Cover Image

Synthesis, characterization and X-ray structures of 2,6-diacetylpyridinebis(benzenesulfonylhydrazide) and its zinc(II) complex

2,6-Diacetylpyridinebis(benzenesulfonylhydrazide) (2,6-DAPBSH) and its zinc(II) complex have been synthesized and characterized by X-ray crystallography. The ligand crystallizes in the monoclinic crystal system, space group Cc, with cell parameter = 16.808(2) angstrom, b = 16.328(2) angstrom, c = 8....

Full description

Saved in:
Bibliographic Details
Main Authors: Yusnita, J., Ali, Hapipah Mohd, Robinson, W.T., Abdulla, M.A., Puvaneswary, S.
Format: Article
Published: 2009
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/5395/
http://link.springer.com/article/10.1007%2Fs10870-009-9540-1
Tags: Add Tag
No Tags, Be the first to tag this record!
id my.um.eprints.5395
record_format eprints
spelling my.um.eprints.53952019-01-29T08:35:40Z http://eprints.um.edu.my/5395/ Synthesis, characterization and X-ray structures of 2,6-diacetylpyridinebis(benzenesulfonylhydrazide) and its zinc(II) complex Yusnita, J. Ali, Hapipah Mohd Robinson, W.T. Abdulla, M.A. Puvaneswary, S. QD Chemistry 2,6-Diacetylpyridinebis(benzenesulfonylhydrazide) (2,6-DAPBSH) and its zinc(II) complex have been synthesized and characterized by X-ray crystallography. The ligand crystallizes in the monoclinic crystal system, space group Cc, with cell parameter = 16.808(2) angstrom, b = 16.328(2) angstrom, c = 8.2670(11) angstrom, beta = 91.869(9)degrees, while the zinc( II) complex crystallizes in the orthorhombic crystal system, space group Pbcn, with cell parameters a = 14.5927(3) angstrom, b = 9.6502(2) angstrom, c = 20.5610(5) angstrom. The metal center is seven-coordinate, with an approximate pentagonal bipyramidal configuration of the chelating ligand and two apically coordinated DMSO molecules. 2009 Article PeerReviewed Yusnita, J. and Ali, Hapipah Mohd and Robinson, W.T. and Abdulla, M.A. and Puvaneswary, S. (2009) Synthesis, characterization and X-ray structures of 2,6-diacetylpyridinebis(benzenesulfonylhydrazide) and its zinc(II) complex. Journal of Chemical Crystallography, 39 (9). pp. 615-618. ISSN 1074-1542 http://link.springer.com/article/10.1007%2Fs10870-009-9540-1 10.1007/s10870-009-9540-1
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QD Chemistry
spellingShingle QD Chemistry
Yusnita, J.
Ali, Hapipah Mohd
Robinson, W.T.
Abdulla, M.A.
Puvaneswary, S.
Synthesis, characterization and X-ray structures of 2,6-diacetylpyridinebis(benzenesulfonylhydrazide) and its zinc(II) complex
description 2,6-Diacetylpyridinebis(benzenesulfonylhydrazide) (2,6-DAPBSH) and its zinc(II) complex have been synthesized and characterized by X-ray crystallography. The ligand crystallizes in the monoclinic crystal system, space group Cc, with cell parameter = 16.808(2) angstrom, b = 16.328(2) angstrom, c = 8.2670(11) angstrom, beta = 91.869(9)degrees, while the zinc( II) complex crystallizes in the orthorhombic crystal system, space group Pbcn, with cell parameters a = 14.5927(3) angstrom, b = 9.6502(2) angstrom, c = 20.5610(5) angstrom. The metal center is seven-coordinate, with an approximate pentagonal bipyramidal configuration of the chelating ligand and two apically coordinated DMSO molecules.
format Article
author Yusnita, J.
Ali, Hapipah Mohd
Robinson, W.T.
Abdulla, M.A.
Puvaneswary, S.
author_facet Yusnita, J.
Ali, Hapipah Mohd
Robinson, W.T.
Abdulla, M.A.
Puvaneswary, S.
author_sort Yusnita, J.
title Synthesis, characterization and X-ray structures of 2,6-diacetylpyridinebis(benzenesulfonylhydrazide) and its zinc(II) complex
title_short Synthesis, characterization and X-ray structures of 2,6-diacetylpyridinebis(benzenesulfonylhydrazide) and its zinc(II) complex
title_full Synthesis, characterization and X-ray structures of 2,6-diacetylpyridinebis(benzenesulfonylhydrazide) and its zinc(II) complex
title_fullStr Synthesis, characterization and X-ray structures of 2,6-diacetylpyridinebis(benzenesulfonylhydrazide) and its zinc(II) complex
title_full_unstemmed Synthesis, characterization and X-ray structures of 2,6-diacetylpyridinebis(benzenesulfonylhydrazide) and its zinc(II) complex
title_sort synthesis, characterization and x-ray structures of 2,6-diacetylpyridinebis(benzenesulfonylhydrazide) and its zinc(ii) complex
publishDate 2009
url http://eprints.um.edu.my/5395/
http://link.springer.com/article/10.1007%2Fs10870-009-9540-1
_version_ 1643687566147321856
score 13.211869

Similar Items