Bis[μ-4-hydroxy-N′-(4-methoxy-2-oxidobenzylidene)benzohydrazidato]bis[pyridinecopper(II)]
In the title compound, [Cu2(C15H12N2O4)2(C6H5N)2], each CuII atom is chelated by the tridentate doubly deprotonated Schiff base and a pyridine molecule in a nearly planar environment (r.m.s. deviation for all non-H atoms = 0.107 Å). The metal ions are bridged by one O atom from the symmetry-related...
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International Union of Crystallography
2010
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Online Access: | http://eprints.um.edu.my/5298/1/Lair-2010-Bis_mu-4-hydroxy-N_%27.pdf http://eprints.um.edu.my/5298/ https://doi.org/10.1107/S1600536810011323 |
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my.um.eprints.52982019-11-11T04:56:46Z http://eprints.um.edu.my/5298/ Bis[μ-4-hydroxy-N′-(4-methoxy-2-oxidobenzylidene)benzohydrazidato]bis[pyridinecopper(II)] Lair, Nooraziah Mohd Khaledi, Hamid Ali, Hapipah Mohd Puteh, Rustam Q Science (General) QD Chemistry In the title compound, [Cu2(C15H12N2O4)2(C6H5N)2], each CuII atom is chelated by the tridentate doubly deprotonated Schiff base and a pyridine molecule in a nearly planar environment (r.m.s. deviation for all non-H atoms = 0.107 Å). The metal ions are bridged by one O atom from the symmetry-related Schiff base ligands, forming a centrosymmetric dinuclear copper(II) complex. The dimeric complex is linked to another dimer via weaker Cu-O interactions and also O-H...N hydrogen bonds. International Union of Crystallography 2010 Article PeerReviewed text en http://eprints.um.edu.my/5298/1/Lair-2010-Bis_mu-4-hydroxy-N_%27.pdf Lair, Nooraziah Mohd and Khaledi, Hamid and Ali, Hapipah Mohd and Puteh, Rustam (2010) Bis[μ-4-hydroxy-N′-(4-methoxy-2-oxidobenzylidene)benzohydrazidato]bis[pyridinecopper(II)]. Acta Crystallographica Section E: Structure Reports Online, E66. M470. ISSN 1600-5368 https://doi.org/10.1107/S1600536810011323 doi:10.1107/s1600536810011323 |
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Q Science (General) QD Chemistry Lair, Nooraziah Mohd Khaledi, Hamid Ali, Hapipah Mohd Puteh, Rustam Bis[μ-4-hydroxy-N′-(4-methoxy-2-oxidobenzylidene)benzohydrazidato]bis[pyridinecopper(II)] |
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In the title compound, [Cu2(C15H12N2O4)2(C6H5N)2], each CuII atom is chelated by the tridentate doubly deprotonated Schiff base and a pyridine molecule in a nearly planar environment (r.m.s. deviation for all non-H atoms = 0.107 Å). The metal ions are bridged by one O atom from the symmetry-related Schiff base ligands, forming a centrosymmetric dinuclear copper(II) complex. The dimeric complex is linked to another dimer via weaker Cu-O interactions and also O-H...N hydrogen bonds. |
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Article |
author |
Lair, Nooraziah Mohd Khaledi, Hamid Ali, Hapipah Mohd Puteh, Rustam |
author_facet |
Lair, Nooraziah Mohd Khaledi, Hamid Ali, Hapipah Mohd Puteh, Rustam |
author_sort |
Lair, Nooraziah Mohd |
title |
Bis[μ-4-hydroxy-N′-(4-methoxy-2-oxidobenzylidene)benzohydrazidato]bis[pyridinecopper(II)] |
title_short |
Bis[μ-4-hydroxy-N′-(4-methoxy-2-oxidobenzylidene)benzohydrazidato]bis[pyridinecopper(II)] |
title_full |
Bis[μ-4-hydroxy-N′-(4-methoxy-2-oxidobenzylidene)benzohydrazidato]bis[pyridinecopper(II)] |
title_fullStr |
Bis[μ-4-hydroxy-N′-(4-methoxy-2-oxidobenzylidene)benzohydrazidato]bis[pyridinecopper(II)] |
title_full_unstemmed |
Bis[μ-4-hydroxy-N′-(4-methoxy-2-oxidobenzylidene)benzohydrazidato]bis[pyridinecopper(II)] |
title_sort |
bis[μ-4-hydroxy-n′-(4-methoxy-2-oxidobenzylidene)benzohydrazidato]bis[pyridinecopper(ii)] |
publisher |
International Union of Crystallography |
publishDate |
2010 |
url |
http://eprints.um.edu.my/5298/1/Lair-2010-Bis_mu-4-hydroxy-N_%27.pdf http://eprints.um.edu.my/5298/ https://doi.org/10.1107/S1600536810011323 |
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1651867324352823296 |
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13.19449 |