Synthesis, characterization and X-ray structures of 2,6-diacetylpyridinebis(benzenesulfonylhydrazide) and its zinc(II) complex
2,6-Diacetylpyridinebis(benzenesulfonylhydrazide) (2,6-DAPBSH) and its zinc(II) complex have been synthesized and characterized by X-ray crystallography. The ligand crystallizes in the monoclinic crystal system, space group Cc, with cell parameter = 16.808(2) angstrom, b = 16.328(2) angstrom, c = 8....
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my.um.eprints.53952019-01-29T08:35:40Z http://eprints.um.edu.my/5395/ Synthesis, characterization and X-ray structures of 2,6-diacetylpyridinebis(benzenesulfonylhydrazide) and its zinc(II) complex Yusnita, J. Ali, Hapipah Mohd Robinson, W.T. Abdulla, M.A. Puvaneswary, S. QD Chemistry 2,6-Diacetylpyridinebis(benzenesulfonylhydrazide) (2,6-DAPBSH) and its zinc(II) complex have been synthesized and characterized by X-ray crystallography. The ligand crystallizes in the monoclinic crystal system, space group Cc, with cell parameter = 16.808(2) angstrom, b = 16.328(2) angstrom, c = 8.2670(11) angstrom, beta = 91.869(9)degrees, while the zinc( II) complex crystallizes in the orthorhombic crystal system, space group Pbcn, with cell parameters a = 14.5927(3) angstrom, b = 9.6502(2) angstrom, c = 20.5610(5) angstrom. The metal center is seven-coordinate, with an approximate pentagonal bipyramidal configuration of the chelating ligand and two apically coordinated DMSO molecules. 2009 Article PeerReviewed Yusnita, J. and Ali, Hapipah Mohd and Robinson, W.T. and Abdulla, M.A. and Puvaneswary, S. (2009) Synthesis, characterization and X-ray structures of 2,6-diacetylpyridinebis(benzenesulfonylhydrazide) and its zinc(II) complex. Journal of Chemical Crystallography, 39 (9). pp. 615-618. ISSN 1074-1542 http://link.springer.com/article/10.1007%2Fs10870-009-9540-1 10.1007/s10870-009-9540-1 |
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QD Chemistry Yusnita, J. Ali, Hapipah Mohd Robinson, W.T. Abdulla, M.A. Puvaneswary, S. Synthesis, characterization and X-ray structures of 2,6-diacetylpyridinebis(benzenesulfonylhydrazide) and its zinc(II) complex |
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2,6-Diacetylpyridinebis(benzenesulfonylhydrazide) (2,6-DAPBSH) and its zinc(II) complex have been synthesized and characterized by X-ray crystallography. The ligand crystallizes in the monoclinic crystal system, space group Cc, with cell parameter = 16.808(2) angstrom, b = 16.328(2) angstrom, c = 8.2670(11) angstrom, beta = 91.869(9)degrees, while the zinc( II) complex crystallizes in the orthorhombic crystal system, space group Pbcn, with cell parameters a = 14.5927(3) angstrom, b = 9.6502(2) angstrom, c = 20.5610(5) angstrom. The metal center is seven-coordinate, with an approximate pentagonal bipyramidal configuration of the chelating ligand and two apically coordinated DMSO molecules. |
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Yusnita, J. Ali, Hapipah Mohd Robinson, W.T. Abdulla, M.A. Puvaneswary, S. |
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Yusnita, J. Ali, Hapipah Mohd Robinson, W.T. Abdulla, M.A. Puvaneswary, S. |
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Yusnita, J. |
title |
Synthesis, characterization and X-ray structures of 2,6-diacetylpyridinebis(benzenesulfonylhydrazide) and its zinc(II) complex |
title_short |
Synthesis, characterization and X-ray structures of 2,6-diacetylpyridinebis(benzenesulfonylhydrazide) and its zinc(II) complex |
title_full |
Synthesis, characterization and X-ray structures of 2,6-diacetylpyridinebis(benzenesulfonylhydrazide) and its zinc(II) complex |
title_fullStr |
Synthesis, characterization and X-ray structures of 2,6-diacetylpyridinebis(benzenesulfonylhydrazide) and its zinc(II) complex |
title_full_unstemmed |
Synthesis, characterization and X-ray structures of 2,6-diacetylpyridinebis(benzenesulfonylhydrazide) and its zinc(II) complex |
title_sort |
synthesis, characterization and x-ray structures of 2,6-diacetylpyridinebis(benzenesulfonylhydrazide) and its zinc(ii) complex |
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2009 |
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http://eprints.um.edu.my/5395/ http://link.springer.com/article/10.1007%2Fs10870-009-9540-1 |
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