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2-{1- 2-((2-Ammonioethyl){2- 1-(5-chloro-2-hydroxyphenyl)ethylideneamino ethyl}amino)ethyliminio ethyl}-4-chlorophenolate trifluoroacetate

In the title ion-pair, C(22)H(29)Cl(2)N(4)O(2)(+)center dot C(2)F(3)O(2)(-), ammonium-carboxylate N-H center dot center dot center dot O hydrogen bonds link two cations and two anions about a centre of inversion to generate a hydrogen-bonded tetramer. In the cation, one of the imino N atoms is proto...

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Main Authors: Lee, S.M., Ng, S.W., Lo, K.M., Ali, Hapipah Mohd
Format: Article
Language:English
Published: International Union of Crystallography 2009
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/5371/1/Lee-2009-2-%7B1-_2-%28%282-Ammonioe.pdf
http://eprints.um.edu.my/5371/
http://journals.iucr.org/e/issues/2009/02/00/bt2856/bt2856.pdf
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spelling my.um.eprints.53712019-01-29T08:47:20Z http://eprints.um.edu.my/5371/ 2-{1- 2-((2-Ammonioethyl){2- 1-(5-chloro-2-hydroxyphenyl)ethylideneamino ethyl}amino)ethyliminio ethyl}-4-chlorophenolate trifluoroacetate Lee, S.M. Ng, S.W. Lo, K.M. Ali, Hapipah Mohd QD Chemistry In the title ion-pair, C(22)H(29)Cl(2)N(4)O(2)(+)center dot C(2)F(3)O(2)(-), ammonium-carboxylate N-H center dot center dot center dot O hydrogen bonds link two cations and two anions about a centre of inversion to generate a hydrogen-bonded tetramer. In the cation, one of the imino N atoms is protonated and donates a hydrogen bond to the O atom of the adjacent chlorophenyl ring. The other imino N atom acts as a hydrogen-bond acceptor from a phenolate O atom. International Union of Crystallography 2009 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5371/1/Lee-2009-2-%7B1-_2-%28%282-Ammonioe.pdf Lee, S.M. and Ng, S.W. and Lo, K.M. and Ali, Hapipah Mohd (2009) 2-{1- 2-((2-Ammonioethyl){2- 1-(5-chloro-2-hydroxyphenyl)ethylideneamino ethyl}amino)ethyliminio ethyl}-4-chlorophenolate trifluoroacetate. Acta Crystallographica Section E: Structure Reports Online, 65. O410-U2938. ISSN 1600-5368 http://journals.iucr.org/e/issues/2009/02/00/bt2856/bt2856.pdf 10.1107/s1600536809002943
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
language English
topic QD Chemistry
spellingShingle QD Chemistry
Lee, S.M.
Ng, S.W.
Lo, K.M.
Ali, Hapipah Mohd
2-{1- 2-((2-Ammonioethyl){2- 1-(5-chloro-2-hydroxyphenyl)ethylideneamino ethyl}amino)ethyliminio ethyl}-4-chlorophenolate trifluoroacetate
description In the title ion-pair, C(22)H(29)Cl(2)N(4)O(2)(+)center dot C(2)F(3)O(2)(-), ammonium-carboxylate N-H center dot center dot center dot O hydrogen bonds link two cations and two anions about a centre of inversion to generate a hydrogen-bonded tetramer. In the cation, one of the imino N atoms is protonated and donates a hydrogen bond to the O atom of the adjacent chlorophenyl ring. The other imino N atom acts as a hydrogen-bond acceptor from a phenolate O atom.
format Article
author Lee, S.M.
Ng, S.W.
Lo, K.M.
Ali, Hapipah Mohd
author_facet Lee, S.M.
Ng, S.W.
Lo, K.M.
Ali, Hapipah Mohd
author_sort Lee, S.M.
title 2-{1- 2-((2-Ammonioethyl){2- 1-(5-chloro-2-hydroxyphenyl)ethylideneamino ethyl}amino)ethyliminio ethyl}-4-chlorophenolate trifluoroacetate
title_short 2-{1- 2-((2-Ammonioethyl){2- 1-(5-chloro-2-hydroxyphenyl)ethylideneamino ethyl}amino)ethyliminio ethyl}-4-chlorophenolate trifluoroacetate
title_full 2-{1- 2-((2-Ammonioethyl){2- 1-(5-chloro-2-hydroxyphenyl)ethylideneamino ethyl}amino)ethyliminio ethyl}-4-chlorophenolate trifluoroacetate
title_fullStr 2-{1- 2-((2-Ammonioethyl){2- 1-(5-chloro-2-hydroxyphenyl)ethylideneamino ethyl}amino)ethyliminio ethyl}-4-chlorophenolate trifluoroacetate
title_full_unstemmed 2-{1- 2-((2-Ammonioethyl){2- 1-(5-chloro-2-hydroxyphenyl)ethylideneamino ethyl}amino)ethyliminio ethyl}-4-chlorophenolate trifluoroacetate
title_sort 2-{1- 2-((2-ammonioethyl){2- 1-(5-chloro-2-hydroxyphenyl)ethylideneamino ethyl}amino)ethyliminio ethyl}-4-chlorophenolate trifluoroacetate
publisher International Union of Crystallography
publishDate 2009
url http://eprints.um.edu.my/5371/1/Lee-2009-2-%7B1-_2-%28%282-Ammonioe.pdf
http://eprints.um.edu.my/5371/
http://journals.iucr.org/e/issues/2009/02/00/bt2856/bt2856.pdf
_version_ 1643687558889078784
score 13.160551

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