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Bis [4-hydroxy-N'-(4-methoxy-2-oxidobenzylidene-O2) benzohydrazidato-2O, N'] cadmium (II) dimethyl sulfoxide disolvate

The metal atom in the title compound, [Cd(C15H13N2O4)2]·2C2H6OS, is twice O,N,O'-chelated by two symmetry-related Schiff base ligands to define a trans-N2O4 octahedral geometry. Each anion occupies meridional sites of the octahedron; the metal atom lies on a special position of site symmetry 2....

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Main Authors: Mohd Lair, N., Ng, S.W., Ali, Hapipah Mohd
Format: Article
Published: 2009
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/5344/
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spelling my.um.eprints.53442019-08-21T09:29:10Z http://eprints.um.edu.my/5344/ Bis [4-hydroxy-N'-(4-methoxy-2-oxidobenzylidene-O2) benzohydrazidato-2O, N'] cadmium (II) dimethyl sulfoxide disolvate Mohd Lair, N. Ng, S.W. Ali, Hapipah Mohd QD Chemistry The metal atom in the title compound, [Cd(C15H13N2O4)2]·2C2H6OS, is twice O,N,O'-chelated by two symmetry-related Schiff base ligands to define a trans-N2O4 octahedral geometry. Each anion occupies meridional sites of the octahedron; the metal atom lies on a special position of site symmetry 2. The dimethyl sulfoxide molecule is a hydrogen-bond acceptor to the -NH- unit, and O-H...O hydrogen bonds link molecules into a supramolecular chain. 2009 Article PeerReviewed Mohd Lair, N. and Ng, S.W. and Ali, Hapipah Mohd (2009) Bis [4-hydroxy-N'-(4-methoxy-2-oxidobenzylidene-O2) benzohydrazidato-2O, N'] cadmium (II) dimethyl sulfoxide disolvate. Acta Crystallographica Section E: Structure Reports Online, 65 (5). m541-m541. 10.1107/S1600536809013774
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QD Chemistry
spellingShingle QD Chemistry
Mohd Lair, N.
Ng, S.W.
Ali, Hapipah Mohd
Bis [4-hydroxy-N'-(4-methoxy-2-oxidobenzylidene-O2) benzohydrazidato-2O, N'] cadmium (II) dimethyl sulfoxide disolvate
description The metal atom in the title compound, [Cd(C15H13N2O4)2]·2C2H6OS, is twice O,N,O'-chelated by two symmetry-related Schiff base ligands to define a trans-N2O4 octahedral geometry. Each anion occupies meridional sites of the octahedron; the metal atom lies on a special position of site symmetry 2. The dimethyl sulfoxide molecule is a hydrogen-bond acceptor to the -NH- unit, and O-H...O hydrogen bonds link molecules into a supramolecular chain.
format Article
author Mohd Lair, N.
Ng, S.W.
Ali, Hapipah Mohd
author_facet Mohd Lair, N.
Ng, S.W.
Ali, Hapipah Mohd
author_sort Mohd Lair, N.
title Bis [4-hydroxy-N'-(4-methoxy-2-oxidobenzylidene-O2) benzohydrazidato-2O, N'] cadmium (II) dimethyl sulfoxide disolvate
title_short Bis [4-hydroxy-N'-(4-methoxy-2-oxidobenzylidene-O2) benzohydrazidato-2O, N'] cadmium (II) dimethyl sulfoxide disolvate
title_full Bis [4-hydroxy-N'-(4-methoxy-2-oxidobenzylidene-O2) benzohydrazidato-2O, N'] cadmium (II) dimethyl sulfoxide disolvate
title_fullStr Bis [4-hydroxy-N'-(4-methoxy-2-oxidobenzylidene-O2) benzohydrazidato-2O, N'] cadmium (II) dimethyl sulfoxide disolvate
title_full_unstemmed Bis [4-hydroxy-N'-(4-methoxy-2-oxidobenzylidene-O2) benzohydrazidato-2O, N'] cadmium (II) dimethyl sulfoxide disolvate
title_sort bis [4-hydroxy-n'-(4-methoxy-2-oxidobenzylidene-o2) benzohydrazidato-2o, n'] cadmium (ii) dimethyl sulfoxide disolvate
publishDate 2009
url http://eprints.um.edu.my/5344/
_version_ 1643687551311020032
score 13.15806

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