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Bis[μ-4-hydr­­oxy-N′-(4-meth­­oxy-2-oxido­benzyl­­idene)benzohydrazidato]bis­­[pyridine­copper(II)]

In the title compound, [Cu2(C15H12N2O4)2(C6H5N)2], each CuII atom is chelated by the tridentate doubly deprotonated Schiff base and a pyridine mol­ecule in a nearly planar environment (r.m.s. deviation for all non-H atoms = 0.107 Å). The metal ions are bridged by one O atom from the symmetry-related...

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Main Authors: Lair, Nooraziah Mohd, Khaledi, Hamid, Ali, Hapipah Mohd, Puteh, Rustam
Format: Article
Language:English
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
QD Chemistry
Online Access:http://eprints.um.edu.my/5298/1/Lair-2010-Bis_mu-4-hydroxy-N_%27.pdf
http://eprints.um.edu.my/5298/
https://doi.org/10.1107/S1600536810011323
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spelling my.um.eprints.52982019-11-11T04:56:46Z http://eprints.um.edu.my/5298/ Bis[μ-4-hydr­­oxy-N′-(4-meth­­oxy-2-oxido­benzyl­­idene)benzohydrazidato]bis­­[pyridine­copper(II)] Lair, Nooraziah Mohd Khaledi, Hamid Ali, Hapipah Mohd Puteh, Rustam Q Science (General) QD Chemistry In the title compound, [Cu2(C15H12N2O4)2(C6H5N)2], each CuII atom is chelated by the tridentate doubly deprotonated Schiff base and a pyridine mol­ecule in a nearly planar environment (r.m.s. deviation for all non-H atoms = 0.107 Å). The metal ions are bridged by one O atom from the symmetry-related Schiff base ligands, forming a centrosymmetric dinuclear copper(II) complex. The dimeric complex is linked to another dimer via weaker Cu-O inter­actions and also O-H...N hydrogen bonds. International Union of Crystallography 2010 Article PeerReviewed text en http://eprints.um.edu.my/5298/1/Lair-2010-Bis_mu-4-hydroxy-N_%27.pdf Lair, Nooraziah Mohd and Khaledi, Hamid and Ali, Hapipah Mohd and Puteh, Rustam (2010) Bis[μ-4-hydr­­oxy-N′-(4-meth­­oxy-2-oxido­benzyl­­idene)benzohydrazidato]bis­­[pyridine­copper(II)]. Acta Crystallographica Section E: Structure Reports Online, E66. M470. ISSN 1600-5368 https://doi.org/10.1107/S1600536810011323 doi:10.1107/s1600536810011323
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
language English
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Lair, Nooraziah Mohd
Khaledi, Hamid
Ali, Hapipah Mohd
Puteh, Rustam
Bis[μ-4-hydr­­oxy-N′-(4-meth­­oxy-2-oxido­benzyl­­idene)benzohydrazidato]bis­­[pyridine­copper(II)]
description In the title compound, [Cu2(C15H12N2O4)2(C6H5N)2], each CuII atom is chelated by the tridentate doubly deprotonated Schiff base and a pyridine mol­ecule in a nearly planar environment (r.m.s. deviation for all non-H atoms = 0.107 Å). The metal ions are bridged by one O atom from the symmetry-related Schiff base ligands, forming a centrosymmetric dinuclear copper(II) complex. The dimeric complex is linked to another dimer via weaker Cu-O inter­actions and also O-H...N hydrogen bonds.
format Article
author Lair, Nooraziah Mohd
Khaledi, Hamid
Ali, Hapipah Mohd
Puteh, Rustam
author_facet Lair, Nooraziah Mohd
Khaledi, Hamid
Ali, Hapipah Mohd
Puteh, Rustam
author_sort Lair, Nooraziah Mohd
title Bis[μ-4-hydr­­oxy-N′-(4-meth­­oxy-2-oxido­benzyl­­idene)benzohydrazidato]bis­­[pyridine­copper(II)]
title_short Bis[μ-4-hydr­­oxy-N′-(4-meth­­oxy-2-oxido­benzyl­­idene)benzohydrazidato]bis­­[pyridine­copper(II)]
title_full Bis[μ-4-hydr­­oxy-N′-(4-meth­­oxy-2-oxido­benzyl­­idene)benzohydrazidato]bis­­[pyridine­copper(II)]
title_fullStr Bis[μ-4-hydr­­oxy-N′-(4-meth­­oxy-2-oxido­benzyl­­idene)benzohydrazidato]bis­­[pyridine­copper(II)]
title_full_unstemmed Bis[μ-4-hydr­­oxy-N′-(4-meth­­oxy-2-oxido­benzyl­­idene)benzohydrazidato]bis­­[pyridine­copper(II)]
title_sort bis[μ-4-hydr­­oxy-n′-(4-meth­­oxy-2-oxido­benzyl­­idene)benzohydrazidato]bis­­[pyridine­copper(ii)]
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/5298/1/Lair-2010-Bis_mu-4-hydroxy-N_%27.pdf
http://eprints.um.edu.my/5298/
https://doi.org/10.1107/S1600536810011323
_version_ 1651867324352823296
score 13.19449

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