Bis (acetato-2O, O') diphenyl (pyridine-N) tin (IV)
The asymmetric unit of the title compound, [Sn(C6H5)2- (C2H3O2)2(C5H5N)], contains two crystallography independent molecules. In both molecules, the SnIV atom is sevencoordinated in a distorted pentagonal-bipyramidal geometry with the two phenyl groups in axial positions. The two molecules diff...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
2010
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5300/1/Khaledi-2010-Bis_%28acetato-2O%2C_O%27%29.pdf http://eprints.um.edu.my/5300/ http://journals.iucr.org/e/issues/2010/04/00/om2322/om2322.pdf |
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| Summary: | The asymmetric unit of the title compound, [Sn(C6H5)2-
(C2H3O2)2(C5H5N)], contains two crystallography independent
molecules. In both molecules, the SnIV atom is sevencoordinated
in a distorted pentagonal-bipyramidal geometry
with the two phenyl groups in axial positions. The two
molecules differ mainly in the torsion of the phenyl and
pyridine rings. The dihredral angles between the phenyl rings
are 89.54 (15) and 60.11 (14)� in the two molecules while the
dihedral angles between the pyridine rings and the acetate
groups are 12.6 (2) and 41.77 (13)� in the two molecules. |
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