130.3 (1)°. The hydr-oxy groups engage in O - H�O...
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International Union of Crystallography
2010
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Online Access: | http://eprints.um.edu.my/6838/1/2%2C2%E2%80%B2-Diethoxy-4%2C4%E2%80%B2-%5B%28E%2C_E%29-hydrazinediyl-_idenebis%28methanylylidene%29%5Ddiphenol.pdf http://eprints.um.edu.my/6838/ |
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my.um.eprints.68382019-01-31T06:31:49Z http://eprints.um.edu.my/6838/ (2-1,1-Bis(hydroxy-meth-yl)-2-oxidoeth-ylimino-meth-yl-4-chloro-phenolato-kap paN,O,O')dibutyl-tin(IV) Reisi, R. Misran, Misni Lo, K.M. Ng, S.W. QD Chemistry The Schiff base ligand in the title compound, Sn(C4H 9)2(C11H12ClNO4), chelates to the Sn atom through the two deprotonated O atoms, as well as through the N atom, to confer an overall cis-C2SnNO2 trigonal-bipyramidal geometry at tin C - Sn - C = 130.3 (1)°. The hydr-oxy groups engage in O - H�O hydrogen bonding with the O atoms of adjacent mol-ecules, generating a chain running along the c axis. International Union of Crystallography 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/6838/1/2%2C2%E2%80%B2-Diethoxy-4%2C4%E2%80%B2-%5B%28E%2C_E%29-hydrazinediyl-_idenebis%28methanylylidene%29%5Ddiphenol.pdf Reisi, R. and Misran, Misni and Lo, K.M. and Ng, S.W. (2010) (2-1,1-Bis(hydroxy-meth-yl)-2-oxidoeth-ylimino-meth-yl-4-chloro-phenolato-kap paN,O,O')dibutyl-tin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (4). m482. ISSN 1600-5368 10.1107/S1600536810011384 |
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QD Chemistry Reisi, R. Misran, Misni Lo, K.M. Ng, S.W. (2-1,1-Bis(hydroxy-meth-yl)-2-oxidoeth-ylimino-meth-yl-4-chloro-phenolato-kap paN,O,O')dibutyl-tin(IV) |
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The Schiff base ligand in the title compound, Sn(C4H 9)2(C11H12ClNO4), chelates to the Sn atom through the two deprotonated O atoms, as well as through the N atom, to confer an overall cis-C2SnNO2 trigonal-bipyramidal geometry at tin C - Sn - C = 130.3 (1)°. The hydr-oxy groups engage in O - H�O hydrogen bonding with the O atoms of adjacent mol-ecules, generating a chain running along the c axis. |
format |
Article |
author |
Reisi, R. Misran, Misni Lo, K.M. Ng, S.W. |
author_facet |
Reisi, R. Misran, Misni Lo, K.M. Ng, S.W. |
author_sort |
Reisi, R. |
title |
(2-1,1-Bis(hydroxy-meth-yl)-2-oxidoeth-ylimino-meth-yl-4-chloro-phenolato-kap paN,O,O')dibutyl-tin(IV) |
title_short |
(2-1,1-Bis(hydroxy-meth-yl)-2-oxidoeth-ylimino-meth-yl-4-chloro-phenolato-kap paN,O,O')dibutyl-tin(IV) |
title_full |
(2-1,1-Bis(hydroxy-meth-yl)-2-oxidoeth-ylimino-meth-yl-4-chloro-phenolato-kap paN,O,O')dibutyl-tin(IV) |
title_fullStr |
(2-1,1-Bis(hydroxy-meth-yl)-2-oxidoeth-ylimino-meth-yl-4-chloro-phenolato-kap paN,O,O')dibutyl-tin(IV) |
title_full_unstemmed |
(2-1,1-Bis(hydroxy-meth-yl)-2-oxidoeth-ylimino-meth-yl-4-chloro-phenolato-kap paN,O,O')dibutyl-tin(IV) |
title_sort |
(2-1,1-bis(hydroxy-meth-yl)-2-oxidoeth-ylimino-meth-yl-4-chloro-phenolato-kap pan,o,o')dibutyl-tin(iv) |
publisher |
International Union of Crystallography |
publishDate |
2010 |
url |
http://eprints.um.edu.my/6838/1/2%2C2%E2%80%B2-Diethoxy-4%2C4%E2%80%B2-%5B%28E%2C_E%29-hydrazinediyl-_idenebis%28methanylylidene%29%5Ddiphenol.pdf http://eprints.um.edu.my/6838/ |
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1643687895658135552 |
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13.160551 |