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{4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate

The crystal structure of the title compound, [Ni(C15H 10Cl2-N2O2)(C5H 5N)3]·C5H5N, is built of molecules of a mononuclear nickel complex and uncoordinated solvent pyridine molecules. The NiII atom in the complex is coordinated by two O and one N atoms of the meridional tridentate ligand, viz. the tw...

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Main Authors: Ali, Hapipah Mohd, Yamin, B.M., Basirun, Wan Jefrey, Khamis, N.A.
Format: Article
Published: International Union of Crystallography 2004
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/5635/
http://www.scopus.com/inward/record.url?eid=2-s2.0-18444415795&partnerID=40&md5=0e726f4566e1d1bfe645759e76c12b9d
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spelling my.um.eprints.56352019-01-31T06:42:01Z http://eprints.um.edu.my/5635/ {4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate Ali, Hapipah Mohd Yamin, B.M. Basirun, Wan Jefrey Khamis, N.A. QD Chemistry The crystal structure of the title compound, [Ni(C15H 10Cl2-N2O2)(C5H 5N)3]·C5H5N, is built of molecules of a mononuclear nickel complex and uncoordinated solvent pyridine molecules. The NiII atom in the complex is coordinated by two O and one N atoms of the meridional tridentate ligand, viz. the twice deprotonated hydrazone formed from 2-hydroxy-5-chloroacetophenone and p-chlorobenzhydrazide. The remaining three coordination sites of the Ni octahedron are occupied by three coordinated pyridine ligands. © 2004 International Union of Crystallography Prinled in Great Britain - all rights reserved. International Union of Crystallography 2004 Article PeerReviewed Ali, Hapipah Mohd and Yamin, B.M. and Basirun, Wan Jefrey and Khamis, N.A. (2004) {4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate. Acta Crystallographica Section E: Structure Reports Online, 60 (9). m1351-m1352. ISSN 1600-5368 http://www.scopus.com/inward/record.url?eid=2-s2.0-18444415795&partnerID=40&md5=0e726f4566e1d1bfe645759e76c12b9d 10.1107/S1600536804020756
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QD Chemistry
spellingShingle QD Chemistry
Ali, Hapipah Mohd
Yamin, B.M.
Basirun, Wan Jefrey
Khamis, N.A.
{4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate
description The crystal structure of the title compound, [Ni(C15H 10Cl2-N2O2)(C5H 5N)3]·C5H5N, is built of molecules of a mononuclear nickel complex and uncoordinated solvent pyridine molecules. The NiII atom in the complex is coordinated by two O and one N atoms of the meridional tridentate ligand, viz. the twice deprotonated hydrazone formed from 2-hydroxy-5-chloroacetophenone and p-chlorobenzhydrazide. The remaining three coordination sites of the Ni octahedron are occupied by three coordinated pyridine ligands. © 2004 International Union of Crystallography Prinled in Great Britain - all rights reserved.
format Article
author Ali, Hapipah Mohd
Yamin, B.M.
Basirun, Wan Jefrey
Khamis, N.A.
author_facet Ali, Hapipah Mohd
Yamin, B.M.
Basirun, Wan Jefrey
Khamis, N.A.
author_sort Ali, Hapipah Mohd
title {4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate
title_short {4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate
title_full {4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate
title_fullStr {4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate
title_full_unstemmed {4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate
title_sort {4-chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3o,n2′ ,o′]benzhydrazido}-tris(pyridine- κn)nickel(ii) pyridine solvate
publisher International Union of Crystallography
publishDate 2004
url http://eprints.um.edu.my/5635/
http://www.scopus.com/inward/record.url?eid=2-s2.0-18444415795&partnerID=40&md5=0e726f4566e1d1bfe645759e76c12b9d
_version_ 1643687626836803584
score 13.160551

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