(E)-4-Hydroxy-N '-(2-hydroxy-4-methoxybenzylidene)benzohydrazide monohydrate
The Schiff base molecule of the title compound, C(15)H(14)N(2)O(4)center dot-H(2)O, adopts a trans configuration with respect to the C=N double bond; the Schiff base itself is almost planar (r. m. s. deviation for all non-H atoms = 0.040 angstrom). The amido N atom is the hydrogen-bond donor to the...
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International Union of Crystallography
2009
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my.um.eprints.53722019-01-29T08:41:33Z http://eprints.um.edu.my/5372/ (E)-4-Hydroxy-N '-(2-hydroxy-4-methoxybenzylidene)benzohydrazide monohydrate Lair, N.M. Ng, S.W. Ali, Hapipah Mohd QD Chemistry The Schiff base molecule of the title compound, C(15)H(14)N(2)O(4)center dot-H(2)O, adopts a trans configuration with respect to the C=N double bond; the Schiff base itself is almost planar (r. m. s. deviation for all non-H atoms = 0.040 angstrom). The amido N atom is the hydrogen-bond donor to the water molecule, which is the hydrogen-bond donor to the hydroxy groups of two neighboring molecules. One of the hydroxyl groups acts as an intramolecular and the other as an intermolecular hydrogenbond donor. International Union of Crystallography 2009 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5372/1/Lair-2009-%28E%29-4-Hydroxy-N_%27-%282.pdf Lair, N.M. and Ng, S.W. and Ali, Hapipah Mohd (2009) (E)-4-Hydroxy-N '-(2-hydroxy-4-methoxybenzylidene)benzohydrazide monohydrate. Acta Crystallographica Section E: Structure Reports Online, 65. O189-U2926. ISSN 1600-5368 http://scripts.iucr.org/cgi-bin/paper?S1600536808042888 10.1107/s1600536808042888 |
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The Schiff base molecule of the title compound, C(15)H(14)N(2)O(4)center dot-H(2)O, adopts a trans configuration with respect to the C=N double bond; the Schiff base itself is almost planar (r. m. s. deviation for all non-H atoms = 0.040 angstrom). The amido N atom is the hydrogen-bond donor to the water molecule, which is the hydrogen-bond donor to the hydroxy groups of two neighboring molecules. One of the hydroxyl groups acts as an intramolecular and the other as an intermolecular hydrogenbond donor. |
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Article |
author |
Lair, N.M. Ng, S.W. Ali, Hapipah Mohd |
author_facet |
Lair, N.M. Ng, S.W. Ali, Hapipah Mohd |
author_sort |
Lair, N.M. |
title |
(E)-4-Hydroxy-N '-(2-hydroxy-4-methoxybenzylidene)benzohydrazide monohydrate |
title_short |
(E)-4-Hydroxy-N '-(2-hydroxy-4-methoxybenzylidene)benzohydrazide monohydrate |
title_full |
(E)-4-Hydroxy-N '-(2-hydroxy-4-methoxybenzylidene)benzohydrazide monohydrate |
title_fullStr |
(E)-4-Hydroxy-N '-(2-hydroxy-4-methoxybenzylidene)benzohydrazide monohydrate |
title_full_unstemmed |
(E)-4-Hydroxy-N '-(2-hydroxy-4-methoxybenzylidene)benzohydrazide monohydrate |
title_sort |
(e)-4-hydroxy-n '-(2-hydroxy-4-methoxybenzylidene)benzohydrazide monohydrate |
publisher |
International Union of Crystallography |
publishDate |
2009 |
url |
http://eprints.um.edu.my/5372/1/Lair-2009-%28E%29-4-Hydroxy-N_%27-%282.pdf http://eprints.um.edu.my/5372/ http://scripts.iucr.org/cgi-bin/paper?S1600536808042888 |
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13.187197 |