Synthesis and Characterization of Sot-Gel Derived Single-Phase PZT Nanoparticles in Aqueous Polyol Solution

• Main Authors: Zak, A.K., Abd Majid, Wan Haliza, Darroudi, M.
• Format: Article
• Language: English
• Published: 2010
• Subjects: QC Physics
• Online Access: http://eprints.um.edu.my/5723/1/Synthesis_and_characterization_of_sot-gel_derived_single-phase_PZT_nanoparticles_in_aqueous_polyol_solution.pdf; http://eprints.um.edu.my/5723/

Lead zirconate titanate nanoparticles (PZT-NPs) were synthesized by the modified sol-gel method in aqueous poly ethylene glycol (PEG) solutions. The mixed metal alkoxide precursor was prepared by moderate refluxing using lead acetate, zirconium n-propoxide, titanium iso-propoxide and acetic acid in aqueous PEG media. The properties of PZT-NPs were studied as a function of calcination temperatures. Results from the Fourier transform infrared (FTIR), powder X-ray diffraction (XRD) and thermal analysis (TGA/DTA), indicated that the single-phase perovskite PZT-NPs were obtained after heat treatment at temperature of 650 degrees C. The average particle size of synthesized PZT-NPs was calculated by using the Debye-Scherrer formula and was found to be around 25 nm, which was in a good agreement with the microstructures obtained performed by scanning electron microscopy (SEM) and transition electron microscopy (TEM).